1. Aqua[1-(1,10-phenanthrolin-2-yl-κ2N,N′)-1H-pyrazol-3-amine-κN2](sulfato-κO)copper(II) methanol monosolvate dihydrate
- Author
-
Liang Yuan, Liu Shu Lian, Zhao Yan Xia, Chi Yan Hui, and Shi Jing Min
- Subjects
Metal-Organic Papers ,chemistry.chemical_element ,General Chemistry ,Condensed Matter Physics ,Bioinformatics ,Copper ,Medicinal chemistry ,Ion ,Solvent ,chemistry.chemical_compound ,chemistry ,General Materials Science ,Chelation ,Basal plane ,Amine gas treating ,Methanol ,Sulfate - Abstract
In the title compound, [Cu(SO(4))(C(15)H(11)N(5))(H(2)O)]·CH(3)OH·2H(2)O, the Cu(II) ion is in a distorted square-pyramidal geometry, in which three N atoms from the chelating 1-(1,10-phenanthrolin-2-yl)-1H-pyrazol-3-amine ligand and one O atom from a sulfate anion define the basal plane and the O atom from the coordinating water mol-ecule is located at the apex. In the crystal, hydrogen-bonding inter-actions involving the coordinating and solvent water mol-ecules, the methanol solvent mol-ecule and the amine group (one with an intra-molecular inter-action to one of the sulfate O atoms) of the complex are observed. π-π inter-actions between symmetry-related phenantroline moieties, with a shortest centroid-centroid inter-action of 3.573 (2)°, are also present.
- Published
- 2012