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Severe climatic and environmental conditions warrant the use of stabilization agents in aid of compaction for sustainable improvement in engineering properties of clays. Physicochemical agents are a viable option because they are cost effective, environmentally friendly, and offer improved long-term performance of treated soils. This research developed a fundamental understanding of the clay–water–electrolyte admixtures relations. Based on a comprehensive literature review, the effect of nanomaterials, biopolymers, and geopolymers on the behavior of compacted clays was investigated. It was found that all of these admixtures facilitate the development of an aggregated soil microstructure through unique mechanisms. Biopolymers have the highest water adsorption capacity followed by geopolymers and then by nanomaterials. The effect of admixtures on optimum compaction properties follows a decreasing trend similar to untreated clays (S = 80% ± 20%). The variation of hydraulic conductivity, compression index, and compressive strength are largely within the family of curves identified by typical relationships for compacted clays. These preliminary findings indicate that not all engineering properties are improved to the same level by the different types of physicochemical admixtures. The specific nature of geotechnical engineering (soil type and site conditions) as well as the wide range of admixture types and potential biodegradation of some of the reagents are the major shortcoming of using this class of materials. [ABSTRACT FROM AUTHOR]

Considering the relevance of clay mineral-bearing geomaterials in landslide/mass movement hazard assessment, various engineering projects for resource development, and stability evaluation of underground space utilization, it is important to understand the permeability of these clay mineral-based geomaterials. However, only a few quantitative data have been reported to date regarding the effects of the clay mineral type and hydraulic gradient on the permeability of clay mineral materials. This study was conducted to investigate the permeability of clay mineral materials based on the clay mineral type, under different hydraulic gradient conditions, through a constant-pressure permeability test. Comparative tests have revealed that the difference in the types of clay mineral influences the swelling pressure and hydraulic conductivity. In addition, it has been found that the difference in water pressure (hydraulic gradient) affects the hydraulic conductivity of clay mineral materials. The hydraulic conductivity has been found to be closely associated with the specific surface area of the clay mineral material. Furthermore, the hydraulic conductivity value measured is almost consistent with the value calculated theoretically using the Kozeny–Carman equation. Moreover, the hydraulic conductivity is also found to be closely associated with the hydrogen energy, calculated from the consistency index of clay. This result suggests that the hydraulic conductivity of clay mineral materials can be estimated based on the specific surface area and void ratio, or consistency index of clay. [ABSTRACT FROM AUTHOR]