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Ti-6Al-4V(TC4) titanium alloy is a kind of α+β type two-phase titanium alloy widely used. However, due to the microscopic defects in additive manufacturing titanium alloy, its mechanical properties are lower than the forging level, and post-treatment is usually required. Therefore, it is necessary to further study the additive manufacturing process and post-treatment of TC4 titanium alloy. In this paper, the microstructure and comprehensive properties of titanium alloy were analyzed by the changes of common process parameters such as energy input power and scanning strategy in the additive manufacturing process, and the influence of other process parameters such as protective gas type, substrate thickness, powder size and other factors in the additive manufacturing process was introduced. The influence of common heat treatment methods after additive manufacturing on its microstructure and mechanical properties was also comprehensively analyzed, and the influence of new post-heat treatment methods, such as vacuum heat treatment and cyclic heat treatment, as well as the influence of multiple post-treatment and comprehensive use of heat treatment were summarized. Generally speaking that the reasonable selection of additive manufacturing process parameters and the application of post-heat treatment method are the basis for obtaining titanium alloy components with excellent performance. The comprehensive use of various heat treatment methods or other post-treatment methods and heat treatment are the effective ways to further improve the performance of titanium alloy components in additive manufacturing. To establish a uniform selection standard for additive manufacturing process parameters and post-processing process is the key to the future development of additive manufacturing.