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Electronic and electrical products have deeply permeated all aspects of life, bringing a lot of convenience to individuals. However, the generation of e-waste after their end-of-life has resulted in serious risks both to the ecological environment and human health due to a lack of scientific and effective recycling and treatments. As two major types of components in e-waste, heavy metals and plastics can not only directly enter the human body via inhalation, ingestion, and skin absorption, but also accumulate in the human body indirectly through the food chain. E-waste is full of resources such as valuable metals like gold, silver, and copper that are often discarded incorrectly. Environmental and health risks derived from unregulated e-waste dismantling activities may be finally addressed through the application of advanced e-waste recycling technology, policy support of governments, legislation on recycling laws and regulations, and the improvement of public environmental protection awareness. This review gives a brief overview of the history, current situation, and future development of e-waste in China, which may provide novel thinking and approaches to e-waste management in the world. [ABSTRACT FROM AUTHOR]

Informal e-waste recycling can cause serious heavy metal(loid) pollution to nearby bodies of water, thereby increasing the risk of heavy metal exposure to local residents. This study investigates metal(loid) pollution levels in the Lianjiang River, which flows through Guiyu, an e-waste recycling town in Shantou, Guangdong. In 2009 and 2020, water samples from the Lianjiang River were taken, and the levels of 12 metal(loid)s (V, Cr, Mn, Sr, Ni, Cu, Zn, As, Se, Cd, Ba, and Pb) were measured by ICP-MS. In total, 380 valid questionnaires from Guiyu kindergarten children were selected to assess child health. Exposure health risks for children were calculated using two forms of exposure (dermal and inhalation) and statistical methods (multiple linear regression and Bayesian kernel machine regression—BKMR). The concentrations of Mn, Ni, Pb, and Cd in 2009 were significantly higher than those in 2020. The concentration of heavy metal(loid)s had been decreasing in 2020. The non-carcinogenic risk levels of the 12 metal(loid)s in both exposure routes were at an acceptable risk level. The average carcinogenic risk levels for As, Cr, Ni, Pb, and Cd exceeded the ILCRi <10–6 acceptable range. According to MLR, it was found that daily oral intake doses of Pb [β(95% CI): −0.949 (−1.596, −0.863), p < 0.001 and Se [β(95% CI): −0.911 (−1.888, −0.092), p = 0.031] were negatively associated with body mass index. A BKMR model was developed, through which the synergistic effects of co-exposure to 12 heavy metal(loid)s on growth and development indicators in children were analyzed. Concentrations of heavy metal(loid)s in rivers near e-waste recycling sites have been decreasing for 10 years. It was found that the growth and development of children are affected by the intake of heavy metal(loid)s in water. The reduction in heavy metal(loid) contamination in e-waste recycling areas needs to be continued, and concern about its impact on children's health must remain. [ABSTRACT FROM AUTHOR]

Novel brominated flame retardants (NBFRs) and dechlorane plus (DP) have been widely used as alternatives to traditional BFRs. However, little is known about the temporal trends of NBFR and DP pollution in e-waste recycling sites. In the current study, three composite sediment cores were collected from an e-waste-polluted pond located in a typical e-waste recycling site in South China to investigate the historical occurrence and composition of NBFRs and DP. The NBFRs and DP were detected in all layers of the sediment cores with concentration ranges of 5.71~180,895 and 4.95~109,847 ng/g dw, respectively. Except for 2,3,5,6-tetrabromo-p-xylene (pTBX) and 2,3,4,5,6-pentabromoethylbenzene (PBEB), all the NBFR compounds and DP showed a clear increasing trend from the bottom to top layers. These results implied the long-term and severe contamination of NBFRs and DP. Decabromodiphenyl ethane (DBDPE) was the most abundant NBFR with the contribution proportions of 58 ± 15%, 73 ± 15%, and 71 ± 18% in three sediment cores, followed by 1,2-bis(2,4,6-tribromophenoxy) ethane (BTBPE) and pentabromobenzene (HBB). The ratios of BTBPE/Octa-BDEs and DBDPE/Deca-BDEs varied from 0.12 to 60 and from 0.03 to 0.49, respectively, which had no clear increase trends with a decrease in sediment depth. As for DP, the fanti values (the concentration ratios of anti-DP to the sum of anti-DP and syn-DP) in sediment cores ranged from 0.41 to 0.83, almost falling in the range of those in DP technical products, suggesting that DP degradation did not occur in sediment cores. The environmental burdens of DBDPE, BTBPE, HBB, PBT, PBEB, pTBX, and DP were estimated to be 34.0, 5.67, 10.1, 0.02, 0.02, 0.01, and 34.8 kg, respectively. This work provides the first insight into the historical contamination status of NBFRs and DP in the sediments of an e-waste recycling site. [ABSTRACT FROM AUTHOR]

The European Green Deal's goals are anticipated to be fulfilled in large part thanks to the New Circular Economy Action Plan. It is believed that recycling materials will have a significant positive impact on the environment, particularly in terms of reducing greenhouse gas emissions and the impacts this will have on preventing climate change. Due to the complexity of the issue and its significant practical ramifications, the activity of Waste Electrical and Electronic Equipment (WEEE) collection networks is a subject of interest for researchers and managers, in accordance with the principles that recent laws have addressed in a large number of industrialized countries. The goal of this paper is to characterize and obtain composite materials using an injection process with a matrix of LDPE, PP, and HDPE, with up to a 10% addition of nonmetallic powders from PCBs and electronic parts from an integrated process of WEEE recycling. The composites present relevant thermal, electrical, and mechanical properties. Such composite materials, due to their relevant dielectric properties, may be further tested for applications in electromagnetic shielding at frequencies above 1 kHz, or for electromagnetic interference/electromagnetic compatibility (EMI/EMC and ESD) applications at lower frequencies due to their superior dielectric loss factor values, associated with relevant behaviors around exploitation temperatures, mainly for the electric, electronic, or automotive industries. [ABSTRACT FROM AUTHOR]

This study delves into the application of oxidative refining for the recovery and concentration of precious metals, namely palladium (Pd) and gold (Au), from waste electrical and electronic equipment by WEEE recycling, leveraging pyrometallurgical techniques. The primary objective is to optimize refining parameters, encompassing variations in gas pressure, temperature, and gas composition, to maximize the extraction and purification of precious metals from recycled materials. Through an array of comprehensive characterization techniques, encompassing microstructural analysis, elemental composition assessment, and metal concentration measurement, this study scrutinizes the potential of oxidative refining. The conclusive findings underscore the remarkable potential of oxidative refining in augmenting the efficiency and effectiveness of metal recovery from waste printed circuit boards (PCBs), with a pronounced emphasis on the concentration of Pd and Au. This research not only highlights the promise of oxidative refining but also concludes that optimizing process parameters, such as a N2/O2 mixed gas pressure of 4 L/min, a process time of 40 min, and a temperature of 1400 °C, is imperative for achieving the highest efficiency in metal recovery from electronic waste, especially precious metals like Pd and Au. It further contributes to the sustainable management of electronic waste and the strategic extraction of valuable precious metals. [ABSTRACT FROM AUTHOR]

The recycling of non-metallic printed circuit boards (NMPCB) as a filler in poly(vinyl chloride) (PVC) composite would help to encourage the use of waste NMPCB, thus, reducing some environmental concerns with regard to e-waste. The objective of this study was to comprehensively evaluate the effect of different interfacial agents, namely polypropylene grafted maleic anhydride (PP-g-MAH) and ϒ-aminopropyltriethoxy silane (ATPS) on the morphology and properties of PVC/NMPCB composites. A PVC/NMPCB composite was prepared by melt compounding with varying amounts of NMPCB ranging between 10, 20 and 30 wt.%. Fourier transform infrared spectroscopy–attenuated total reflectance (FTIR–ATR) analysis revealed the interactions between PVC and NMPCB when using both PP-g-MAH and ATPS interfacial agent. The properties and morphology of PVC/NMPCB composites were significantly dependent on the interfacial agent treated on the NMPCB surface. The phase morphology and mechanical properties of PVC/NMPCB composites (30 wt.% of NMPCB) were improved and the result also indicated that the higher compatibility of composites with ATPS as an interfacial agent led to our obtaining the maximum Young's modulus of 484 MPa. The dynamic mechanical analysis revealed the interaction at the interface, with the Tg shifting to a lower temperature in the presence of PP-g-MAH and strong interfacial adhesion noted with the improved Tg in the presence of the ATPS interfacial agent. Further evidence of the improved interaction was observed with the increment in density in the presence of ATPS when compared with PP-g-MAH in PVC/NMPCB composite. Hence, of the two interfacial agents, ATPS showed itself to be more effective when employed as an interfacial agent for NMPCB in PVC composite for industry. [ABSTRACT FROM AUTHOR]

Material Flow Cost Accounting (MFCA) is an environmental management accounting method that allocates costs to material and energy flows through a process, thereby enabling a simultaneous reduction in environmental impacts alongside an improvement in business and economic efficiency. This study illustrates the versatility of MFCA beyond its usual application to existing production and manufacturing processes. In this paper, MFCA is used to assess the financial viability of two emerging recycling technologies, IRETA2 (Development and Evaluation of Recycling Routes to Recover Tantalum from Electronic Waste) and ReComp (Development of an Innovative, Economically and Ecologically Sensible Recycling Method for Metallised ABS and PC/ABS Composite Waste). These two projects differ in their process structure. Whilst IRETA2 is a strictly linear recycling process, ReComp consists of two process streams, split according to the treatment of its two material fractions. For both projects, the lab-scale experimental results were used to develop an MFCA model of the recycling process scaled at each project partner's facilities. MFCA was utilised to calculate the projects' overall profit or loss, the impact of the final products' market conditions and processing rate (in the case of IRETA2), or machinery capacity (for ReComp) on the overall results. The results show that neither IRETA2 nor ReComp are financially viable based on the current output products' market value and quantity produced. However, through a sensitivity analysis, it is demonstrated that IRETA2 could become financially viable if the processing rate or market conditions were to improve. Additionally, ReComp could become financially viable if there was an increase in machine capacity. Finally, this paper also explores possible implications of MFCA when applied to emerging recycling technologies on EU policy and strategy, particularly those related to the EU Green Deal, such as extended producer responsibility and supply chain acts. [ABSTRACT FROM AUTHOR]

Industrial production generates aerosols of complex composition, including an ultrafine fraction. This is typical for mining and metallurgical industries, welding processes, and the production and recycling of electronics, batteries, etc. Since nano-sized particles are the most dangerous component of inhaled air, in this study we aimed to establish the impact of the chemical nature and dose of nanoparticles on their cytotoxicity. Suspensions of CuO, PbO, CdO, Fe2O3, NiO, SiO2, Mn3O4, and SeO nanoparticles were obtained by laser ablation. The experiments were conducted on outbred female albino rats. We carried out four series of a single intratracheal instillation of nanoparticles of different chemical natures at doses ranging from 0.2 to 0.5 mg per animal. Bronchoalveolar lavage was taken 24 h after the injection to assess its cytological and biochemical parameters. At a dose of 0.5 mg per animal, cytotoxicity in the series of nanoparticles changed as follows (in decreasing order): CuO NPs > PbO NPs > CdO NPs > NiO NPs > SiO2 NPs > Fe2O3 NPs. At a lower dose of 0.25 mg per animal, we observed a different pattern of cytotoxicity of the element oxides under study: NiO NPs > Mn3O4 NPs > CuO NPs > SeO NPs. We established that the cytotoxicity increased non-linearly with the increase in the dose of nanoparticles of the same chemical element (from 0 to 0.5 mg per animal). An increase in the levels of intracellular enzymes (amylase, AST, ALT, LDH) in the supernatant of the bronchoalveolar lavage fluid indicated a cytotoxic effect of nanoparticles. Thus, alterations in the cytological parameters of the bronchoalveolar lavage and the biochemical characteristics of the supernatant can be used to predict the danger of new nanomaterials based on their comparative assessment with the available tested samples of nanoparticles. [ABSTRACT FROM AUTHOR]

The article presents the results of a study on metallurgical sludge reduction using electronic waste such as Printed Circuit Boards (PCBs). Two aspects were taken into account when selecting such a reducer, namely the environmental aspect and the technological aspect. The research was an attempt to use waste metal-bearing material of which the effective management causes many problems from an environmental point of view. In the technological aspect, the specific chemical composition of this waste was taken into account. Its gasification yields significant amounts of hydrocarbons, which are excellent reducing agents in such process. The separation of these compounds may additionally cause the mixing of the molten slag, which should result in faster separation of the formed metal droplets and the molten slag. In the case of the fragmented PCB (Printed Circuit Board) reducer used in this study, a significant degree of copper removal was achieved, as much as 92%. As the reduction-process time increased, the degree of copper removal also increased. For the 1 h process, the average value of copper removal was 60%, and for the 4.5 h process it was over 70%. The case was the same with the addition of reductant: as the amount of reductant added to the process increased, an increase in copper removal was observed. With the addition of 30 g of the reducing agent (per 65 g of slag), the degree of copper removal was over 90%. [ABSTRACT FROM AUTHOR]

The circular business model (CBM) is one of the main building blocks of circular economy (CE), and recycling is one of the main strategies for achieving it. CBM literature is currently evolving, and recycling-oriented discussion has been found in a scattered manner. This review article aims to identify critical components of the recycling-focused business model in CE and evaluate potential business and research opportunities in the area. Data collection was undertaken from the Web of Science (WoS) core collection and ScienceDirect database. Results of the study showed that efficiency of municipal solid waste management, reporting mechanism of recyclers cost of recycled materials, the establishment of a plastic hub, implementation of extended producer responsibility, strategic partnership, incentives, and product design were highlighted as critical requirements for efficient recycling operated business models, especially for waste solar PV panels, e-waste, textile waste, and vehicles and battery sector. It also identified the benefits of using recycled materials in reducing carbon footprint, energy consumption, and achieving low environmental impact. Three-dimensional printing, sensor-based RFID tags, digital twins, additive manufacturing, Industry 4.0, and the Internet of Things (IoT) were found as state-of-the-art technological innovations applied to recycling-oriented circular business models. This article provides critical practical solutions for new business model development and indicates vital future research directions along with a conceptual framework development, which would be helpful for policymakers, business entities, and research academics. [ABSTRACT FROM AUTHOR]

Since its inception, the electronics industry has mass-produced equipment. The fast evolution of electronic technologies made obsolete the entire generation of products and even technologies. Until the government issued regulations and guidelines on how to address the issue of reuse of obsolete electronic equipment, with special regard to the ones still operating (e.g., give it to family/friends, donate to charity, or sell to individuals or recycling companies), most of it was thrown out with usual rubbish, with a destructive effect on the environment. This paper presents the design techniques and methods for revaluation of obsolete vacuum tube analog receivers, with a focus on the manufacturing steps of a high-performance receiver. The choice of receiver type is not accidental at all, since tube technology is still a real success among audiophiles many providers offer vacuum tube amplifiers at considerably high prices. The redesign implied the original FM unit replacement with a DSP-based AM/FM tuner while the AM RF vacuum tube section has been preserved with the original architecture to allow the reception of the broadcast stations for the long-wave band and the alternative operation with the silicon tuner for the medium-wave and short-wave bands. The electrical performances of the modified receiver in terms of reliability, sensitivity, selectivity, and distortions on the reception chain are clearly superior to the original one, while the power consumption of the RF section is reduced more than 10 times from 11.5 W–15.5 W to 1 W. Last, but not least important, the proposed solution implied the use of few additional parts and resources and extended significantly the lifetime of the original vacuum tubes receiver. The work has been developed to serve as an example of how obsolete electronic equipment can be redesigned and reused avoiding its complete recycling or even worse, its disposal with usual rubbish. It has been imagined and performed as the initial step in launching a professional student contest on the reuse/redesign of obsolete equipment aimed at raising awareness regarding the issue of pollution with e-waste amongst students from the electronic departments of Romanian technical universities. [ABSTRACT FROM AUTHOR]

In the field of electronics manufacturing, electronic component classification facilitates the management and recycling of the functional and valuable electronic components in electronic waste. Current electronic component classification methods are mainly based on deep learning, which requires a large number of samples to train the model. Owing to the wide variety of electronic components, collecting datasets is a time-consuming and laborious process. This study proposed a Siamese network-based classification method to solve the electronic component classification problem for a few samples. First, an improved visual geometry group 16 (VGG-16) model was proposed as the feature extraction part of the Siamese neural network to improve the recognition performance of the model under small samples. Then, a novel channel correlation loss function that allows the model to learn the correlation between different channels in the feature map was designed to further improve the generalization performance of the model. Finally, the nearest neighbor algorithm was used to complete the classification work. The experimental results show that the proposed method can achieve high classification accuracy under small sample conditions and is robust for electronic components with similar appearances. This improves the classification quality of electronic components and reduces the training sample collection cost. [ABSTRACT FROM AUTHOR]

This commentary is an investigation of sources of lead (Pb) exposure in West Africa. Pb is generally acknowledged as one of the most widespread environmental health hazards in West Africa, and there is heightened concern over adverse health effects at various levels of exposure (at doses once considered safe) in the West African region. A literature review for the possible health implications of Pb exposure on human health showed nervous system dysfunction, anemia, and potential cognitive diseases as the major health issues among children, while adults were found to suffer more from cardiovascular dysfunction, neurological decline, and reproductive diseases. Despite a decline in blood lead levels (BLLs), lead exposure continues to be a major public health concern as no level of Pb exposure can be considered safe. Moreover, lowering BLLs entails identifying various lead sources such as gasoline emissions, leaded paint, canned foods, and beverages, as well as plausible biological pathways of lead exposure and response. However, only countries such as Nigeria and Ghana have extensive research available regarding the different sources of Pb exposure. Further, it is not apparent which country is affected the most by Pb exposure. Therefore, this commentary was aimed to explore different literature sources to describe and list the different sources of Pb exposure in 15 West African countries. The findings indicated water, food, and occupational exposure as the major sources of Pb exposure in the region. People with occupations such as e-waste and Pb acid battery recycling, auto mechanics, fuel attending, welding, electronic repairing, farming/spraying, and mining were found to be at immediate risk. Tobacco, spices and paints constituted additional potential sources of exposure. For residents living near landfills or urban area, the major sources of Pb exposure were soil, air, and dust particles. The review revealed a vast research gap on the sources and implications of Pb exposure. Exposure to Pb could further increase due to uncontrolled traffic, urban growth, inadequate urban planning, and the inadequate enforcement of regulations. Therefore, more extensive research on the changing trends of Pb exposure among West African populations is needed. [ABSTRACT FROM AUTHOR]

Waste-derived materials obtained from the recovery and recycling of electronic waste (e-waste) such as batteries and printed circuit boards have attracted enormous attention from academia and industry in recent years, especially due to their eco-friendly nature and the massive increment in e-waste due to technological development. Several investigations in the literature have covered the advances achieved so far. Meanwhile, photocatalytic applications are especially of interest since they maintain mutual benefits and can be used for H2 production from solar water splitting based on semiconductor processing as a proper environmentally friendly technique for solar energy conversion. In addition, they can be utilized to degrade a variety of organic and non-organic contaminations. Nonetheless, to the best of the authors' knowledge, there has not been any comprehensive review that has specifically been focused on e-waste-derived photocatalytic materials. In this regard, the present work is dedicated to thoroughly discussing the related mechanisms, strategies, and methods, as well as the various possible photocatalysts synthesized from e-wastes with some critiques in this field. This brief overview can introduce modern technologies and promising possibilities for e-waste valorization, photocatalytic processes, and new photocatalytic degradation methods of eco-friendly nature. This paper discusses various e-waste-obtained photocatalytic materials, synthesis procedures, and applications, as well as several types of e-waste, derived materials such as TiO2, ZnO, indium tin oxide, and a variety of sulfide- and ferrite-based photocatalytic materials. [ABSTRACT FROM AUTHOR]

E-waste generation has become a major environmental issue worldwide. Heavy metals (HMs) in e-waste can be released during inappropriate recycling processes. While their pollution characteristics have been studied, the migration and transformation of different multi-metal fractions in soil–plant system of e-waste dismantling sites is still unclear. In this study, pot experiments were conducted to investigate the migration and transformation of different multi-metal fractions (Cu, Pb, Zn and Al) in the soil–plant system using two Chinese cabbage cultivars (heavy metals low-accumulated variety of Z1 and non-low-accumulated Z2) treated with or without biochar. The result showed that the acid-soluble fraction of Cu, Pb, Zn and Al in soil decreased by 5.5%, 55.7%, 7.8% and 21.3%, but the residual fraction (ResF) of them increased by 48.5%, 1.8%, 30.9% and 43.1%, respectively, when treated with biochar and plants, compared to that of the blank soil (CK). In addition, Pb mainly existed as a reducible fraction, whereas Cu existed as an oxidisable fraction. Biochar combined with plants significantly increased the ResF of multi-metals, which reduced the migration ability of Pb among all other metals. The relative amount of labelled 13C in the soil of Z1 was higher than that of Z2 (25.4 fold); among them, the Gram-negative bacteria (18-1ω9c, 18-1ω7c) and fungi (18-2ω6c) were significantly labelled in the Z1-treated soil, and have high correlation with HM migration and transformation. In addition, Gemmatimonadete were significantly positive in the acid-soluble fraction of HMs, whereas Ascomycota mostly contributed to the immobilisation of HMs. Therefore, the distribution of fractions rather than the heavy metal type plays an important role in the HM migration in the soil–plant system of e-waste dismantling sites. [ABSTRACT FROM AUTHOR]

Successful recycling of electronic waste requires accurate separation of materials such as plastics, PCBs and electronic components on PCBs (capacitors, transistors, etc.). This article therefore proposes a vision approach based on a combination of 3D and HSI data, relying on the mutual support of the datasets to compensate existing weaknesses when using single 3D- and HSI-Sensors. The combined dataset serves as a basis for the extraction of geometric and spectral features. The classification is performed and evaluated based on these extracted features which are exploited through rules. The efficiency of the proposed approach is demonstrated using real electronic waste and leads to convincing results with an overall accuracy (OA) of 98.24%. To illustrate that the addition of 3D data has added value, a comparison is also performed with an SVM classification based only on hyperspectral data. [ABSTRACT FROM AUTHOR]

Reverse logistics include all operations related to the reuse of products and materials. In this study, we focus on collection, which is the first operation of reverse logistics, and on the strength of using the sensor data and the concept of Industry 4.0. Previously, the collection activities of electronic wastes (e-wastes) was conducted by a fixed schedule without consideration of the fulfillment level of the collection boxes. However, due to the progress of IoT(internet of things) technology and sensor technology, it is possible to consider the fulfillment level of the collection boxes in order to make the collection schedule. To utilize the sensor data and IoT technology in reverse logistics, a collection signal algorithm is required to treat the rate of fulfilment of collection boxes. However, the collection signal algorithm for the disposal of small and medium (S&M)-sized e-wastes have not yet been developed in South Korea. This study uses a collection box to develop the collection algorithm based on an experimental design method with multiple sensors. The proposed algorithm can be utilized to solve the current collection problems and to save logistics costs. Furthermore, proper collection of e-wastes will lead to more recycling activities, which can further create and sustain a safer environment on Earth. [ABSTRACT FROM AUTHOR]

Informal recycling of electronics in the developing world has emerged as a new global environmental concern. The primary approach to address this problem has been command-and-control policies that ban informal recycling and international trade in electronic scrap. These bans are difficult to enforce and also have negative effects by reducing reuse of electronics, and employment for people in poverty. An alternate approach is to link informal and formal sectors so as to maintain economic activity while mitigating environmental damages. This article explores the idea of an interface organization that purchases components and waste from informal dismantlers and passes them on to formal processors. Environmental, economic and social implications of interface organizations are discussed. The main environmental questions to resolve are what e-scrap components should be targeted by the interface organization, i.e., circuit boards, wires, and/or plastic parts. Economically, when formal recycling is more profitable (e.g., for circuit boards), the interface organization is revenue positive. However, price subsidies are needed for copper wires and residual waste to incentivize informal dismantlers to turn in for formal processing. Socially, the potential for corruption and gaming of the system is critical and needs to be addressed. [ABSTRACT FROM AUTHOR]

E-waste and end-of-life vehicles (ELVs) are fast-growing waste streams in the EU and beyond that require specific collection and treatment activities to avoid environmental pollution and resource depletion fed by the linear economy model. This paper aims to investigate the links between e-waste and ELVs streams and the circular economy approach of the EU. Romania is examined as a relevant case study for the central and eastern European Region regarding: (i) the current e-waste and ELVs management deficiencies and challenges in line with circular economy principles promoted by EU; (ii) analysis of E-waste and ELVs flows data; and (iii) best circular economy initiatives related to e-waste and ELVs in Romania, including the opportunity to create new jobs in treatment activities that the simple operations from the first stages of e-waste recycling can produce locally and regionally in Romania. This work points out the current knowledge gaps and future research directions for these special waste streams in Romania and beyond. [ABSTRACT FROM AUTHOR]

Informal recycling of electronic waste leads to soil contamination that can impact human health. To accurately assess exposure to potentially toxic elements (PTE) in soil it is necessary to consider their bioavailability through ingestion, inhalation and dermal contact. However, bioaccessibility tests that estimate dermal absorption following adhesion of contaminated soil particles to skin are not well established. In this study the concentrations of As, Cd, Cr, Cu, Fe, Mn, Ni, Pb and Zn were estimated in the <45 µm particle size fraction of a bulk composite soil from an e-waste recycling site using five different artificial sweat formulations. Extractions were performed at temperatures ranging from 17 to 47 °C to investigate the effect of ambient temperature on bioaccessibility. Results obtained using the different artificial sweats were not consistent with one another. In particular, the NIHS 96-10 formulation solubilized larger amounts of analytes (ranging from 6.3 times the next most effective extractant for Cu to 1700 times the next most effective for Pb). There was a general increase in release of PTE with increasing temperature, except for As. Although trends varied between analytes and formulations, this highlights the need to consider ambient temperature when estimating dermal bioaccessibility of PTE in soil. [ABSTRACT FROM AUTHOR]

Currently, less than 20% of electronic waste (E-waste) produced in the U.S. is recycled. To improve the recycling rate of E-waste, the study aimed to: (1) identify the major plastics found within electronic shredder residue (ESR), (2) design solvents and processing conditions capable of separating out 90% of the plastic in ESR, and (3) estimate the energy efficiency of the solvent-based process developed. Preliminary screening showed 25 wt.% of the ESR was composed of plastics, with two polymers dominating the sorted plastic fraction—polystyrene (PS, 40 wt.%) and acrylonitrile butadiene styrene (ABS, 25 wt.%). Subsequently, solvents and anti-solvents were screened using Hansen Solubility Parameter Theory for PS, ABS, and ESR dissolution. The pre-screening results showed dichloromethane (DCM) and tetrahydrofuran (THF) as the most effective solvents for PS and ABS, with methanol (MeOH) and ethylene glycol (EG) as the most effective anti-solvents. By optimizing the dissolution time and the solvents used, the highest polymer dissolution yield (99 wt.%) was achieved using DCM for 48 h. Both MeOH and EG precipitated 71 wt.% of the polymer fraction of ESR. EG removed more phosphorus containing flame retardants (94 wt.%) than MeOH (69 wt.%). Energy analysis indicated that the solvent-based processes could save 25–60% of the embodied energy for PS and ABS. Characterization showed that the solvent-based processing could preserve the high molecular weight fraction of the polymers while removing flame retardants at the same time. The results from this study prove the potential of solvent-based processing to produce secondary plastic materials from E-waste for cross-industry reuse. [ABSTRACT FROM AUTHOR]

In the literature of information theory and fuzzy set doctrine, there exist various prominent measures of divergence; each possesses its own merits, demerits, and disciplines of applications. Divergence measure is a tool to compute the discrimination between two objects. Particularly, the idea of divergence measure for fuzzy sets is significant since it has applications in several areas viz., process control, decision making, image segmentation, and pattern recognition. In this paper, some new fuzzy divergence measures, which are generalizations of probabilistic divergence measures are introduced. Next, we review two different generalizations of the following measures. Firstly, directed divergence (Kullback–Leibler or Jeffrey invariant) and secondly, Jensen difference divergence, based on these measures, we develop a class of unified divergence measures for fuzzy sets (FSs). Then, a method based on divergence measure for fuzzy sets (FSs) is proposed to evaluate the multi-criteria decision-making (MCDM) problems under the fuzzy atmosphere. Lastly, an illustrative example of the recycling job selection problem of sustainable planning of the e-waste is presented to demonstrate the reasonableness and usefulness of the developed method. [ABSTRACT FROM AUTHOR]

Due to the advanced technologies, governments today are facing more challenges in the governance field than ever before. One of the serious issues is how to develop relationships with younger generations. As a purpose of smart governance, sustainability emphasizes the responsibility of government for building a stable association with future generations. This study is devoted to promoting sustainability in the smart governance field through e-government services. It seeks to understand the situation of local e-government use in a special group of future generations: undergraduate students. In order to achieve this objective, this research conducts a case study in Chongqing, the only inland municipality in China. Drawing upon data from a sample of 1046 respondents in 2019, the findings reveal that the way to interact with the government via e-government is by receiving a wide range of undergraduate students at the local level. In this sense, the role of e-government in linking government and younger generations is larger and more significant than previously estimated. Additionally, the results witness a rise of social media in e-government services among younger generations. Based on all these findings, it offers practical suggestions for the future development of e-government services in China. [ABSTRACT FROM AUTHOR]

Quantitatively evaluating the spatial characteristics of regional e-retailing economy linkages is of great significance for clarifying the spatial organization of regional e-retailing economies, and promoting regional coordinated development. However, due to the lack of study data, it is difficult toconduct quantitative research on these regional e-retailing economic linkages. Taking advantage of emerging new data sources, the depth and breadth of related research cannow be improved. This paper considers 64 county-level economic areas in Zhejiang Province as network nodes.A revised gravity model was used to measure the intensity of the e-retailing economic linkage in 2016,based upon the e-retailing data provided by the Department of Commerce of Zhejiang Province, China. On this basis, the geographic information system (GIS) tool, a model-potential method and a social network, were used to analyze the spatial features of the e-retail economic linkages at the countylevel in Zhejiang Province. The results showed that the spatial polarization of the economic linkage pattern emerged as prominent, with the overall difference and east-west gradient difference between counties proving significant. In addition, the major linking partners of most regions were relatively singular, and a problem of vulnerability in e-retail economic development was shown.Secondly, the southwest region of Zhejiang Province was an important obstacle in the integration process of regional e-retail economy, through analyzing the connection scope of e-retailing economics. Thirdly, the central Zhejiang subgroupwas a key plate connecting east and west, which plays an importantlinking role in the development of regional equalizationwhen we analyzethe cohesive subgroup pattern. Inspired by this, we hypothesized that a microscopic analysis results of Zhejiang Province could provide some enlightenment for the balanced and integrated development of China's regional e-retailing economy. [ABSTRACT FROM AUTHOR]

Car electronics form a large but poorly utilized source for secondary critical raw materials (CRMs). To capitalize on this potential, it is necessary to understand the mechanism in which car electronics enter and exit the vehicle fleet over time. We analyze the historical penetration of selected car electronic control systems (ECS) in 65,475 car models sold in the past 14 years by means of statistical learning. We find that the historical penetration of ECS tends to follow S-shaped curves, however with substantial variations in penetration speed and saturation level. Although electronic functions are increasing rapidly, comfort-related ECS tend to remain below 40% penetration even after 14 years on the market. In contrast, safety regulations lead to rapid ECS penetration approaching 100%, while environmental emission regulations seem to indirectly push related ECS to a medium penetration level (e.g., growing to 60% after six years). The trend towards integration of individual ECS poses long-term challenges for car electronics dismantling and recycling. Monitoring the ECS embedded in new cars, such as carried out in this study, can inform timely updates for such strategies. The results also provide a framework for developing scenarios to identify related future CRM stocks and flows. [ABSTRACT FROM AUTHOR]