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Urban air pollution is rapidly becoming a major environmental problem of public concern in several developing countries of the world. Jeddah, the second-largest city in Saudi Arabia, is subject to high air pollution that has severe implications for the health of the exposed population. Fine particulate matter (PM2.5) samples were collected for 24 h daily, during a 1-year campaign from 2013 to 2014. This study presents a detailed investigation of PM2.5 mass, chemical composition, and sources covering all four seasons of the year. Samples were analyzed for black carbon (BC), trace elements (TEs), and water-soluble ionic species (IS). The chemical compositions were statistically examined, and the temporal and seasonal patterns were characterized using descriptive analysis, correlation matrices, and elemental enrichment factor (EF). Source apportionment and source locations were performed on PM2.5 samples using the positive matrix factorization (PMF) model, elemental enrichment factor, and air-mass back trajectory analysis. The 24-h mean PM2.5 and BC concentrations ranged from 33.9 ± 9.1–58.8 ± 25 µg/m3 and 1.8 ± 0.4–2.4 ± 0.6 µg/m3, respectively. Atmospheric PM2.5 concentrations were well above the 24-h WHO guideline of 15 µg/m3, with overall results showing significant temporal and seasonal variability. EF defined two broad categories of TEs: anthropogenic (Ni, V, Cu, Zn, Cl, Pb, S, Lu, and Br), and earth-crust derived (Al, Si, Mg, K, Ca, Ti, Cr, Mn, Fe, and Sr). The five identified factors resulting from PMF were (1) fossil-fuels/oil combustion (45.3%), (2) vehicular emissions (19.1%), (3) soil/dust resuspension (15.6%), (4) industrial mixed dust (13.5%), and (5) sea-spray (6.5%). This study highlights the importance of focusing control strategies, not only on reducing PM concentration but also on the reduction of components of the PM as well, to effectively protect human health and the environment. [ABSTRACT FROM AUTHOR]

Particulate air pollution is a health concern. This study determines the microscopic make-up of different varieties of sand particles collected at a sand dune site in Badr, Saudi Arabia in 2012. Three categories of sand were studied: black sand, white sand, and volcanic sand. The study used multiple high resolution electron microscopies to study the morphologies, emission source types, size, and elemental composition of the particles, and to evaluate the presence of surface "coatings or contaminants" deposited or transported by the black sand particles. White sand was comprised of natural coarse particles linked to wind-blown releases from crustal surfaces, weathering of igneous/metamorphic rock sources, and volcanic activities. Black sand particles exhibited different morphologies and microstructures (surface roughness) compared with the white sand and volcanic sand. Morphological Scanning Electron Microscopy (SEM) and Laser Scanning Microscopy (LSM) analyses revealed that the black sand contained fine and ultrafine particles (50 to 500 nm ranges) and was strongly magnetic, indicating the mineral magnetite or elemental iron. Aqueous extracts of black sands were acidic (pH = 5.0). Fe, C, O, Ti, Si, V, and S dominated the composition of black sand. Results suggest that carbon and other contaminant fine particles were produced by fossil-fuel combustion and industrial emissions in heavily industrialized areas of Haifa and Yanbu, and transported as cloud condensation nuclei to Douf Mountain. The suite of techniques used in this study has yielded an in-depth characterization of sand particles. Such information will be needed in future environmental, toxicological, epidemiological, and source apportionment studies. [ABSTRACT FROM AUTHOR]