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Gas reservoirs have significant engineering characteristics of injection and extraction. The reservoir cap rock is subjected to cyclic alternating loading and has the potential risk of seal failure. Therefore, it is necessary to study the stress−percolation−damage mechanism of the reservoir cap rock in depleted gas reservoirs. The rock Mechanics Test System (MTS) was used to study the permeability characteristics of a typical mud shale cap layer under different loading and unloading rates, analyze the deformation characteristics and permeability performance evolution law of the rock under the confining pressure alternation, and study the effects of loading and unloading rate, confining pressure and number of cycles on the permeability of the cap rock. The test results show that with the increase in the number of cycles, the hysteresis loop moves in the direction of axial strain increase offset. The overall morphology is presented as an elongated type, and the damage of the specimen is small in the cyclic confining pressure; At the beginning of the cycling period, the permeability decreases with the increase in the confining pressure in the form of a negative exponential. At the later stage of the cycling period, the permeability basically stays unchanged, and is maintained at a low level; At low confining pressure, permeability also decreases in a negative exponential form with the increase in the number of confining pressure cycles; The greater the loading and unloading rate at the beginning of the cycle, the more the permeability decreases; There is a tendency of sealing improvement under cyclic loading in the gas storage of depleted reservoirs with mud shale as the cap layer. The results of the study can provide technical parameters for the evaluation of the cap sealing of gas storage of depleted reservoirs. [ABSTRACT FROM AUTHOR]

Low-permeability sandstone reservoirs have been widely used as a gas storage medium worldwide. Compared with the high porosity and high permeability of sandstone, low-permeability sandstone may present different mechanical (deformation, damage or failure) and acoustic responses under cyclic loading-unloading processes caused by the high-rate injection–production of underground gas storage. In this paper, multistage triaxial loading–unloading tests with a continuously increased upper limit of stress were carried out on low-permeability sandstone under six different confining pressures. The results showed that the superposition of stress–strain curves become much denser in the process of each level of stress. Based on the variation of the elastic modulus of low-permeability sandstone under alternating loads, the mechanical behavior of low-permeability sandstone under cyclic loading is divided into three stages: cyclic hardening, stability and cyclic softening. According to the evolution of acoustic emission (AE) signal parameters, AE counts appear intensively at the initial stage of each level of stress and then gradually stabilize. The peak frequency presents the zonal distribution, which is divided into low-frequency, intermediate-frequency and high-frequency zones. Low confining pressure leads to a small b-value. The RA–AF distribution implies that the mixed tensile–shear cracks are continuously generated in low-permeability sandstone during the cyclic loading process, and the shear cracks are more obviously developed. [ABSTRACT FROM AUTHOR]

The good sealing caprocks are significant for the integrity of underground gas storage (UGS) in depleted natural gas reservoirs. The screening of parameters, weight assignment, and evaluation method are important for evaluating the sealing performance of caprocks. Many factors can affect the sealing performance of caprocks, including caprock thickness, lithology, brittleness, porosity and permeability, breakthrough pressure, etc. In this paper, the dominant factors in the sealing performance of caprocks in UGSs are systematically analyzed, and the weights of these factors are analyzed by the analytic hierarchy process (AHP). The fuzzy comprehensive evaluation method (FCEM) is applied in the sealing evaluation of caprocks in three typical underground gas reservoirs (i.e., Zhujiadun, Xu-2, and Xing-9) in China. The sandstone reservoir in the Zhujiadun gas field is only about 20 m, and the thickness of the overlying mudstone is about 600 m. The caprock of the Xu-2 gas reservoir in Zhongba gas field is well distributed and developed, and the breakthrough pressure is relatively large. The caprock of Xing-9 gas field is mudstone with a thickness of over 400 m. The results show that the breakthrough pressure and permeability are the key parameters affecting the sealing ability of caprocks, with weights of 0.4291 and 0.2157, respectively. Among these three examples of gas fields, the sealing performance of caprocks in Zhujiadun gas storage is the best. The evaluation procedure and methods proposed in this paper are valuable for the evaluation of the tightness of caprocks in depleted gas reservoirs. [ABSTRACT FROM AUTHOR]

The structure of caprocks is often greatly altered by different scales of faults or fissures in long-term geological tectonic evolution, and the sealing performance may be deteriorated. In this paper, a simplified geological model characterized as multilayered sandstone and fault-bearing caprocks extracted from the Shuang 6 underground gas storage located in the Liaohe oilfield was established. Different fault geometry (e.g., fault length, fault dip angle, and fault type) and seepage attributes (porosity and permeability) were considered to illustrate their impacts on natural gas migration during the cyclic high rate of injection and production of natural gas. The results showed that the seepage anisotropy and the natural gas front are strongly affected by the formation properties and, especially, are hindered by the low permeability sandstone layers. The difference in the lateral migration distance of natural gas in different layers can reach 110 m at the end of the injection period, with an annual injection volume of 108 m3. The migration of natural gas along the fault zone is mainly controlled by the permeability of faults, followed by fault scale, fault dip angle, and fault type. The sealing failure of caprocks in the fault zone does not occur based on the simulated gas migration distribution, showing that a very limited amount of natural gas migrates into the caprocks. [ABSTRACT FROM AUTHOR]

In the current international situation, energy storage is an important means for countries to stabilize their energy supply, of which underground storage of natural gas is an important part. Depleted gas reservoir type underground gas storage (UGS) has become the key type of gas storage to be built by virtue of safety and environmental protection and low cost. The multi-cycle high injection and production rate of natural gas in the depleted gas reservoir type UGS will cause the in-situ stress disturbance. The slip risk of fault in the geological system increases greatly compared with that before the construction of the storage engineering, which becomes a great threat to the sealing of the gas storage. Reasonable injection and production strategy depend on the reliable assessment of the shear behavior of the fault belt, which can guarantee the sealing characteristics of the UGS geological system and the efficient operation of the UGS. Therefore, the shear behavior of the fault is studied by carrying out experiments, which can provide important parameters for the evaluation of fault stability. However, there is a large gap between the rock samples used in the previous experimental study and the natural faults, and it is difficult to reflect the shear failure characteristics of natural faults. In this paper, similar fault models based on high-precision three-dimensional scanners and engraving machines, filled with three types of fault gouge, are prepared for a batch of representative direct shear tests. The results show that the peak shear strength of the fault rocks with a shear surface is higher than that of the fault rocks with a tensile surface. Compared with the clay mineral content, the roughness of the fault surface is much more significant for the shear strength of the fault rock. For the fault rocks with similar fault surface morphology, the higher the clay content in the fault gouge, the greater the shear strength of the fault rocks. For the fault rocks with different fault surface morphology and the same fault gouge, the cohesion and internal friction angle of the tensile type is generally smaller than that of the shear type. [ABSTRACT FROM AUTHOR]

The underground gas storage (UGS) in depleted sandstone reservoirs forms the largest proportion of the UGS market in China. Multiple cycles of natural gas injection and production in the sandstone cause the rapid increase and drawdown of pore pressure, which may induce damage to the rock skeleton structure, and cause complex fluid flow paths in the sandstone reservoir. In this paper, transverse relaxation time (T2), nuclear magnetism resonance imaging, and high-pressure mercury intrusion analysis are combined to evaluate the variation in pore structure of medium-grained sandstone. The results show that cyclic injection and production of fluid leads to a slight increase in total pore volume, indicating that weak damage to rocks occurs. The T2 spectrum at the low pore pressure (10 MPa) and high pore pressure (25 MPa) both show that the shrinkage of the medium-size pores occurs after multiple cycles of injection and production. The pore volume of large-size pores was not highly correlated with the number of cycles. With the increase in pore pressure, the pore volume ratio under high pore pressure increased with the number of cycles, while it fluctuated strongly under low pore pressure. [ABSTRACT FROM AUTHOR]

With the increasing scale and depth of underground engineering, the geological environment that engineering is faced with is becoming more complex. As the weak position of rock mass, the structural surface has a particularly great influence on the mechanical characteristics of the rock mass. In order to obtain the shear strength characteristic of the structural plane and analyze the influence of morphological parameters such as the undulating angle and bulge degree on shearing, taking medium-low permeability tight sandstone as the research object, four kinds of structural plane samples with different undulating angles (10, 20, 30 and 40°) were prepared with a Python and high-precision engraving machine. Direct shear tests under different normal stresses (2, 4, 6 and 8 MPa) and shear rates (0.6, 1.2 and 2.4 mm/min) were performed, and the shear mechanical properties were analyzed. The structural surfaces before and after shearing were scanned using a high-precision three-dimensional scanner, so as to evaluate the roughness of the structural surface and determine the influence from various factors on the shear characteristics. The test results showed that for the structural plane with the same undulating angle, the peak shear stress increased approximately linearly with an increase in normal stress at a 0.6 mm/min shear rate and an increment speed of approximately 0.82, while the peak shear stress negatively correlated with the shear rate at a value of 4 MPa for normal stress. The larger the undulating angle was, the greater the influence of the shear rate (the shear stress decreased by 2.31 MPa at a 40° angle). When the normal stress and the shear rate were fixed, the peak shear stress corresponding to the structural surface gradually increased with the increase in the undulating angle, and the maximum increment was 5.04 MPa at 4 MPa normal stress and a 0.6 mm/min shear rate. An analysis of the morphological characteristics of the structural plane showed that when the undulating angle (40°) and the normal stress (6 and 8 MPa) were larger, the damage of the structural plane became more obvious, the shear point was closer to the tooth valley position, and the mechanical bite force and friction force of the structural plane were better utilized. When the shear rate was lower (0.6 mm/min), the friction characteristics of the shear surface were more visible, the shear was increasingly sufficient, and the corresponding shear strength was also greater. [ABSTRACT FROM AUTHOR]

In a casing-cement sheath-formation system, the cement–formation interface is usually weakly cemented for the residual of drilling mud, in which a leakage path would easily form, threatening the safe operation of underground energy exploitation and storage. To evaluate the compressive and shear mechanical behavior of the cement–formation interface, cement–rock composite cylindrical specimens were prepared. Uniaxial and triaxial compression and direct shear tests were implemented. The flushing efficiency of the rock surface, compressive strength, interface incompatible deformation, parameters of shear strength, and morphology of shear failure surface were acquired and analyzed. Results show that the flushing efficiency of shale surface decreases from 76.7% to 64.2% with the surface roughness increasing from 0 to 2 mm. The flushing efficiency of sandstone is only 44.7%, remarkably lower than that of shale. With the stress condition transforming from uniaxial to triaxial compression, the feature of the stress–strain curves changes from elastic-brittle to elastoplastic, and the compressive strength increases from 20.6~60.1 MPa to 110~120 MPa. The cement part presents noteworthy plastic deformation and several micro shear fractures develop. There is incompatible deformation between cement and rock, which induces interface debonding for almost all the composite specimens. The internal friction angle and cohesive strength both decrease with the increase in pollution degree of drilling mud, and increase with the rise in surface roughness. The shear facture surface is not exactly the rock–cement interface, but usually manifests as a shear zone, in which the rock, cement, and interface all contribute to the final shear failure. The above findings would be valuable for the revealing of cement–formation interface failure mechanism. [ABSTRACT FROM AUTHOR]

Most of the discovered high-temperature geothermal energy systems are often related with granite that is characterized by natural faults, fractures and cracks of different size. However, the porosity and permeability of the granite matrix is very low, greatly limiting the efficiency of heat extraction in granitic rock. Chemical stimulation, which is regarded as one of the most important means of reservoir stimulation, has consequently received more and more attention. In this paper, a Triassic granite obtained from the eastern region of Liaoning Province in China was reacted with three different concentration of mud acid solution (8% HCl + 1% HF, 10% HCl + 2% HF, 12% HCl + 3% HF) and the resulting microstructure changes studied by scanning electron microscopy (SEM) and nuclear magnetic resonance (NMR). The experimental results show that the number of micropores in the granite increases after chemical corrosion by mud acid solution. A higher mud acid solution concentration results in a much higher pore volume. Triaxial compression tests on the granite before and after chemical corrosion were carried out to study the effect of acidification on the mechanical characteristics of granite, showing that the peak stress and elastic modulus of granite decreases 25.7% and 16.5%, respectively, after exposure to mud acid solution (12% HCl + 3% HF) corrosion for three weeks at room temperature. The particle flow program PFC2D based on discrete element method was used to investigate the mechanical response before and after the chemical corrosion. Considering that the granite is rich in microcracks, the study is simplified by considering them all grouped into one main closed fracture. The influences of main crack inclination angle, crack length, friction coefficient and confining pressure on the mechanical response were investigated. Under the triaxial compression loading state, wing cracks appear at the initial crack tip, then secondary cracks begin to appear. The sensitivity analysis shows that three characteristic strengths (crack initiation strength, damage strength and peak strength) are strongly correlated with crack length, crack inclination angle, crack surface friction coefficient and confining pressure. These three characteristic strengths decrease 60%, 59% and 53%, respectively, compared with their initial values with the increase of main crack length from 6 mm to 22 mm, while they present positive correlation with the fracture friction coefficient from 0 to 1.0 and confining pressure from 10 to 50 MPa. There is a critical inclination angle of the main crack (i.e., 45°), meaning that these three characteristic strengths of granite decrease with inclination angles smaller than 45°, while they increase with an inclination angle larger than 45°. After the corrosion effect of mud acid solution on granite, the pore structure was changed and mechanical properties was damaged, which further affect the failure mode and failure process of granite samples affected by mud acid solutions. This paper provides a theoretical reference for evaluating the effect of chemical stimulation technology on the mechanical characteristics of granite, serving for the continuous hydraulic stimulation design after the chemical stimulation. [ABSTRACT FROM AUTHOR]

In order to study the influence of different confining pressures on the stability and airtightness of dolomite underground gas storage, a permeability test under hydrostatic confining pressure, conventional triaxial compression test and gas–solid coupling test under triaxial compression were carried out on MTS815 test machine. During the tests, an acoustic emission (AE) monitoring system was also employed to estimate the rock damage. The experimental results showed that the relationships between permeability, porosity and hydrostatic confining pressure were exponential function and power function, respectively. Increasing confining pressure reduced the porosity and permeability of dolomite, and increased its triaxial compressive strength, but the addition of nitrogen reduced the compressive strength of dolomite by 10~30%, the higher the confining pressure, the smaller the difference. Compared with the maximum permeability under 15 MPa, confining pressure in the gas–solid coupling experiment, the maximum permeability under confining pressure of 30, 45, and 60 MPa is reduced by 42.0%, 84.4%, and 97.9%, respectively. In addition, the AE activity of dolomite decreases significantly with the increase in confining pressure, which also delayed the arrival of the AE active period. [ABSTRACT FROM AUTHOR]

Ground thermal properties are the design basis of ground source heat pumps (GSHP). However, effective ground thermal properties cannot be obtained through the traditional thermal response test (TRT) method when it is used in the coaxial borehole heat exchanger (CBHE). In this paper, an improved TRT (ITRT) method for CBHE is proposed, and the field ITRT, based on the actual project, is carried out. The high accuracy of the new method is verified by laboratory experiments. Based on the results of the ITRT and laboratory experiment, the 3D numerical model for CBHE is established, in which the flow directions, sensitivity analysis of heat transfer characteristics, and optimization of circulation flow rate are studied, respectively. The results show that CBHE should adopt the anulus-in direction under the cooling condition, and the center-in direction under the heating condition. The influence of inlet temperature and flow rate on heat transfer rate is more significant than that of the backfill grout material, thermal conductivity of the inner pipe, and borehole depth. The circulating flow rate of CBHE between 0.3 m/s and 0.4 m/s can lead to better performance for the system. [ABSTRACT FROM AUTHOR]

Impure salt rock strata are extensively distributed in China, giving them great significance in the study of the physical properties of impure salt rock for the construction of underground gas storage in salt mines. To investigate the confining pressure and impurity effects on the mechanical properties and gas permeability characteristics of salt rock, permeability tests under hydrostatic confining pressure and conventional triaxial compression (CTC), on salt rock samples with different impurity contents, were carried out. The results demonstrate that the confining pressure effects cause an increase in triaxial compression strength, but a decrease in permeability. However, impurity enhances the bearing capacity and permeability of the salt rock; both rock strength and permeability increase with an increase in impurity content. Moreover, the broken salt rock specimens were analyzed after the CTC test using Computed Tomography (CT) equipment. To understand the relationships between pore volume and permeability, considering the confining pressure and impurity effects, the cracks were divided into four groups according to different crack diameter ranges: ~0.05 mm, 0.05–1 mm, 1–10 mm and ~10 mm. The CT analysis results show that while the pore volume of smaller cracks shows an "increasing–decreasing" trend by increasing confining pressure, the pore volume of large cracks gradually decreases, indicating that the rock permeability is highly related to macro-cracks. However, impurity has more complicated implications on rock permeability and cracks, and needs further investigation. [ABSTRACT FROM AUTHOR]

The emissions of greenhouse gases, especially CO2, have been identified as the main contributor for global warming and climate change. Carbon capture and storage (CCS) is considered to be the most promising strategy to mitigate the anthropogenic CO2 emissions. This review aims to provide the latest developments of CO2 storage from the perspective of improving safety and economics. The mechanisms and strategies of CO2 storage, focusing on their characteristics and current status, are discussed firstly. In the second section, the strategies for assessing and ensuring the security of CO2 storage operations, including the risks assessment approach and monitoring technology associated with CO2 storage, are outlined. In addition, the engineering methods to accelerate CO2 dissolution and mineral carbonation for fixing the mobile CO2 are also compared within the second section. The third part focuses on the strategies for improving economics of CO2 storage operations, namely enhanced industrial production with CO2 storage to generate additional profit, and co-injection of CO2 with impurities to reduce the cost. Moreover, the role of multiple CCS technologies and their distribution on the mitigation of CO2 emissions in the future are summarized. This review demonstrates that CO2 storage in depleted oil and gas reservoirs could play an important role in reducing CO2 emission in the near future and CO2 storage in saline aquifers may make the biggest contribution due to its huge storage capacity. Comparing the various available strategies, CO2-enhanced oil recovery (CO2-EOR) operations are supposed to play the most important role for CO2 mitigation in the next few years, followed by CO2-enhanced gas recovery (CO2-EGR). The direct mineralization of flue gas by coal fly ash and the pH swing mineralization would be the most promising technology for the mineral sequestration of CO2. Furthermore, by accelerating the deployment of CCS projects on large scale, the government can also play its role in reducing the CO2 emissions. [ABSTRACT FROM AUTHOR]