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1. An Alternative Prostaglandin Analog Synthesis Strategy:1An Initial α-Ylation Sequence for Bis-Unsaturated Prostaglandins

Author

Shoji Imamoto and Niels H. Andersen

Subjects
chemistry.chemical_classification, Prostaglandin analog, chemistry, Stereochemistry, Organic Chemistry, Sequence (biology), Alkyl
Abstract

Studies from a number of laboratories have led to prostaglandin analogs of high potency and increased specificity largely by variation of the ω chain, that is the alkyl unit beyond C-15: particularly intriguing analogs being the 16,16-dimethyl-,3 20-ethyl-,4 and various substituted 16-benzyloxy-nor-17,18,19,20-prostaglandin analogs.5 At present these are prepared by the standard Corey route,6 in which ω-ylation precedes α-ylation.

Published
1976

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