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Selective extraction of low-concentration thorium (Th(IV)) from wastewater is a very important research topic. In this paper, amidoxime cellulose was synthesized, and its composition and structure were characterized by FT-IR, SEM, XPS, and elemental analysis. The adsorption experiment results showed that the adsorption reaction was a spontaneous exothermic process. When the solid–liquid ratio was 0.12 g/L and the pH value was 3.5, the adsorption percentage of the Th(IV) in water onto amidoxime-functionalized cellulose (AO-CELL) could reach over 80%. The maximum adsorption capacity can reach to 450 mg/g. At the same time, the adsorption selectivity, desorption process and reusability of the material were also studied. The results showed that the AO-CELL had a good selectivity for Th(IV) in the system with Sr2+, Cu2+, Mg2+, Zn2+, Pb2+, Ni2+, and Co2+ as co-ions. In the nitric acid concentration of 0.06 mol/L system, the AO-CELL desorption rate of Th(IV) can reach 95%, and the adsorption rate of Th(IV) in aqueous solution of AO-CELL is still above 60% when the AO-CELL is reused four times. The above results show that the amidoxime cellulose adsorption material synthesized by our research group has good selective adsorption performance for Th(IV) of a low concentration in an aqueous solution and has a good practical application value. [ABSTRACT FROM AUTHOR]

In this report, the β-CD(AN- co -AA) hydrogel was used to remove the thorium(IV) [Th(IV)] from the water system, and the new adsorbent was characterized through Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and X-ray diffraction (XRD). The influences of contact time, pH value, ionic strength, solid-liquid ratio, initial Th(IV) concentration, and temperature on Th(IV) adsorption onto the functional hydrogel were researched. The results showed that the experimental data followed the Langmuir isotherm and the maximum adsorption capacity ( q max ) for Th(IV) was 692 mg/g at pH 2.95, which approached the calculated ( q e ) 682 mg/g. The desorption capacity of Th(IV) in different HNO₃ concentrations ranging from 0.005 to 0.5 M was also studied, and the percentage of the maximum desorption was 86.85% in the condition of 0.09 M HNO₃. The selectivity of β-CD(AN- co -AA) hydrogel was also be studied, the results indicated that this material retained the good adsorption capacity to Th(IV) even when the Ca 2+ , Mg 2+ , or Pb 2+ existed in the system. The findings indicate that β-CD(AN- co -AA) can be used as a new candidate for the enrichment and separation of Th(IV), or its analogue actinides, from large-volume solution in practical application., Competing Interests: The authors declare no conflict of interest.