1. Unusual thermodynamics of low-energy phonons in the Dirac semimetal Cd3As2
- Author
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Zhen Wang, Hengcan Zhao, Meng Lyu, Junsen Xiang, Qingxin Dong, Genfu Chen, Shuai Zhang, and Peijie Sun
- Subjects
General Physics and Astronomy - Abstract
By studying the thermal conductivity, specific heat, elastic modulus, and thermal expansion as a function of temperature for Cd3As2, we have unveiled a couple of important thermodynamic features of the low-energy phonons strongly interacting with Dirac electrons. The existence of soft optical phonons, as inferred from the extremely low thermal conductivity, is unambiguously confirmed by low-temperature specific heat revealing significant deviation from Debye’s description. The estimated Debye temperature is small in the range of 100–200 K and varies significantly depending upon the measurement used in its experimental determination. The thermodynamic Grüneisen ratio γ reveals a remarkable reduction below about 100 K, an energy scale that is highly relevant to the Dirac states, towards negative values below about 10 K that are indicative of lattice instability.
- Published
- 2022
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