1. Investigation of growth dynamics of β-Ga2O3 LPCVD by independently controlling Ga precursor and substrate temperature
- Author
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Gavax Joshi, Yogesh Singh Chauhan, and Amit Verma
- Subjects
General Engineering ,General Physics and Astronomy - Abstract
We present results on low-pressure chemical vapor deposition (LPCVD) of β-Ga2O3 on a c-sapphire substrate with independent control of Ga precursor (T P) and substrate (T SUB) temperatures, allowing independent tuning of the Ga flux and thermal energy of the adatoms on the substrate surface. Experiments with constant T P = 900 °C with varying T SUB (600 °C–1050 °C) and varying T P (800 °C–1000 °C) with constant T SUB = 900 °C are reported. Island/nanorod formation on top of β-Ga2O3 thin film was observed at T SUB = 600–750 °C, suggesting the Stranski–Krastanov mode of growth, while thin film growth was observed for T SUB = 825–1050 °C. The growth rate decreased at higher T SUB, whereas it increased sharply for T P = 800–850 °C followed by a quasi-saturation for T P = 800–1000 °C. The growth rate evolution in both experiments reveals the significant role of gallium suboxide formation and desorption at the precursor/film during β-Ga2O3 LPCVD. This study provides useful insights into the growth dynamics involved in LPCVD of β-Ga2O3.
- Published
- 2023