1. Effect of Pressurized Carbon Dioxide on Mutual Miscibility Temperatures for Methanol + Hydrocarbon Binary Liquid Mixtures
- Author
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Tohru Saito, Yoshio Iwai, Futoshi Nakadai, Daisuke Taniguchi, Takeshi Furuya, Kenji Ochi, and Yasuhiko Arai
- Subjects
chemistry.chemical_classification ,Cyclohexane ,General Chemical Engineering ,Thermodynamics ,General Chemistry ,Decane ,Miscibility ,Hexane ,chemistry.chemical_compound ,Hydrocarbon ,chemistry ,Non-random two-liquid model ,Organic chemistry ,Methanol ,Physics::Chemical Physics ,Astrophysics::Galaxy Astrophysics ,Octane - Abstract
An apparatus has been developed for the measurement of mutual miscibility temperatures of binary liquid mixtures coexisting with a high pressure gas to examine to what extent the phase behavior changes. Methanol + hydrocarbon (cyclohexane, hexane, octane, and decane) binary mixtures were selected as typical polar and non-polar mixtures. And their mutual miscibility temperatures were measured at temperatures from 275.4 to 363.9 K and pressures up to 2.2 MPa with pressurized carbon dioxide (CO2). The experimental results were correlated with the NRTL equation by adopting a pseudo-binary mixture treatment. The NRTL interaction parameters between methanol and hydrocarbons were assumed to vary due to the presence of CO2. A good agreement between the experimental and the correlated mutual miscibility temperatures is obtained.
- Published
- 2006
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