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Simple Summary: The feeding and nutrition of Hermetia illucens becomes an important issue due to its ability to convert organic by-products obtained from agri-food chains into extremely valuable biomass. In this context, coffee silverskin, a by-product of coffee roasting, enriched with 5%, 10%, 20%, and 25% of microalgae (Schizochytrium limacinum and Isochrysis galbana), was investigated as a basal rearing substrate for H. illucens. The study also analyzed the evaluation of the environmental sustainability of diets. The results showed that the inclusion of microalgae in the diets led to an increase in larval growth performance, especially in larvae fed with S. limacinum. Conversely, the higher the proportion of microalgae, the greater the environmental impact of larval production. Therefore, considering that the 10% S. limacinum inclusion achieved the best waste reduction index and showed only minor differences compared to the higher inclusions of this microalgae, it can be considered a compromise between the nutritional properties of the insects and sustainability. Moreover, considering that the rearing substrate enriched with 10% S. limacinum achieved the best waste reduction index and showed only minor differences in terms of nutritional value of H. illucens prepupae compared to the higher inclusions of this microalgae, it can be considered a compromise for sustainable insect production. Hermetia illucens is a promising insect due to its ability to convert low-value substrates as food chain by-products into highly nutritious feed. Its feeding and nutrition are important issues. The aim of this work was to investigate the effect of different substrates consisting of coffee silverskin, a by-product of the roasting process, enriched with different inclusions of microalgae (5%, 10%, 20%, and 25%), Schizochytrium limacinum, and Isochrysis galbana, combined with the assessment of environmental sustainability by LCA. In general, the addition of microalgae led to an increase in larval growth performance due to the higher content of protein and lipids, although S. limacinum showed the best results with respect to larvae fed with coffee silverskin enriched with I. galbana. A higher prepupal weight was observed in larvae fed with 10%, 20%, and 25% S. limacinum; shorter development times in larvae fed with 25% of both S. limacinum and I. galbana; and a higher growth rate in larvae fed with 25% S. limacinum. The 10% S. limacinum inclusion was only slightly different from the higher inclusions. Furthermore, 10% of S. limacinum achieved the best waste reduction index. The greater the inclusion of microalgae, the greater the environmental impact of larval production. Therefore, the addition of 10% S. limacinum appears to be the best compromise for larval rearing, especially considering that a higher inclusion of microalgae did not yield additional benefits in terms of the nutritional value of H. illucens prepupae. [ABSTRACT FROM AUTHOR]

The relevant growth of the wood pellet market in Europe in the last decade led to an increased focus on solid biofuel as a necessary and available renewable resource for energy production. Among biofuels, wooden pellets are among the most widespread for domestic heating. Therefore, monitoring the qualitative properties of commercialized pellets is crucial in order to minimize the amount of harmful emissions in residential areas. Standard ISO 17225 sets threshold values for the chemical and physical properties that commercialized biofuels must fulfil. Specifically, ISO 17225-2 defines that pellets for residential use must be produced from virgin wood, but no method is proposed to assess the actual origin of the material, leading to the risk of the commercialization of pellets made up from chemically treated materials. This study proposes a model obtained via near infrared spectroscopy analyses and chemometrics methods, such as classification, to rapidly assess whether pellets are made up of virgin or chemically treated wood. The result suggests the effectiveness of NIRs for the detection of non-virgin pellets with an accuracy greater than 99%. Furthermore, the model appeared to be accurate in the assessment of both milled and intact pellets, making it a potential in-line instrument for assessments of pellets' quality. [ABSTRACT FROM AUTHOR]

Increasing legume intake through dietary diversification confers nutritional and environmental benefits. This study used life cycle assessment to evaluate the environmental impacts of producing frozen green peas from conventional and organic farming. We explored two ways of treating farm data: modeling each farm (baseline) and using a uniform distribution of each farm parameter's average, maximum, and minimum values (alternative). We also assessed the indirect land-use change (iLUC) impacts by applying a deterministic model and used the EF 3.0 method to estimate the midpoint environmental impacts. The results of the two scenarios for pea cultivation (including iLUC) showed notable differences in absolute terms with minor discrepancies in the contribution analysis (e.g., climate change (CC) for the baseline and alternative were 0.98 and 2.09 kg CO2 eq./kg fresh peas, respectively). Generally, conventional peas had a higher environmental impact than organic peas, although this was not uniformly observed across all farms. When included, iLUC accounted for nearly half of the CC score. Pea cultivation was the most impactful phase due to emissions from fertilizers and field operations. The impacts of pea production can be reduced by anaerobic digestion of pea residues with energy and nutrient recycling. However, improvements in processing and nitrogen use efficiency could significantly enhance the overall environmental performance of frozen green peas. In summary, this study emphasizes the need for sustainable practices to minimize the environmental impact of frozen pea production. [ABSTRACT FROM AUTHOR]

Biomass materials play a key role in the renewable energy market as they can serve as a suitable alternative to fossil fuels. However, the quality of the material entering bioenergy plants is often a cause of technical concern. Biomass quality assessment is crucial not only for energy characterization but also for environmental and operational aspects. The goal of this study is to characterize and classify the biomasses used by Italian power plants with reference to the quality classes stated by the ISO standard 17225:2021. A further objective is to verify the ability of the standard to classify heterogeneous and specific biomasses. In this study, more than 900 biomass samples were analyzed. The samples were collected from several Italian power plants with >5 MWe between 2010 and 2020, and the most important physical and chemical parameters were analyzed according to the international standards of reference. The results of the analyses were collected in a large dataset used for subsequent statistical analyses. Statistical analyses applied are Principal Component Analysis and Pearson correlation maps, which showed that the ash content is a fundamental and ideal parameter to assess the biomass quality. Results obtained demonstrate that herbaceous biomasses are of low quality mainly due to the high ash content; a relatively low ash content was found for woody biomasses. [ABSTRACT FROM AUTHOR]

The chemical composition of woody biomass directly influences its thermal degradation and, subsequently, the selection of processes and technologies used for its conversion into energy or value-added products. Thus, the present study aimed to evaluate the thermal behavior and chemical-physical characteristics of three different woody biomass species (hardwood, softwood and chemically-treated wood) using thermogravimetric and characterization analysis based on ISO 16948, ISO 18125 and ISO 18122 methods. The main findings show that the most significant trend of mass loss, around 70%, in the thermal degradation of the different species of woody biomass occurred between 150 °C and 500 °C and that the residual mass at 650 °C was between 13% and 24%. Although the three species of woody biomass showed a high average energy content (19.60 MJ/kg), softwood samples had a more stable thermal degradation than hardwoods and chemically-treated woods. [ABSTRACT FROM AUTHOR]

The black soldier fly (BSF) is recognised as a valuable insect for mitigating feed and organic waste management challenges. Thus, concerted efforts are being directed toward the promotion of the BSF. Despite the numerous advantages of BSF larvae, there are several critical environmental aspects, particularly its global warming potential, that need to be considered before large-scale adoption due to the complexity of the insect's value chain. The direct assessment of greenhouse gas (GHG) and ammonia emissions from BSF larvae biotreatment is crucial for conducting a life cycle assessment (LCA) to evaluate the insect products' environmental performance. This article reviews the emissions of GHG from BSF larvae bioconversion activities based on different gas sensing techniques while highlighting the factors that influence these emissions. Generally, low gas emissions were reported. However, the influence of various factors influencing emissions remains unclear, especially for nitrous oxide. We also analysed LCA studies on BSFL products while emphasising the uncertainties and variabilities among the studies. The wide variation of impact scores reported in the studies suggests that standardised guidelines should be developed to streamline methodical approaches for impact assessments pertaining to system boundaries, functional units, allocation, and system expansion assumptions. We identified several aspects for future improvements to harmonise studies in order to enhance the comparative assessment of the BSFL products. [ABSTRACT FROM AUTHOR]

Quality is a crucial issue for the energy use of residual biomass, especially for agricultural biomass [[20]]. The authors highlighted that local sourcing of biomass materials with an efficient logistics system presents environmental benefits and significant economic advantages regarding various logistical aspects of biomass transport and energy distribution. All the published papers deal with aspects connected with the SI's theme, such as residual biomass quality, sustainability assessment of solid biofuel production, and bioenergy sustainability assessment. Ilari et al. [[45]] analytically defined the quality of residual woody biomass produced in marginal areas and the solid biofuels obtained from that biomass material. [Extracted from the article]

Background: The production of seeds for horticultural crops has seen a steady growth since 2006. Onion is one of the most widespread crops that followed this trend until 2013, undergoing a slight decline in 2016. Even though these crops are characterized by high economic value, they present some important issues such as high costs and labor required by some operations such as threshing. The purpose of this study is the evaluation of a patented and dedicated system for mechanical threshing throughout the evaluation of seed quality parameters. Methods: The study was conducted comparing seed samples mechanically threshed obtained from 12 companies and samples of the same batches manually threshed to determine the maximum qualitative potential. The chosen terms for comparison are the most important qualitative parameters included within ISTA standards for seed evaluation. Results: The mechanically threshed seeds show lower values for all the considered quality parameters compared to those found in the control samples. In the same way, there is also greater variability. Conclusions: The introduction of the dedicated mechanical systems allows the reduction of seed processing time while maintaining the quality standards within the limits of merchantability, but for obtaining higher standards, further analysis is necessary. [ABSTRACT FROM AUTHOR]

The agricultural sector and its related production chains are good sources of residual biomass. Olive and vineyard pruning residues are present in high quantities in Italy. The limited bulk and energy densities of these biomass materials affect the harvesting and logistic costs, limiting energy and environmental sustainability. Pelletisation is the most efficient process for increasing bulk and energy densities. This study evaluates the pelletisation process of olive and vineyard prunings, pure, or blended with variable quantities of spruce sawdust. A 15 kW pelletisation system was chosen, in line with production at the farm level. The most important quality parameters of the produced agripellets were analyzed. The results of this investigation suggest that blending could valorize other biomass materials less suitable for pelletisation and reach the pellet quality required by Italian technical standards. The addition of pruning residues to spruce sawdust leads to an improvement in durability. Spruce sawdust pellets have a durability value of 78.4%. Adding 20% of olive prunings (S80O20) increases this value to 92.2, while adding 20% vineyard prunings (S80V20) increases this value up to 90.3. The addition of 20% of pruning residues significantly increased the length and decreased fines. [ABSTRACT FROM AUTHOR]

At present, the majority of available road and jet biofuels are produced from oleochemical feedstocks that include vegetable oils and biowastes such as waste cooking oils and animal fats. Additionally, one of the most promising ways to achieve long-term environmental goals is to sustainably use lignocellulosic residues. These resources must be treated through a deoxygenation process and subsequent upgrading processes to obtain high-quality road and jet biofuels. Accordingly, in this review, we explore recent advancements in the deoxygenation of oleochemical and lignocellulosic feedstocks in the absence of hydrogen to produce high-quality road and jet biofuels, mainly focusing on the use of nanomaterials as catalysts and the valorization of lipid-rich biowastes and lignocellulosic residues. As a result, we found that regardless of the catalyst particle size, the coexistence of basic sites and weak/medium acid sites is highly important in catalytic systems. Basic sites can enhance the removal of oxygenates via decarboxylation and decarbonylation reactions and inhibit coke formation, while weak/medium acid sites can enhance the cracking reaction. Additionally, the extraction of value-added derivatives from lignocellulosic residues and their subsequent upgrade require the use of advanced methods such as the lignin-first approach and condensation reactions. [ABSTRACT FROM AUTHOR]

Phasing out fossil fuels to renewables is currently a global priority due to the climate change threat. Advocacy for biomass use as an energy source requires assessing the quality biomass and ecological impacts of bioenergy supply chains. This study evaluated the quality of biomass residues from orchards and silviculture transported from different Northern and Central Italy locations and the carbon footprint of a biomass power plant. The total greenhouse emissions were calculated based on primary data for 2017 according to the ISO/TS 14067. All the residue samples showed their suitability for biofuel use. Ash content was relatively low on average (3–5% d.m.), except for grapevine residues (18% d.m.). The lower heating value was within the expected range of 15–21 MJ kg−1 for plant species. The average GHG emission from the power plant was 17.4 g CO2 eq./MJ of electrical energy, with the energy conversion (38%) and transportation of biomass (34%) phases being the main impact contributors. For this study, impacts of residual agricultural residue were about half that of residues from forest management, mainly due to chipping and greater transport distance. Results show that sourcing residual biomass materials for electricity generation close to power plants significantly reduce GHG emissions compared to conventional fossil fuels. [ABSTRACT FROM AUTHOR]

Replacing fossil energy sources with renewable energy sources is a key strategic action to limit environmental issues. To achieve this goal, substitution with biomass is beneficial due to its versatility in various fields. In terms of circular economy and sustainability, the possibility of energy exploitation of residual biomass is particularly desirable in small-medium enterprises. The use of supply chain by-products can improve sustainability and create opportunities for companies. The purpose of this study is to evaluate the suitability of residual biomass of conifers and broad-leaved trees to produce quality pellets using an agri-pellet machine activated by the power take-off of a tractor. This system can be employed at the farm level. Wood biomass of four species was tested; poplar, stone pine, black locust, and oak. Wood chips samples were analyzed to determine their qualitative characteristics following the technical standard ISO 17225-4. Based on the results, different wood blends were created to produce pellets, subsequently characterized according to ISO 17225-2. The analyses carried out on wood chips and pellets were bulk density, moisture, ash content, calorific value, elemental composition, chlorine, sulfur, and heavy metals. In addition, particles size was measured only for wood chips, while the length, diameter, mechanical durability, and ash melting behaviors were determined only for pellets. Some of the analyzed mixtures show acceptable values according to the current ISO technical standards. The values related to the apparent pellet bulk density and the durability test highlight that not all the mixtures are suitable to produce quality pellets. Results also represent a good starting point for future studies. [ABSTRACT FROM AUTHOR]

Environmental sustainability continues to attract global interest, especially due to the issue of climate change. The agri-food sector is considered a major contributor to climate change as processes and activities within the sector can negatively impact the environment. The recent changing dietary pattern towards increased vegetable consumption implies a consequent increase in production to meet demand. This study assessed the environmental performance of 1 kg of spinach/FU (Functional Unit) cultivated by different producers in Italy under integrated and organic farming systems. The life cycle assessment was used following the CML_IA impact assessment method. The data used was mainly primary, related to 2019/2020 (harvest period), and representative of the cultivation systems of central and southern Italy. From the results obtained, impact scores for central Italy were higher (e.g., for global warming 0.56 and 0.47 kg CO2 eq. for central and southern respectively). There was high variability among the scores obtained. However, no statistically significant differences were observed at a confidence level of 95% (p < 0.05). Integrated farming was also more impacting than organic for most categories (e.g., for global warming 0.20 kg CO2 eq. for integrated and 0.075 kg CO2 eq. for organic) in Cerignola, Puglia region. Emissions from fertilizer, pesticide, tillage, and combine harvesting were major contributors to impact shares. The results of this study will be helpful to ensure sustainable spinach production and consumption. [ABSTRACT FROM AUTHOR]

Ghana is an important cocoa producer and exporter and this production is of high economic importance. Increasing interest in the sustainable productions of cocoa/chocolate necessitated the need to assess the environmental impacts associated with the production of different chocolate variants (extra dark (EDC), dark (DC), milk (MC) and flavoured milk (FMC) in Ghana, including the identification of environmental hotspots for improvement. The life cycle assessment tool was used following the CML_IA and CED impact assessment methods. EDC had the lowest scores for most of the impact categories while FMC was most impactful. For Global Warming Potential (GWP), EDC and FMC were estimated to be 1.61 kg CO2 eq. and 4.21 kg CO2 eq., respectively. CED ranged from 1.44 × 102 to 1.50 × 102 MJ-eq. Chocolate manufacturing phase was generally more impactful than cocoa cultivation due to high emissions from milk and sugar production. The impact scores for 100 g packaged chocolate bar were the lowest in comparison to 300 g chocolate pouches and 12.5 g packaged chocolate strips. GWP for 100 g and 12.5 g were 0.20 kg CO2 eq. and 0.39 kg CO2 eq., respectively. Comparing different destination points for the manufactured chocolate, impact scores for the international destination were similar to those recorded for local destinations. Improvement options are suggested for all phases to ensure more sustainable chocolate production and distribution. [ABSTRACT FROM AUTHOR]

Agricultural activities in Europe cover half of the total area of the continent and are simultaneously a cause of environmental impact and victims of the same impact. Horticultural or fruit crops are considered highly intensive and often employ many crop inputs such as fertilizers, pesticides, and various materials. Strawberry falls into this group, and it has grown in acreage and production more than others globally. The aim of this study is to compare the environmental impact of two strawberry cultivation systems in central Italy, a mulched soil tunnel and a soilless tunnel system. The method used to assess the impact is LCA, widely applied in agriculture and supported by international standards. The data used are mainly primary, related to 2018, and representative of the cultivation systems of central Italy. For impact assessment, the method selected was the CML_IA baseline version. From the results obtained, the two systems show a similar impact per kg of strawberries produced (e.g., for global warming: 0.785 kg CO2 eq for soilless, 0.778 kg CO2 eq for mulched soil tunnel). Reduced differences can be observed for the use of crop inputs (greater for the tunnel) and the use of materials and technology (greater for soilless). The mitigation measures considered concern the replacement of the packaging (excluding plastic) and the growing medium of the soilless using perlite and compost from insect breeding. [ABSTRACT FROM AUTHOR]

Moisture content is the most relevant quality parameter for wood fuels. Effective and fast determination of moisture of incoming feedstock is essential in the management of bioenergy facilities. The availability of fast and reliable moisture meters based on innovative technologies simplifies this task. However, in Mediterranean conditions the inherent variability of wood fuels calls for a careful sampling strategy if representative results are required while facing acceptable analytic costs. The present study is aimed at measuring the fuel heterogeneity and defining accordingly the appropriate number of samples to be analyzed in order to get reliable moisture-content results. A total of 70 truckloads (about 2270 t of woodchips) were sampled during commercial operations in two different seasons. Five samples were collected from each load and measured with standard method and magnetic resonance gauge. Results show that the variability of moisture content is influenced by mixing of species and storage of biomass. Heterogeneity can vary greatly also within single truckloads, to the point that three samples are needed to achieve about 90% of estimates within the desired precision limits. In the case of larger lots, such as barge or ship loads, 20 samples can provide sufficient precision in most scenarios. [ABSTRACT FROM AUTHOR]

Near infrared spectroscopy is a non-invasive and rapid technique to support the analysis of solid biofuels such as woodchip, which is considered as a suitable alternative for energy production, according to European goals for fossil fuel reduction. Chemical and physical properties of the woodchip influence combustion performance, so the most discriminant parameters such as moisture and ash content and gross calorific value were constantly monitored. The aim of this study was the development of prediction models for these three parameters with the use of a hand-held NIR spectrometer. Laboratory analyses were carried out to evaluate the quality of several Italian samples from a power plant, and PLS regression models were developed to test prediction accuracy. Moreover, the most relevant wavelengths were investigated to discriminate chemical compounds influence. Prediction models demonstrated the capacity of handheld MicroNIR instrument to be considered a practical tool for solid biofuel quality assessment. As a consequence, NIR spectroscopy improved real-time analysis and made it suitable for practical and industrial applications, as supported by the recent Italian standard UNI/TS 11765. [ABSTRACT FROM AUTHOR]

In the latex production chain, rubber tree seeds (Hevea brasiliensis) represent an underutilized fraction with high potentialities, which can increase the sustainability of the whole process if rightly valorized. In the present study, the quality of all the fractions obtained from the rubber fruit were evaluated, with the aim to identify possible applications for their valorization with a circular economy perspective. Seeds from five different varieties of rubber tree were analyzed. Furthermore, a whole mass and energy balance was defined, which has allowed us to define hypothetical production scenarios. The obtained results show negligible differences among varieties. Shells and capsules have shown a composition similar to woody biomass, with high heating values (more than 16.5 MJ kg−1), low nitrogen content (below 0.5% on weight basis (w/w)) and reduced ash content (0.51% w/w and 1.90% w/w, respectively). Kernels were chemically extracted comparing two different solvents: n-hexane and ethanol. Both solvents showed similar extraction yields, i.e., 49% w/w and 46% w/w for n-hexane and ethanol, respectively. The resulting extraction flour was characterized by a high protein content (around 40% w/w) making it suitable for animal feeding. The rubber seed oil could be used in blends of different vegetable oils for biodiesel production. All this information is useful for improving the sustainability of the latex production chain and to assess the sustainability of possible bioenergy value chains. [ABSTRACT FROM AUTHOR]

The impact of heat production from vineyard pruning pellets has been evaluated in this paper. The study considers two different systems: the first one based on a mobile pelletizer (PS1) and the second one based on a stationary pellet plant (PS2). The analysis conducted is from "cradle to grave"; the systems under analysis includes pruning harvesting, transport to storage area, pelletization (mobile system or stationary production plant), transport to consumer and combustion. The functional unit selected is 1 MJ of thermal energy produced. The impact assessment calculation methods selected are Eco-Indicator 99 (H) LCA Food V2.103/Europe EI 99 H/A with a midpoint and endpoint approach, and ReCiPe Midpoint (H) V1.10. Considering Life Cycle Assessment results, Eco-indicator shows a total impact of 4.25 and 4.07 mPt for mobile pelletizer and stationary pellet plant, respectively. Considering the three damage categories, PS1 has values of 2.4% (Human Health), 3.8% (Ecosystem Quality) and 17.3% (Resources), more impactful than PS2. Contribution analysis shows that direct emissions are the major damage contributor, followed by wood ash management. From a comparison between the baseline scenario and a scenario with an avoided product (wood ash as a standard potassium fertilizer), PS1 and PS2 with an avoided product approach are 41% and 40% less impactful than in the baseline scenarios. When testing the impact of mobile pelletizer while considering transportation as a factor, a reduction of distance for pellet has been evaluated. Reducing the distance from 100 to 10 km, the total impact of PS1 almost reaches the impact of PS2 with a difference of around 4.6% (Eco-indicator 99 method). The most impactful processes are pellet production, direct emissions and ash management, while a less impactful factor is the electricity consumption. Transportation shows the lowest impact. Considering the ReCiPe impact calculation method with a midpoint approach, the results confirm what was found with Eco-indicator 99; the PS1 shows a slightly higher impact than PS2. [ABSTRACT FROM AUTHOR]

The determination of strawberry fruit quality through the traditional destructive lab techniques has some limitations related to the amplitude of the samples, the timing and the applicability along all phases of the supply chain. The aim of this study was to determine the main qualitative characteristics through traditional lab destructive techniques and Near Infrared Spectroscopy (NIR) in fruits of five strawberry genotypes. Principal Component Analysis (PCA) was applied to search for spectral differences among all the collected samples. A Partial Least Squares regression (PLS) technique was computed in order to predict the quality parameters of interest. The PLS model for the soluble solids content prediction was the best performing—in fact, it is a robust and reliable model and the validation values suggested possibilities for its use in quality applications. A suitable PLS model is also obtained for the firmness prediction—the validation values tend to worsen slightly but can still be accepted in screening applications. NIR spectroscopy represents an important alternative to destructive techniques, using the infrared region of the electromagnetic spectrum to investigate in a non-destructive way the chemical–physical properties of the samples, finding remarkable applications in the agro-food market. [ABSTRACT FROM AUTHOR]

Sunflower is one of the most important oilseed crops cultivated in the world for different purposes. In Italy, the production is mostly located in the central area, representing 70% of Italian production. The market demand for sunflower oil is higher than the national production. There is an increasing request for cold pressed sunflower oil for food application. The success of this activity is linked to a correct setting up and management of the production and supply chain with a valorization of products and by-products. To this aim, information is needed, and this paper is focused on the cultivation of sunflower in central Italy using suitable hybrids, as well as on the study of the cold extraction performance of the sunflower seed produced and the quality of by-products and residues. Results indicate that, on average, a range of about 1.0–1.5 t ha−1 of cold pressed oil and different amounts of by-products can be obtained. According to a proposed scenario, 30 ha cultivated with sunflower are needed to create a complete supply chain within the farm, avoiding many additional passages and maintaining all the value for the farmer. It is important to use suitable hybrids for obtaining good yield, but also the cold extraction performances are important because they also affect the quality of by-products and residues that can be valorized themselves to improve sustainability. [ABSTRACT FROM AUTHOR]