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Coalbed Methane (CBM) accounts for about 5% of China's domestic gas supply, which has been regarded as one of the most promising energies for alleviating the energy supply–demand imbalance. Deep CBM reservoirs have the characteristics of low permeability, low porosity, and low water saturation, which easily experience reservoir damage during the drilling process, further affecting the gas productivity. Based on the analysis of coal mineral composition, pore structure distribution, and the surface micromorphology change in coal surface before and after hydration, a possible mechanism for CBM formation damage was revealed. It was found that the damage caused by drilling fluid intrusion can be divided into three stages: stripping, migration, and plugging. Based on the water-sensitive, acid-sensitive, and stress-sensitive evaluation tests, a novel anti-waterblocking agent with both wettability alteration and surface tension reduction was developed; then a reservoir protection drilling fluid for deep coal formation in Daning-Jixian block was constructed; then the reservoir protection performance of drilling fluid was evaluated. The results show that as the concentration of the anti-waterblocking agent FSS increases from 0% to 1%, the surface tension of the water phase is significantly reduced from 72.15 mN/m to 26.58 mN/m, while the maximum contact angle of water on the surface reaches 117°. This enhancement in wettability leads to an improvement in the permeability recovery rate from 56.6% to 80.0%, indicating a substantial reduction in waterblocking effects and better fluid mobility within the reservoir. These findings highlight the efficacy of FSS in mitigating formation damage and optimizing gas production in coalbed methane reservoirs. The drilling fluid has good wettability alteration, inhibition, and sealing performance, which is of great significance for protecting gas well productivity. [ABSTRACT FROM AUTHOR]

To investigate the effect of the chemical composition of a metal–organic crosslinker on the performances of fracturing fluid in high-temperature conditions, four zirconium (Zr) crosslinkers and one aluminum–zirconium (Al-Zr) crosslinker with a polyacrylamide were used. The crosslinkers possessed the same Zr concentration, but they differed in component amounts and the order of the addition of the crosslinker components, leading to different chemical compositions in the crosslinkers. The fracturing fluids prepared by different tested crosslinkers were compared in terms of properties of rheological behavior, sand-carrying ability, microstructure, and gel breaking characteristics. The results showed that the fracturing fluids prepared by zirconium lactic acid, ethanediamine, and sorbitol crosslinkers offered the slowest viscosity development and highest final viscosity compared to the zirconium lactic acid crosslinker and the zirconium lactic acid and ethanediamine crosslinker. The zirconium sorbitol, lactic acid, and ethanediamine crosslinker exhibited a faster crosslinking rate and a higher final viscosity than the zirconium lactic acid, ethanediamine, and sorbitol crosslinker; the crosslinker showed crosslinking density and crosslinking reactivity, resulting in more crosslinking sites and a higher strength in the fracturing fluid. The Al-Zr-based crosslinker possessed better properties in temperature and shear resistance, viscoelasticity, shear recovery, and sand-carrying ability than the Zr-based crosslinker due to the synergistic crosslinking effect of aluminum and zirconium ions. The tertiary release gelation mechanism of the Al-Zr-based fracturing fluid achieved a temperature resistance performance in the form of continuous crosslinking, avoiding the excessive crosslinking dehydration and reducing viscosity loss caused by early shear damage. These results indicated that the chemical compositions of metal–organic crosslinkers were important factors in determining the properties of fracturing fluids. Therefore, the appropriate type of crosslinker could save costs without adding the additional components required for high-temperature reservoirs. [ABSTRACT FROM AUTHOR]

To develop high-salinity, high-temperature reservoirs, two hydrophobically associating polymers as fracturing fluid thickener were respectively synthesized through aqueous solution polymerization with acrylamide (AM), acrylic acid (AA), 2-acrylamido-2-methylpropanesulfonic acid (AMPS), nonionic polymerizable surfactant (NPS) and double-tail hydrophobic monomer (DHM). The thickener ASDM (AM/AA/AMPS/NPS/DHM) and thickener ASD (AM/AA/AMPS/DHM) were compared in terms of properties of water dissolution, thickening ability, rheological behavior and sand-carrying. The results showed that ASDM could be quickly diluted in water within 6 min, 66.7% less than that of ASD. ASDM exhibited salt-thickening performance, and the apparent viscosity of 0.5 wt% ASDM reached 175.9 mPa·s in 100,000 mg/L brine, 100.6% higher than that of ASD. The viscosity of 0.5 wt% ASDM was 85.9 mPa·s after shearing for 120 min at 120 °C and at 170 s−1, 46.6% higher than that of ASD. ASDM exhibited better performance in thickening ability, viscoelasticity, shear recovery, thixotropy and sand-carrying than ASD. The synergistic effect of hydrophobic association and linear entanglement greatly enhancing the performance of ASDM and the compactness of the spatial network structure of the ASDM was enhanced. In general, ASDM exhibited great potential for application in extreme environmental conditions with high salt and high temperatures. [ABSTRACT FROM AUTHOR]

It is widely accepted that permeability is a key attribute for sustainable development, but two puzzles remain unsolved. First, there is no consensus on its measurement. Second, there are still many new urban developments that lack this quality; regardless, it is a well-known urban design principle. This paper reviews different permeability measurements and proposes to categorize them into four quadrants, then compares eleven of them with four sets of abstract forms and four real cases from Southeast China. The two measures rooted in space syntax theory demonstrate their robustness in the abstract forms. In contrast, the area-based measures cannot quantify the differences between places with similar content. In the actual case studies, by comparing the differences between original plans and the real built forms, we suggest that three traps impair their permeability and therefore deviate greatly from the initial design visions, resulting in automobile-oriented travel patterns. The two new measures were used to quantify the different levels of permeability in these four cases. It is concluded that the qualitative urban design principles may fail to be delivered without a quantitative and precise description of urban form. Consistent measures and more empirical cases are needed to reveal the contribution of spatial networks to sustainable development. [ABSTRACT FROM AUTHOR]

China's rapid urbanization has been accompanied by serious urban sprawl. Instead of measuring the physical urban boundaries (PUBs), most of existing studies in China rely on yearbook statistics to describe the growth of urbanized area; therefore, the understanding of the actual form and quantity of urban sprawl are restrained. As the statistical unit is generally at or above the county level, these studies tend to omit the lower-level "larger towns". This paper discusses the measurement of urban sprawl and compactness using multi-source data on the GIS platform through the case study of the Wen-Tai region in China. GlobeLand30 remote sensing image data, vector road network data, NPP/VIIRS nighttime light data, and points of interest (POIs) data are adopted. The new method enhances the identification of built-up areas in larger towns. Besides, the 2020s' PUBs of this region, data for 2010 and 2000 are retraced to assess the urban expansion rate, and two approaches are used to discuss the urban growth pattern. Additionally, a compactness model is constructed from four dimensions, i.e., the compactness of external contour, accessibility of road network, land-use intensity, and functional diversity, by which a high-resolution visual analysis tool is created for the provincial government to monitor urban sprawl. [ABSTRACT FROM AUTHOR]

With increasing global energy consumption, oil/gas drilling has gradually expanded from conventional shallow reservoirs to deep and ultra-deep reservoirs. However, the harsh geological features including high temperature and high salinity in ultra-deep reservoirs have become a critical challenge faced by water-based drilling fluids (WDFs), which seriously deteriorate the rheology and fluid loss properties, causing drilling accidents, such as wellbore instability and formation collapse. In this study, a novel temperature- and salt-resistant micro-crosslinked polyampholyte gel was synthesized using N,N-dimethylacrylamide, diallyldimethyl ammonium chloride, 2-acrylamido-2-methylpropanesulfonic acid, maleic anhydride and chemical crosslinking agent triallylamine through free radical copolymerization. Due to the synergistic effect of covalent micro-crosslinking and the reverse polyelectrolyte effect of amphoteric polymers, the copolymer-based drilling fluids exhibit outstanding rheological and filtration properties even after aging at high temperatures (up to 200 °C) and high salinity (saturated salt) environments. In addition, the zeta potential and particle size distribution of copolymer-based drilling fluids further confirmed that the copolymer can greatly improve the stability of the base fluid suspension, which is important for reducing the fluid-loss volume of WDFs. Therefore, this work will point out a new direction for the development of temperature- and salt-resistant drilling fluid treatment agents. [ABSTRACT FROM AUTHOR]

Gas-wetting alteration is a versatile and effective approach for alleviating liquid-blockage that occurs when the wellbore pressure of a gas-condensate reservoir drops below the dew point. Fluorochemicals are of growing interest in gas-wetting alteration because of their high density of fluorine groups and thermal stability, which can change the reservoir wettability into more favorable conditions for liquids. This review aims to integrate the overlapping research between the current knowledge in organic chemistry and enhanced oil and gas recovery. The difference between wettability alteration and gas-wetting alteration is illustrated, and the methods used to evaluate gas-wetting are summarized. Recent advances in the applications of fluorochemicals for gas-wetting alteration are highlighted. The mechanisms of self-assembling adsorption layers formed by fluorochemicals with different surface morphologies are also reviewed. The factors that affect the gas-wetting performance of fluorochemicals are summarized. Meanwhile, the impacts of gas-wetting alteration on the migration of fluids in the pore throat are elaborated. Furthermore, the Wenzel and Cassie-Baxter theories are often used to describe the wettability model, but they are limited in reflecting the wetting regime of the gas-wetting surface; therefore, a wettability model for gas-wetting is discussed. Considering the promising prospects of gas-wetting alteration, this study is expected to provide insights into the relevance of gas-wetting, surface morphology and fluorochemicals, further exploring the mechanism of flow efficiency improvement of fluids in unconventional oil and gas reservoirs. [ABSTRACT FROM AUTHOR]