1. CONJUGATED PLATINUM-POLY-YNES WITH EXTENDED ARYLENE ETHYNYLENES.
- Author
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NAHER, MASNUN, MEHDI, SHAWON SHAHRIAR, AHMED, KAUSAR, RAHMAN, MOSTAFIJUR, RAHMAN KHAN, MOHAMMAD MIZANUR, and YOUNUS, MUHAMMAD
- Subjects
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POLYYNES , *PLATINUM , *CONDENSATION - Abstract
The platinum-poly-yne polymers poly[trans-bis(tri-n-butylphosphine) platinum-poly (4,4´- diethynylenearylene)] (arylene = biphenylene 3 and anthracene 4) were synthesized by the condensation reaction between poly(diethynylenearylene) (arylene = biphenylene 1 and anthracene 2) and trans-[(PnBu3)2PtCl2] in diisopropyl amine and dichloromethane under nitrogen atmosphere in the presence of CuI catalyst. The newly synthesized platinum containing poly-yne polymers exhibit good solubility in common organic solvents. These metal linked polymers were characterized by IR, ¹H NMR and 31P NMR spectros [ABSTRACT FROM AUTHOR]
- Published
- 2015
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