Search

Clouds are notoriously difficult to simulate. Here, we separate and quantify the impact of Pacific climate modes on total cloud cover (TCC) variability, using reliable satellite observations together with state-of-the art reanalysis outputs, over the 1979–2020 period. The two most prominent modes of annual TCC variability show intense loadings over the Pacific basin and explain most of the variance in what could be considered the "signal" in satellite TCC data. Canonical correlation analysis (CCA) provides coupled TCC—sea surface temperature (SST) patterns that are linked to the Eastern Pacific (EP) ElNiño—Southern Oscillation (ENSO) and the Central Pacific (CP) ENSO in a physically consistent manner. The two ENSO modes dominate global coupled SST–TCC variability with the footprint of the CP ENSO explaining roughly half of the variance induced by the EP ENSO among these coupled fields. Both the EP and the CP ENSO exert an influence on Pacific decadal TCC variability. The impact of both ENSO modes on global total cloud cover variability is amplified by two positive feedbacks. These results could be used as a reference for model investigations on future projections of coupled TCC—SST variability responses to the CP and the EP ENSO. [ABSTRACT FROM AUTHOR]

The ability of TiO2 to generate reactive oxygen species under UV radiation makes it an efficient candidate in antimicrobial studies. In this context, the preparation of TiO2 microparticles coated with Ca- and Cu-based composite layers over which Cu(II), Cu(I), and Cu(0) species were identified is presented here. The obtained materials were characterized by a wide range of analytical methods, such as X-ray diffraction, electron microscopy (TEM, SEM), X-ray photoelectron (XPS), and UV-VIS spectroscopy. The antimicrobial efficiency was evaluated using qualitative and quantitative standard methods and standard clinical microbial strains. A significant aspect of this composite is that the antimicrobial properties were evidenced both in the presence and absence of the light, as result of competition between photo and electrical effects. However, the antibacterial effect was similar in darkness and light for all samples. Because no photocatalytic properties were found in the absence of copper, the results sustain the antibacterial effect of the electric field (generated by the electrostatic potential of the composite layer) both under the dark and in light conditions. In this way, the composite layers supported on the TiO2 microparticles' surface can offer continuous antibacterial protection and do not require the presence of a permanent light source for activation. However, the antimicrobial effect in the dark is more significant and is considered to be the result of the electric field effect generated on the composite layer. [ABSTRACT FROM AUTHOR]

The variability of stable oxygen isotope ratios (δ18O) from Greenland ice cores is commonly linked to changes in local climate and associated teleconnection patterns. In this respect, in this study we investigate ice core δ18O variability from a synoptic scale perspective to assess the potential of such records as proxies for extreme climate variability and associated weather patterns. We show that positive (negative) δ18O anomalies in three southern and central Greenland ice cores are associated with relatively high (low) Rossby Wave Breaking (RWB) activity in the North Atlantic region. Both cyclonic and anticyclonic RWB patterns associated with high δ18O show filaments of strong moisture transport from the Atlantic Ocean towards Greenland. During such events, warm and wet conditions are recorded over southern, western and central part of Greenland. In the same time the cyclonic and anticyclonic RWB patterns show enhanced southward advection of cold polar air masses on their eastern side, leading to extreme cold conditions over Europe. The association between high δ18O winters in Greenland ice cores and extremely cold winters over Europe is partly explained by the modulation of the RWB frequency by the tropical Atlantic sea surface temperature forcing, as shown in recent modeling studies. We argue that δ18O from Greenland ice cores can be used as a proxy for RWB activity in the Atlantic European region and associated extreme weather and climate anomalies. [ABSTRACT FROM AUTHOR]

Preventing and controlling the spread of multidrug-resistant (MDR) bacteria implicated in healthcare-associated infections is the greatest challenge of the health systems. In recent decades, research has shown the need for passive antibacterial protection of surfaces in order to reduce the microbial load and microbial biofilm development, frequently associated with transmission of infections. The aim of the present study is to analyze the efficiency of photocatalytic antimicrobial protection methods of surfaces using the new photocatalytic paint activated by light in the visible spectrum. The new composition is characterized by a wide range of analytical methods, such as UV-VIS spectroscopy, electron microscopy (SEM), X-ray powder diffraction (PXRD) or X-ray photoelectron spectroscopy (XPS). The photocatalytic activity in the UV-A was compared with the one in the visible light spectrum using an internal method developed on the basis of DIN 52980: 2008-10 standard and ISO 10678—2010 standard. Migration of metal ions in the composition was tested based on SR EN1186-3: 2003 standard. The new photocatalytic antimicrobial method uses a type of photocatalytic paint that is active in the visible spectral range and generates reactive oxygen species with inhibitory effect against all tested microbial strains. [ABSTRACT FROM AUTHOR]

The aim of this study is to investigate the stable isotope composition of precipitation and river water from the northeastern part of Romania. For this study, we collected monthly samples (for variable periods of time) of precipitation from six stations, and river water from three stations, between March 2012 and December 2017. The precipitation in the area is sourced mainly from the Atlantic Ocean, and secondarily from the Black Sea, local recycling being important especially in summer. We found that the seasonal δ18O in precipitation is in agreement with the seasonal temperature variability, as shown by the significant correlation coefficient between the two variables (r = 0.77), which indicates that the temperature has an important role in the δ18O variability in precipitation water in this region. The local meteoric water line in the northeastern part of Romania is defined by the equation δ2H = 7.80 × δ18O + 7.47, (r2 = 0.99, n = 121). The results presented in this study emphasize that the δ18O (and δ2H) and d-excess variability are strongly influenced by temperature, precipitation and the prevailing large-scale atmospheric circulation. [ABSTRACT FROM AUTHOR]

Falling between seasonal cycle variability and the impact of local drivers, the sea level in the Red Sea and Gulf of Aden has been given less consideration, especially with large-scale modes. With multiple decades of satellite altimetry observations combined with good spatial resolution, the time has come for diagnosis of the impact of large-scale modes on the sea level in those important semi-enclosed basins. While the annual cycle of sea level appeared as a dominant cycle using spectral analysis, the semi-annual one was also found, although much weaker. The first empirical orthogonal function mode explained, on average, about 65% of the total variance throughout the seasons, while their principal components clearly captured the strong La Niña event (1999–2001) in all seasons. The sea level showed a strong positive relation with positive phase El Niño Southern Oscillation in all seasons and a strong negative relation with East Atlantic/West Russia during winter and spring over the study period (1993–2017). We show that the unusually stronger easterly winds that are displaced north of the equator generate an upwelling area near the Sumatra coast and they drive both warm surface and deep-water masses toward the West Indian Ocean and Arabian Sea, rising sea level over the Red Sea and Gulf of Aden. This process could explain the increase of sea level in the basin during the positive phase of El Niño Southern Oscillation events. [ABSTRACT FROM AUTHOR]