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Stable isotopes of precipitation play an important role in understanding hydrological and climatic processes of arid inland river basins. In order to better understand the difference of regional water cycle and precipitation patterns, precipitation samples were collected in Shiyang River Basin from June 2018 to May 2020, and spatial and temporal variation characteristics of stable isotopes in precipitation and their relationships with meteorological factors were discussed. The results showed that stable isotopes in precipitation showed seasonal variation characteristics, that δ2H and δ18O values were higher in summer and autumn and lower in winter and spring, and d-excess values were higher in spring and autumn and lower in winter and summer. Slopes and intercepts of the local meteoric water lines gradually increased with elevation increasing. δ18O significantly showed a positive correlation with temperature but a negative correlation with precipitation in summer. Contrary to below 15 hPa, δ18O significantly showed a negative correlation with water vapor pressure above 15 hPa. Due to the influence of meteorological factors, there are significant differences in stable isotopes of precipitation in arid inland river basins, which were more influenced by local moisture recycling in upstream area but by below-cloud secondary evaporation in mid-downstream area. [ABSTRACT FROM AUTHOR]

Studying the spatial and temporal distribution of soil organic carbon (SOC) content in high-altitude mountainous areas and its correlation with soil nutrients provides a basis for understanding soil carbon stocks and the factors affecting the local carbon cycle. Based on soil samples collected from a semi-sunny slope and semi-shady slope in the subalpine shrub zone of the eastern Qilian Mountains from May to October 2019, we studied the temporal and spatial changes in SOC and soil available nutrients and their relationships. The results showed that SOC content and soil nutrients were greater on the semi-shady slope than on the semi-sunny slope during the growing season and decreased with an increase in soil depth in different slope directions, showing obvious surface aggregation. The soil available nitrogen (SAN) content was consistent with the SOC content and exhibited greater synchronization. SOC was significantly positively correlated with soil available nutrients in the study area during the whole growing season. However, the correlation between SOC and soil nutrients varied among the different soil layers and slope orientations. The SOC content was more obviously correlated with the SAN content in the soil layer at a depth of 30–40 cm (r = 0.67, p < 0.05) on the semi-shady slope. The SOC content was more obviously correlated with soil-available phosphorus (SAP) content in the soil layer at a depth of 30–40 cm (r = 0.57) on the semi-sunny slop. The SOC content was more obviously correlated with the SAP content in the soil layer at a depth of 60–70 cm (r = 0.55) and with the soil-available potassium (SAK) content in the soil layer at a depth of 70–80 cm (r = 0.84) on the semi-sunny slope. [ABSTRACT FROM AUTHOR]

Fractionation of stable isotopes in precipitation runs through the water cycle, and deuterium excess is a second-order parameter linking water-stable oxygen and hydrogen isotopes. It is strongly influenced by under-cloud evaporation in unsaturated air, especially in arid climates. Based on the improved Stewart model, this study used 670 precipitation stable isotope data and measured meteorological element data from 11 sampling points from January 2018 to September 2019 to verify the existence of sub-cloud secondary evaporation in the Shiyang river basin and quantitatively calculate the intensity of sub-cloud secondary evaporation and its influence on precipitation stable isotopes. The study used the vapor flux and the improved Lagrangian model to track the moisture source of precipitation and analyze the influence of the moisture source of different paths on the stable isotopes of precipitation. Therefore, this study is helpful to understand the evapotranspiration loss mechanism and recharge mechanism of moisture in the watershed. The results showed that there is sub-cloud secondary evaporation in the Shiyang River Basin, and from the seasonal scale, the sub-cloud secondary evaporation is stronger in spring and summer, but weaker in autumn and winter, which makes heavy isotopes enriched in spring and summer and depleted in autumn and winter. From the perspective of spatial distribution, the sub-cloud secondary evaporation is stronger in the midstream and downstream of the Shiyang river, resulting in more enrichment of heavy isotopes. In the vertical direction, the sub-cloud secondary evaporation at 850–700 hPa is the strongest, which enriches the heavy isotope in this layer and reduces the deuterium excess. In addition, the main moisture source of precipitation in the Shiyang River Basin is the westerly air mass, and the mid and high-latitude land sources contribute more moisture to the precipitation. However, the supply of the sea source is very limited, which makes the deuterium excess of precipitation higher and does not show regional consistency and seasonality well. [ABSTRACT FROM AUTHOR]

Atmospheric precipitation is an important part of the water circle in an inland basin. Based on the analytical results of 149 precipitation samples and corresponding surface meteorological data collected at four sampling sites (Lenglong, Ningchang, Huajian and Xiying) at different elevations in the Xiying river basin on the north slope of Qilian Mountains from May to September 2017, the sub-cloud evaporation in precipitation and its controlling factors are analyzed by the Stewart model. The results show that sub-cloud evaporation led to d-excess value in precipitation decrease and d-excess variation from cloud-base to near surface (Δd) increase with decreasing altitude. The remaining evaporation fraction of raindrop (f) decreases with decreasing altitude. The difference of underlying surface led to a difference change of f and Δd in the Xiying sampling site. For every 1% increase in raindrop evaporation, d-excess value in precipitation decreased by about 0.99‰. In an environment of high relative humidity and low temperature, the slope of the linear relationship between f and Δd is less than 0.99. In contrast, in the environment of low relative humidity and high temperature, the slope is higher than 0.99. In this study, set constant raindrop diameter may affect the calculation accuracy. The Stewart model could have different parameter requirements in different study areas. This research is helpful to understand water cycle and land–atmosphere interactions in Qilian Mountains. [ABSTRACT FROM AUTHOR]

The Shiyang River Basin is located at the edge of the monsoon wind system of South and Southeast Asia. The hydrochemical characteristics of precipitation are influenced by both monsoon and arid regions. The regression analysis method, comparative analysis, neutralization factor (NF), enrichment factor (EF) and HYSPLIT4 were used to analyze the precipitation samples collected from the upper reaches of the Shiyang River from October 2016 to October 2017. In order to study the hydrochemical characteristics and ion sources of precipitation in this basin. The results, as discussed in this paper, show that the precipitation in the upper reaches of the Shiyang River is mildly alkaline all year round while the neutralization ability of Ca2+ and NH4+ in precipitation is strong. The ion concentration was higher in the dry season than that in the wet season, but the concentration of NH4+ was higher in summer. Furthermore, as the altitude increased, the electrical conductivity (EC) of the precipitation decreased gradually. Influenced by precipitation and rainy days, the wet deposition of nitrogen (N) and sulfur (S) was higher in the wet season than that during the dry season, and the wet deposition gradually increased with the elevation. In precipitation, the earth's crust is a major source of Ca2+, K+ and Mg2+, the ocean is a major source of Cl−, the ocean and the earth's crust are the sources of Na+, human activities are the main sources of SO42−, NO3− and NH4+, the amount of F− is very small, its sources are natural and human activities. Water vapor in precipitation mainly comes from westerly air mass circulation and monsoon circulation while the particles come mainly from the earth's crust. [ABSTRACT FROM AUTHOR]