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Dielectric and thermal properties of polyvinyl butyral (PVB) were studied in this work, using dynamic electrical analysis (DEA) at frequencies from 100 Hz to 1 MHz and temperatures from 293 K to 473 K. Two electrical relaxation processes were investigated: glass transition and interfacial polarization. Above the glass transition temperature (~343 K), interfacial polarization dominates conductive behavior in polyvinyl butyral. The framework of the complex electric modulus was used to obtain information about interfacial polarization. The viscoelastic behavior was analyzed through dynamic mechanical analysis (DMA), where only the mechanical manifestation of the glass transition is observed. The experimental results from dielectric measurements were analyzed with fractional calculus, using a fractional Debye model with one cap-resistor. We were successful in applying the complex electric modulus because we had a good correlation between data and theoretical predictions. The fractional order derivative is an indicator of the energy dissipated in terms of molecular mobility, and the calculated values close to 1 suggest a conductive behavior at temperatures above the glass transition temperature of PVB. [ABSTRACT FROM AUTHOR]