1. Layered K0.37MnO2·0.25H2O as cathode material for potassium ion batteries
- Author
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Chang Liu, Feiyang Chao, Zhen Huang, Zhuo Qu, Gangyuan Liu, Yao Xiao, Wenwei Zhang, Han Tang, Shijie Dong, and Ping Luo
- Subjects
Mechanics of Materials ,Mechanical Engineering ,General Materials Science ,Bioengineering ,General Chemistry ,Electrical and Electronic Engineering - Abstract
Lithium supply shortages have prompted the search for alternatives to widespread grid system applications. Potassium-ion batteries (PIBs) have emerged to promising candidates for this purpose. Nonetheless, the large radius of K+ (1.38 Å) impedes the march of satisfactory cathode materials. Here, we used solid-phase synthesis to prepare a layered K0.37MnO2·0.25H2O (KMO) cathode, comprising alternately connected MnO6 octahedra with a large interlayer spacing (0.71 nm) to accommodate the migration and transport of K+ ions. The cathode material achieved initial specific capacities of 102.3 and 88.1 mA h g−1 at current densities of 60 mA g−1 and 1 A g−1, respectively. The storage mechanism of K+ ions in PIBs was demonstrated ex situ using x-ray diffraction, x-ray photoelectron spectroscopy, and Raman spectroscopy measurements. Overall, our proposed KMO was confirmed as an auspicious cathode material for potential use in PIBs.
- Published
- 2023