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To characterize seasonal carbonaceous aerosol pollution in Taiyuan, a typical city in North China that mainly relies heavily on coal, a total of 124 PM2.5 samples were collected from August 2018 to the next May. The annual mean PM2.5 concentration was 83.8 ± 48.5 μg m−3, with a seasonal rank of winter (117.4 ± 47.6 μg m−3) > spring (79.2 ± 34.3 μg m−3) > fall (67.3 ± 34.7 μg m−3) > summer (31.8 ± 6.5 μg m−3), suggesting that fine particulate pollution was still serious in cold seasons. Organic carbon (OC) and elemental carbon (EC) showed similar seasonal patterns with PM2.5. The mean concentration values of OC in summer, fall, winter, and spring were 5.1 ± 0.9, 11.8 ± 6.4, 22.1 ± 14.9, and 12.2 ± 6.7 μg m−3, respectively. The mean concentration values of EC in summer, fall, winter, and spring were 1.5 ± 0.3, 2.5 ± 1.6, 4.4 ± 2.8, and 2.4 ± 1.5 μg m−3, respectively. The proportion of total carbon aerosol (TCA) was about 31.7%, 33.8%, 30.0%, and 27.0% in PM2.5 in summer, fall, winter, and spring, respectively. The good correlation between OC vs. EC and the high value of OC/EC suggests that coal and biomass combustion were the main emissions in cold seasons, aggravated by adverse meteorological conditions and the dustpan-shaped terrain. The mean annual secondary organic carbon (SOC) concentration was 6.1 ± 7.1μg m−3, representing 38.7% of the OC content. The present results presented the serious carbonaceous particulate pollution, which might affect haze pollution in cold seasons. [ABSTRACT FROM AUTHOR]

To evaluate air pollution and the public health burden of heavy metals in PM2.5 in a campus with a population of approximately 40,000 in a typical suburb area of Taiyuan, North China, PM2.5 measurements were conducted during the spring and winter of 2016. The average concentrations of PM2.5 in spring and winter were 97.3 ± 35.2 μg m-3 and 205.9 ± 91.3 μg m-3, respectively. The order of concentration of heavy metals in PM2.5 was as follows: Zn > Pb > Mn > Cu > Cr > Ni > Cd > As, in both spring and winter. The concentrations of Cd and Pb in winter and the concentrations of Cr in both spring and winter in this study were significantly higher than the corresponding air quality standard values. Road/soil dust, industrial emissions/coal combustion, and vehicle emissions/oil combustion and coal combustion/industrial emissions, road/soil dust, and vehicle emissions/oil combustion were identified by principal component analysis to be the major sources of heavy metals for spring and winter, respectively. The carcinogenic risks posed by Cr via the three exposure pathways (except for inhalation exposure to children) and by Pb via ingestion exposure exceeded the acceptable level for both children and adults. The non-carcinogenic risks posed by Mn via inhalation for both children and adults, and by Cr and Pb for children via ingestion exceeded the acceptable level. [ABSTRACT FROM AUTHOR]

PM2.5 samples were collected in the rural and urban areas of Taiyuan, China during a typical haze episode and the heavy metals (Cr, Mn, Ni, Cu, Zn, As, Cd and Pb) in PM2.5 were analyzed. The haze was characterized by start-up stage with a daily mean PM2.5 of 149.34 ± 52.33 and 146.73 ± 18.96 μg m-3 in the rural and urban sites, respectively, a peak stage (288.20 ± 12.43 and 323.44 ± 5.23 μg m-3), and a weakening stage (226.59 ± 12.43 and 195.60 ± 2.93 μg m-3). The concentrations of PM2.5 in the rural and urban sites in the peak stage were 5.9 and 5.5 times higher than those in the normal stage, respectively. The order of concentrations of heavy metals in PM2.5 at the rural and urban sites were the same and are listed as follows: Zn > Pb > Mn > Cr > Cu > Ni > Cd > As. Pb at the rural site, As at the urban site, and Cd at the both sites failed to meet the air quality standard. The concentrations of Pb and Zn were higher at the rural site than those at the urban site. Principal component analysis indicated that the main sources of heavy metals for the rural area were raw coal combustion and soil/road dust, and for the urban area were coal combustion/industrial emissions, road/soil dust, and vehicle emissions/oil combustion. [ABSTRACT FROM AUTHOR]

Climate change has been recognized as a threatening environmental problem around the world. CO2 is considered to be the main component of greenhouse gas. By using solar energy (light energy) as the energy source, photocatalytic conversion is one of the most effective technologies to reveal the clean utilization of CO2. Herein, using sodium tungstate, nickel nitrate, and selenium powder as the main raw materials, the high absorption and utilization of WSe2 for light energy and the high intrinsic conductivity of NiSe2 were combined by a hydrothermal method to prepare NiSe2/WSe2 and hydrazine hydrate as the reductant. Then, high-performance NiSe2/WSe2 photocatalytic material was prepared. The characterization results of XRD, XPS, SEM, specific surface area, and UV-visible spectroscopy show that the main diffraction peak of synthesized NiSe2/WSe2 is sharp, which basically coincides with the standard card. After doping NiSe2, the morphology of WSe2 was changed from a flake shape to smaller and more trivial crystal flakes, which demonstrates richer exposed edges and more active sites; the specific surface area increased from 3.01 m2 g−1 to 8.52 m2 g−1, and the band gap becomes wider, increasing from 1.66 eV to 1.68 eV. The results of a photocatalytic experiment show that when the prepared NiSe2/WSe2 catalyst is used to conduct photocatalytic reduction of CO2, the yield of CH3OH is significantly increased. After reaction for 10 h, the maximum yield could reach 3.80 mmol g−1, which presents great photocatalytic activity. [ABSTRACT FROM AUTHOR]