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Tea is a non-alcoholic drink containing various active ingredients, including tea polysaccharides (TPSs). TPSs have various biological activities, such as antioxidant, anti-tumor, hypoglycemic, and anti-cancer activities. However, TPSs have a complex composition, which significantly limits the extraction and isolation methods, thus limiting their application. This paper provides insight into the composition, methodological techniques for isolation and extraction of the components, biological activities, and functions of TPSs, as well as their application prospects. [ABSTRACT FROM AUTHOR]

Selective extraction of low-concentration thorium (Th(IV)) from wastewater is a very important research topic. In this paper, amidoxime cellulose was synthesized, and its composition and structure were characterized by FT-IR, SEM, XPS, and elemental analysis. The adsorption experiment results showed that the adsorption reaction was a spontaneous exothermic process. When the solid–liquid ratio was 0.12 g/L and the pH value was 3.5, the adsorption percentage of the Th(IV) in water onto amidoxime-functionalized cellulose (AO-CELL) could reach over 80%. The maximum adsorption capacity can reach to 450 mg/g. At the same time, the adsorption selectivity, desorption process and reusability of the material were also studied. The results showed that the AO-CELL had a good selectivity for Th(IV) in the system with Sr2+, Cu2+, Mg2+, Zn2+, Pb2+, Ni2+, and Co2+ as co-ions. In the nitric acid concentration of 0.06 mol/L system, the AO-CELL desorption rate of Th(IV) can reach 95%, and the adsorption rate of Th(IV) in aqueous solution of AO-CELL is still above 60% when the AO-CELL is reused four times. The above results show that the amidoxime cellulose adsorption material synthesized by our research group has good selective adsorption performance for Th(IV) of a low concentration in an aqueous solution and has a good practical application value. [ABSTRACT FROM AUTHOR]

The β-cyclodextrin-graft-(maleic anhydride-co-acrylonitrule) copolymer (β-CD-g-(MAHco-AN)) synthesized through radical polymerization reactions of β-cyclodextrin (β-CD) with maleic anhydride (MAH) and acrylonitrule (AN) in the special monomer proportion, chemically modify with amidoxime groups to obtained the new adsorbent, which was terms as amidoxime-functionalized β-cyclodextrin-graft-(maleic anhydride-co-acrylonitrule) copolymer (β-CD-g-(MAH-co-AO)). Based on the characteristic results of Fourier transform infrared spectra (FTIR), scanning electron microscopy (SEM), X-ray Diffraction (XRD), and thermalgravity analysis (TGA) techniques, the grafted nitrile groups were successfully converted to amidoxime groups by reaction with hydroxylamine. In this report, the influence of different factors such as pH value and ionic strength, solid-liquid ratio, contact time, initial U(VI) concentration, and temperature on adsorption was investigated by a batch adsorption experiment. The adsorption process fitting results show that the adsorption followed the Langmuir isotherm model and the maximum adsorption capacity was 0.747 g/g at pH 4.0. In addition, the regeneration performance was investigated by varying the concentration of eluent, temperature, and contact time. Under the desorption condition of 0.10 M HNO3, the adsorbents can be reused 12 times in the case that the adsorption capacity was not significantly reduced. The functionalized copolymer exhibits high selectivity under circumstance of other co-existing ions is present in the solution. [ABSTRACT FROM AUTHOR]

In this study, 32 novel quinazolinone-scaffold-containing pyrazole carbamide derivatives were designed and synthesized in a search for a novel fungicide against Rhizoctonia solani . Single-crystal X-ray diffraction of 3-(difluoromethyl)- N -(2-((6,7-difluoro-4-oxoquinazolin-3(4H)-yl)methyl)phenyl)-1-methyl-1H-pyrazole-4-carboxamide ( 6a 11 ) confirmed the structure of the target compounds. The in vitro antifungal activity of the target compounds against R. solani was evaluated at 100 µg/mL. The structure-activity relationship analysis results revealed that antifungal activity was highest when the substitution activity was at position 6. Moreover, the position and number of chlorine atoms directly affected the antifungal activity. Further in vitro bioassays revealed that 6a 16 (EC 50 = 9.06 mg/L) had excellent antifungal activity against R. solani that was higher than that of the commercial fungicide fluconazole (EC 50 = 12.29 mg/L) but lower than that of bixafen (EC 50 = 0.34 mg/L). Scanning electron microscopy), 7.33 (SEM) revealed that N -(2-((6,8-dichloro-4-oxoquinazolin-3(4H)-yl)methyl)phenyl)-3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxamide ( 6a 16 ) also affected the mycelial morphology. The findings revealed that molecular hybridization was an effective tool for designing antifungal candidates. Meanwhile, pyrazolecarbamide derivatives bearing a quinazolinone fragment exhibited potential antifungal activity against R. solani .