1. Investigation of slurry erosion-corrosion behavior of Ta(Si1−xAlx)2 nanocrystalline coatings
- Author
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Jiang Xu, Qingwen Xie, Shuang Peng, Zhengyang Li, and Shuyun Jiang
- Subjects
erosion-corrosion ,refractory metal silicides ,slurry flow ,EIS ,mechanical properties ,Materials of engineering and construction. Mechanics of materials ,TA401-492 ,Chemical technology ,TP1-1185 - Abstract
To enhance the erosion-corrosion resistance of titanium alloys, two Ta(Si _1−x Al _x ) _2 coatings with different Al content were deposited on Ti−6Al−4V alloy by double cathode glow discharge method. The coatings consist of single hexagonal C40 structured TaSi _2 phase, which forms an equiaxed grain structure with an average diameter of ∼5 nm. Al addition was found to enhance the values of H/E and adhesive strength between the substrate and coating. The erosion–corrosion behavior of the coatings was studied in a liquid–solid acid slurry flow (specifically a medium of 5 wt% HCl solution that contained a 10 wt% concentration of silica-based sand) using electrochemical measurements, weight loss tests and SEM observation. The results indicated that the ternary Ta(Si _0.875 Al _0.125 ) _2 coating provided better protection, compared to the binary TaSi _2 coating, against the combined attack of mechanical erosion and electrochemical corrosion in a liquid–solid acid slurry flow. This is attributable to high self-healing ability of the surface passive film and a higher H/E ratio.
- Published
- 2020
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