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This study investigated the impact of paclobutrazol (PBZ) concentrations and application protocols on ornamental quality and consumer preference. PBZ was applied at five concentrations using three different protocols: drench at transplanting, drench 30 days after transplanting, and immersion. At commercial maturity, plants were assessed based on growth parameters related to height, canopy structure, fruit and leaf characteristics, and sensory attributes. The results indicated that PBZ treatments led to darker green leaves and, in general, the drench method, regardless of time application, was more effective in modulating plant growth compared to the immersion protocol. Conversely, the sensory analysis showed a greater preference among evaluators for plants treated with PBZ at 2.5 and 5 mg L−1 via drench at 30 days after transplanting (D30DAT) or through immersion (IM), even though IM was not associated with any of the ornamental quality parameters evaluated. Likewise, the application of PBZ by drench during transplanting is not recommended as the plants showed a reduced number and size of fruits, which affected the ornamental value of the plants and global preference. Therefore, PBZ applied by D30DAT at concentrations of 2.5 and 5 mg L−1 produced 'Biquinho Vermelha' pepper plants with attractive ornamental characteristics; and thereby, should be considered an alternative method for producers of potted ornamental plants. [ABSTRACT FROM AUTHOR]

Through the shikimate pathway, a massive metabolic flux connects the central carbon metabolism with the synthesis of chorismate, the common precursor of the aromatic amino acids phenylalanine, tyrosine, and tryptophan, as well as other compounds, including salicylate or folate. The alternative metabolic channeling of chorismate involves a key branch-point, finely regulated by aromatic amino acid levels. Chorismate mutase catalyzes the conversion of chorismate to prephenate, a precursor of phenylalanine and tyrosine and thus a vast repertoire of fundamental derived compounds, such as flavonoids or lignin. The regulation of this enzyme has been addressed in several plant species, but no study has included conifers or other gymnosperms, despite the importance of the phenolic metabolism for these plants in processes such as lignification and wood formation. Here, we show that maritime pine (Pinus pinaster Aiton) has two genes that encode for chorismate mutase, PpCM1 and PpCM2. Our investigations reveal that these genes encode plastidial isoenzymes displaying activities enhanced by tryptophan and repressed by phenylalanine and tyrosine. Using phylogenetic studies, we have provided new insights into the possible evolutionary origin of the cytosolic chorismate mutases in angiosperms involved in the synthesis of phenylalanine outside the plastid. Studies based on different platforms of gene expression and co-expression analysis have allowed us to propose that PpCM2 plays a central role in the phenylalanine synthesis pathway associated with lignification. [ABSTRACT FROM AUTHOR]

Anodic layers have been grown on 304L stainless steel (304L SS) using two kinds of fluoride-free organic electrolytes. The replacement of NH4F for NaAlO2 or Na2SiO3 in the glycerol solution and the influence of the H2O concentration have been examined. The obtained anodic layers were characterized by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, and potentiodynamic polarization tests. Here, it was found that, although the anodic layers fabricated within the NaAlO2-electrolyte and high H2O concentrations presented limited adherence to the substrate, the anodizing in the Na2SiO3-electrolyte and low H2O concentrations allowed the growth oxide layers, and even a type of ordered morphology was observed. Furthermore, the electrochemical tests in chloride solution determined low chemical stability and active behavior of oxide layers grown in NaAlO2-electrolyte. In contrast, the corrosion resistance was improved approximately one order of magnitude compared to the non-anodized 304L SS substrate for the anodizing treatment in glycerol, 0.05 M Na2SiO3, and 1.7 vol% H2O at 20 mA/cm2 for 6 min. Thus, this anodizing condition offers insight into the sustainable growth of oxide layers with potential anti-corrosion properties. [ABSTRACT FROM AUTHOR]

Agro-industrial waste valorization is an attractive approach that offers new alternatives to deal with shrinkage and residue problems. One of these approaches is the synthesis of advanced carbon materials. Current research has shown that citrus waste, mainly orange peel, can be a precursor for the synthesis of high-quality carbon materials for chemical adsorption and energy storage applications. A recent approach to the utilization of advanced carbon materials based on lignocellulosic biomass is their use in solar absorber coatings for solar-thermal applications. This study focused on the production of biochar from Citrus aurantium orange peel by a pyrolysis process at different temperatures. Biochars were characterized by SEM, elemental analysis, TGA-DSC, FTIR, DRX, Raman, and XPS spectroscopies. Optical properties such as diffuse reflectance in the UV−VIS−NIR region was also determined. Physical-chemical characterization revealed that the pyrolysis temperature had a negative effect in yield of biochars, whereas biochars with a higher carbon content, aromaticity, thermal stability, and structural order were produced as the temperature increased. Diffuse reflectance measurements revealed that it is possible to reduce the reflectance of the material by controlling its pyrolysis temperature, producing a material with physicochemical and optical properties that could be attractive for use as a pigment in solar absorber coatings. [ABSTRACT FROM AUTHOR]

In this paper, the influence of an electrolytic temperature bath was used in the electrodeposition process on the size, color, and shape of the as-deposited Co(OH)2, and the electrochemical performance was investigated. Three different temperatures of 25, 60, and 95 °C were evaluated for the electrodeposition of Co(OH)2 on stainless steel plates (SSP). The electrochemical performance of the as-deposited electrodes (SSP) was measured in a symmetric electrochemical cell (EC) arrangement. XRD, SEM, and N2 physisorption analyses were carried out to evaluate the structure and morphological composition, along with the textural properties. Results showed that the hexagonal platelet micro-clusters of Co(OH)2 are formed in a mixed composition of both α-Co(OH)2 and β-Co(OH)2 phases, with the α-Co(OH)2 phase being the major phase formed in the electrodeposition process at temperatures below 95 °C, as suggested by the XRD analysis. Electrochemical cell performances were evaluated by galvanostatic cycling, results showed maximum areal capacity values of 1.97, 2.69, and 4.34 mA h cm−2 at a charge/discharge current of 6.25 mA cm−2, for the as-deposited materials at 25, 60 and 95 °C, respectively. The specific power of the EC reached up to 19 kW kg−1 for the EC obtained material at 60 °C, with a specific energy of 2.8 W h kg−1. The maximum specific energy was reached at a current density of 6.25 mA cm−2, with a value of 10.79 W h kg−1 for the EC at 60 °C. These results offer some insight into how the morphology and composition of thin films can be tuned by the electrochemical synthesis temperature, yielding different electrochemical performances and areal capacity behaviors. [ABSTRACT FROM AUTHOR]