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This work is devoted to evaluating the corrosion behaviors of SS 304L and SS 316L in monoethanolamine solutions (MEA) containing SOX and NOX pollutants, examining both lean and CO2-loaded conditions at 25 °C and 40 °C. Electrochemical techniques (potentiodynamic and cyclic polarization) were used along with Scanning Electron Microscopy, Confocal Microscopy and weight loss measurements. The results reveal that the introduction of SOX and NOX pollutants increased the corrosion rate, whereas CO2 loading primarily reduced the corrosion resistance in the lean MEA solution, while its impact on solutions with SOX and NOX was less pronounced. This suggests that SOX and NOX play primary roles in the metal's dissolution. Also, SS 316L demonstrated superior corrosion resistance compared to 304L in nearly all of the cases examined. Elevated temperatures were also found to intensify the corrosion rate, indicating a correlation between the corrosion rate and temperature. A microscopic observation and EDX analysis revealed that corrosion products are characterized by high concentrations of iron (Fe) and oxygen (O) as well as carbon (C). There is also an indication of the possible formation of amine complexes, suggesting a potential for amine degradation. No pitting corrosion was observed in SS 304L and SS 316L across any tested solution. Finally, the immersion results expose a tendency for passivity in all amine solutions and at both temperatures after several days of exposure. Moreover, they confirm the very low corrosion rate calculated from potentiodynamic curves due to minimal weight loss after 24 days of immersion. [ABSTRACT FROM AUTHOR]

The corrosion behavior of two stainless steels (316L and 304L) was evaluated using a CO2-loaded aqueous solution of 30 wt.% monoethanolamine (MEA) with a view to simulating corrosion related mechanisms in amine treatment procedures. Corrosion behavior was experimentally evaluated as a function of CO2 loading and solution temperature, using electrochemical techniques (polarization curves, cyclic polarization, and EIS measurement). The results reveal that the aqueous MEA solution containing CO2 creates a favorable environment for the corrosion of both stainless steels. The rate of corrosion is accelerated when the temperature of the loaded MEA solution rises, which was attributed to the thermal degradation of the loaded MEA, thus causing higher kinetics of the cathodic reactions at higher temperatures. More specifically, for the SS 304L the corrosion rate is almost doubled when the solution temperature is increased from 25 °C to 40 °C and is quadrupled when the solution temperature rises to 80 °C. For the SS 316L, the corrosion rate becomes almost threefold and sixfold upon increasing temperature of the load amine solution to 40 °C and 80 °C, respectively. The overall corrosion rate of SS 316L is lower with respect to the SS 304L for the same temperature and loading conditions. The essential dependency of corrosion rate on solution type (unloaded and loaded MEA solution) demonstrates that the corrosion process and reactions are controlled by a diffusion mechanism. [ABSTRACT FROM AUTHOR]

Solvent-based CO2 capture technologies hold promise for future implementation but conventional solvents incur significant energy penalties and capture costs. Phase-change solvents enable a significant reduction in the regeneration energy but their performance has only been investigated under steady-state operation. In the current work, we employed a systematic approach for the evaluation of conventional solvents and mixtures, as well as phase-change solvents under the influence of disturbances. Sensitivity analysis was used to identify the impact that operating parameter variations and different solvents exert on multiple CO2 capture performance indicators within a wide operating range. The resulting capture process performance was then assessed for each solvent within a multi-criteria approach, which simultaneously accounted for off-design conditions and nominal operation. The considered performance criteria included the regeneration energy, solvent mass flow rate, cost and cyclic capacity, net energy penalty from integration with an upstream power plant, and lost revenue from parasitic losses. The 10 investigated solvents included the phase-change solvents methyl-cyclohexylamine (MCA) and 2-(diethylamino)ethanol/3-(methylamino)propylamine (DEEA/MAPA). We found that the conventional mixture diethanolamine/methyldiethanolamine (DEA/MDEA) and the phase-change solvent DEEA/MAPA exhibited both resilience to disturbances and desirable nominal operation for multiple performance indicators simultaneously. [ABSTRACT FROM AUTHOR]

Efficient power generation from low to medium grade heat is an important challenge to be addressed to ensure a sustainable energy future. Organic Rankine Cycles (ORCs) constitute an important enabling technology and their research and development has emerged as a very active research field over the past decade. Particular focus areas include working fluid selection and cycle design to achieve efficient heat to power conversions for diverse hot fluid streams associated with geothermal, solar or waste heat sources. Recently, a number of approaches have been developed that address the systematic selection of efficient working fluids as well as the design, integration and control of ORCs. This paper presents a review of emerging approaches with a particular emphasis on computer-aided design methods. [ABSTRACT FROM AUTHOR]

The tightened approach of the European Commission to the issue of meeting the levels of pollutant emissions to the environment, inextricably connected with the level of technology used, is a serious financial challenge for many European coke producers, therefore the main aim of the article is to develop an algorithm of conduct that allows a selection of the best available emission abatement techniques from the coking plant in conditions with multiple emission sources, taking into account technological, environmental, and economic criteria. This algorithm can be used as a universal tool supporting production managers in planning investments limiting the environmental impact of the coking plant in the most economically advantageous way, while using BAT techniques. In the development of the algorithm, a multi-criteria analysis and a scenario method were used, as well as a number of typical methods for measuring and reducing the level of emissions in the coke production process. Its demonstration and verification were carried out within ten investment scenarios prepared for a selected coking plant. The presented method of selecting the optimal scenario is universal and allows for a flexible selection of weights for the criteria depending on the needs and limits of the investor at a given time or to long term plans to adapt to the increasingly tightening environmental requirements. This method can also be used in discussions with the authorities issuing integrated permits as regards the deadlines for adapting to legal requirements. [ABSTRACT FROM AUTHOR]

A three-phase multi-level multi-input power converter topology is presented for grid-connected applications. It encompasses a three-phase transformer that is operated on the primary side in an open-end winding configuration. Thus, the primary winding is supplied on one side by a three-phase N-level neutral point clamped inverter and, on the other side, by an auxiliary two-level inverter. A key feature of the proposed approach is that the N-level inverter is able to perform independent management of N − 1 input power sources, thus avoiding the need for additional dc/dc power converters in hybrid multi-source systems. Moreover, it can manage an energy storage system connected to the dc-bus of the two-level inverter. The N-level inverter operates at a low switching frequency and can be equipped with very low on-state voltage drop Insulated-Gate Bipolar Transistor (IGBT) devices, while the auxiliary inverter is instead operated at low voltage according to a conventional high-frequency two-level Pulse Width Modulation (PWM) technique and can be equipped with very low on-state resistance Metal-Oxide-Semiconductor Field-Effect Transistor (MOSFET) devices. Simulations and experimental results confirm the effectiveness of the proposed approach and its good performance in terms of grid current harmonic content and overall efficiency. [ABSTRACT FROM AUTHOR]