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The title compound, C 17 H 10 BrCl 2 NO 2 , crystallizes in the monoclinic space group C 2/ c with a large cell volume of 6207 (3) Å 3 . The asymmetric unit of the title compound investigated at 120 K contains two crystallographically independent mol-ecules ( Z ' = 2). Each mol-ecule demonstrates slight non-planarity in the solid state and a Z -configuration for the exocyclic C=C bond. The crystal packing reveals the presence of π-π stacking inter-actions between the substituted benzene rings [centroid-centroid distances of 3.836 (5) Å, shift distances in the range 1.272-1.843 Å]., (© Mayorova et al. 2020.)

In the title compound, C 12 H 13 NO 2 , the pyrrolidinone moiety is almost flat while the oxazole ring adopts an envelope conformation with the carbon atom bearing the phenyl substituent as the flap: the angle between the mean planes of the fused heterocyclic rings is 45.47 (19)°. In the crystal, C-H⋯O and C-H⋯π contacts link the mol-ecules into infinite [010] chains., (© Linkova et al. 2020.)

The crystal structures and packing features of two homologous Meyer's bicyclic lactams with fused pyrrolidone and medium-sized perhydropyrimidine rings, namely, 8a-phenyl-2,3,4,7,8,8a-hexahydropyrrolo[1,2-a]pyrimidin-6(1H)-one, C 13 H 16 N 2 O (1), and 8a-(4-methylphenyl)-2,3,4,7,8,8a-hexahydropyrrolo[1,2-a]pyrimidin-6(1H)-one, C 14 H 18 N 2 O (2), were elucidated, and Hirshfeld surface plots were calculated and drawn for visualization and a deeper analysis of the intermolecular noncovalent interactions. Molecules of 1 and 2 are weakly linked by intermolecular C=O...H-N hydrogen bonds into chains, which are in turn weakly linked by other C=O...H-C ar interactions. The steric volume of the substituent significantly affects the crystal packing pattern.