1. Facile Synthesis Gold-Polyindole-Reduced Graphene Oxide Ternary Nanocomposites with Enhanced Electrocatalytic Activity for the Electrochemical Sensing of Caffeine.
- Author
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Rongfang Li, Lei Yao, Zhongxia Wang, Weixin Lv, Wenjuan Wang, Fenying Kong, and Wei Wang
- Subjects
GRAPHENE oxide ,ELECTROCHEMICAL analysis - Abstract
An efficient and eco-friendly ultraviolet (UV) irradiation method was developed to synthesize a ternary nanocomposites of goldpolyindole-reduced graphene oxide (Au-PIn-RGO), and as-prepared nanomaterial was then used to fabricate an electrochemical caffeine (CAF) sensor. In the synthesis process, the polymerization of the indole monomer, the reduction of Au3+ ions and GO occurred simultaneously by UV irradiation without using any chemical reagents. The synthesis procedure was simple, inexpensive and green environmentally. Morphology, structure and composition of the Au-PIn-RGO nanocomposites were characterized by various technologies including UV-visible (UV-Vis) spectroscopy, fourier transform infrared (FT-IR) spectroscopy, transmission electron microscopy (TEM), X-ray powder diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). Under the optimum conditions, a linear relationship existed between oxidation peak currents and the concentration of CAF in the range of 0.8-40 µM and 40-1000 µM, with a detection limit of 0.26 µM (S/N = 3). The proposed method was successfully applied to determine the CAF in beverages. [ABSTRACT FROM AUTHOR]
- Published
- 2019
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