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In order to address the issues of energy depletion, more resources are being searched for in the deep sea. Therefore, research into how the deep-sea environment affects cement-based materials for underwater infrastructure is required. This paper examines the impact of ocean depth (0, 500, 1000, and 1500 m) on the ion interaction processes in concrete nanopores using molecular dynamics simulations. At the portlandite interface, the local structural and kinetic characteristics of ions and water molecules are examined. The findings show that the portlandite surface hydrophilicity is unaffected by increasing depth. The density profile and coordination number of ions alter as depth increases, and the diffusion speed noticeably decreases. The main cause of the ions' reduced diffusion velocity is expected to be the low temperature. This work offers a thorough understanding of the cement hydration products' microstructure in deep sea, which may help explain why cement-based underwater infrastructure deteriorates over time. [ABSTRACT FROM AUTHOR]

Customarily, retarders serve as the setting time regulators of cement-based composites to meet the demands of various construction environments. However, the limited ability to adjust the setting time restricts the application of polysaccharides in special environments. In this study, we reported a naturally high-efficiency retarder, konjac glucomannan (KGM), and studied the mechanism of its effect on the hydration of ordinary Portland cement. Incorporating KGM could significantly prolong cement hydration without strength damage. Furthermore, the active hydroxyl group (−OH, rich in KGM) could chelate with Ca2+ (released from cement hydration) to form a cross-linking network, which is adsorbed on the surface of cement clinker, thereby being conducive to delaying the process of cement hydration and reducing the heat of hydration. The findings of this study are critical to the ongoing efforts to develop polysaccharide-cement-based composite materials for application in various special environments. [ABSTRACT FROM AUTHOR]

The increasing degree of urbanization has continuously aggravated the surface urban heat island (sUHI) effect in China. To investigate the correlation between spatiotemporal changes of sUHI and urbanization in Beijing, land surface temperature in summer from 2000 to 2017 and the distribution of local climate zones (LCZs) in 2003, 2005, 2010, and 2017 was retrieved using remote sensing data and used to analyze the sUHI area and intensity change. The statistical method GeoDetector was utilized to investigate the explanatory ability of LCZs and population as the driving factors. The year of 2006 was identified as the main turning year for sUHI evolution. The variation the sUHI from 2000 showed first an increasing trend, and then a decreasing one. The sUHI pattern changed before and after 2009. Before 2009, the sUHI mainly increased in the suburbs, and then, the enhancement area moved to the central area. The sUHI intensity change under different LCZ conversion conditions showed that the LCZ conversion influences the sUHI intensity significantly. Based on population distribution data, we found that the relationship between population density and sUHI gets weaker with increasing population density. The result of GeoDetector indicated that the LCZ is the main factor influencing the sUHI, but population density is an important auxiliary factor. This research reveals the sUHI variation pattern in Beijing from 2000 and could help city managers plan thermally comfortable urban environments with a better understanding of the effect of urban spatial form and population density on sUHIs. [ABSTRACT FROM AUTHOR]