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Iron in soil exists in various valence states and is prone to changes with alterations in soil environmental conditions. Its migration and transformation are crucial for soil formation and understanding soil evolution. This study focuses on Quaternary red soils found in woodland, sparse forest grassland, grassland, and cultivated land located in the semi-humid region of the middle temperate zone. For comparison, buried Quaternary red soil was also examined. A soil reconstruction model was used to quantitatively calculate the variation of different forms of iron in order to analyze various forms of iron composition, migration, and transformation within the soil profile, as well as the evolutionary traits of Quaternary red soils influenced by diverse land use activities. This study found that after exposure and use, iron from the topsoil of buried Quaternary red soil migrated to the subsoil, altering the iron distribution. Free iron and crystalline oxides decreased in the topsoil but increased in specific subsoil layers, with woodland and grassland showing the most significant changes. Silicate-bound iron pooled in the soil weathered to form free iron under different land uses, and poorly crystalline iron oxides transformed into crystalline oxides, with grassland exhibiting the highest transformation intensity. Conversion processes predominated over iron migration in the Quaternary red soils. The evolution of Quaternary red soils can be divided into three stages, marked by changes in iron composition and crystallization due to anthropogenic land use activities. Initially, during 140−94 ka BP, iron composition was stable. Then, between 94–24 ka BP, plant decomposition formed iron–metal complexes, releasing and crystallizing poorly crystalline iron oxides. Finally, from 24 ka BP to the present, anthropogenic activities intensified, increasing the formation and conversion rates of these oxides. This study quantifies iron migration and transformation in Quaternary red soils, providing insights for sustainable soil management, especially in regions where human activities have accelerated iron evolution. Based on these findings, the following policy recommendations are proposed: implement sustainable land use practices, encourage land management strategies that preserve natural vegetation, promote research on soil management techniques, develop and implement regulatory policies, and support educational programs to maintain the health and stability of Quaternary red soils, particularly in regions prone to accelerated iron evolution due to anthropogenic activities. [ABSTRACT FROM AUTHOR]

The frequent occurrence of meteorological disasters in China has caused huge losses to agriculture. Risk assessment serves as a bridge from disaster crisis management to disaster risk management. Therefore, it is necessary to carry out a refined comprehensive risk assessment of meteorological disasters in typical areas. However, several limitations remain in the disaster loss risk research, such as too coarse resolution and too single risk indicator. Additionally, less research has examined geographical information on risk clustering and barycenter migration, as well as temporal information on the sustainability of trends. Consequently, it is significant to unearth the geographical and temporal information on disaster loss and identify the refined spatial and temporal evolution pattern of crop risk. For this reason, we evaluated the risk of corn production in Gansu Province. First, based on maize yield data, a risk evaluation index system was constructed using the characteristics of variation trends, fluctuations, and extreme values of disaster losses. Then, the spatial distribution patterns and temporal evolution characteristics of maize production risks on a county scale in Gansu Province were determined using spatial analysis and climate diagnosis technology. The results show that there is a large interdecadal fluctuation in risk. In the 1980s, 1990s, 2000s, and 2010s, the average yield reduction rates of maize in Gansu Province were −11.8%, −12.6%, −8.7%, and −8.5%, and the proportions of counties with severe yield reduction were 34.8%, 44.4%, 20.8%, and 9.7%, respectively. Second, most counties belong to medium-low or low-risk areas for maize production. High-risk counties are primarily located in eastern and southern Gansu, whereas low-risk counties are mostly found along the Hexi Corridor. Third, most risk indicators exhibit some geographical aggregation. The Jiuquan region falls within the low-low-risk aggregation zone. In contrast, the Qingyang region is a high-high aggregation zone with a gradual expansion trend. Four, each risk indicator's geographical barycenter migrates over a complicated path, but the direction and distance vary considerably. The comprehensive risk migrates along the south-northwest-southeast trajectory, albeit at a shorter distance. Five, the proportion of counties with a medium, medium-severe, severe, and total yield reduction tended to decline. In addition, the annual precipitation is significantly or very significantly correlated with most risk indicators and the comprehensive risk level. The results can guide agricultural production processes at all levels, as well as government disaster prevention. [ABSTRACT FROM AUTHOR]

The change in agricultural soil organic carbon (SOC) at a global scale has a great impact on the soil quality, crop yields, and greenhouse gas concentration in the atmosphere. Plant-derived C input into soil is an effective strategy to increase the SOC; meanwhile, it promotes SOC mineralization. The SOC dynamics after plant-derived C input have received widespread attention in the past 20 years. This bibliometric study was performed to identify the basic characteristics, research output, and knowledge base as well as to understand the research trends and key topics of agricultural SOC mineralization. We collected data from the Web of Science Core Collection databases, with dates ranging from 2000 to 2022. The parameter calculated from the default indicators of bibliometric software tools was used to indicate the contribution of the journal/author/institution/countries. The activity and attractive index were calculated separately to evaluate the relative effort and impact made by a country. The results showed that: (1) the number of articles increased gradually during 2000–2010 and thereafter sharply increased; (2) Soil Biology & Biochemistry was the most representative journal, and agriculture was the most popular subject category; (3) the most productive institution was the Chinese Academy of Sciences, which is based China and cooperates closely with other institutions; (4) although the number of articles from China was the largest, both the cited frequency and activity index were much lower for China than for the USA, which had the highest citation and centrality among countries; and (5) the studies involving agricultural SOC mineralization have primarily investigated the effect of exogenous C and nutrient addition, as well as biotic processes, especially the microbial process. We concluded that there was an increasing trend in research on agricultural SOC mineralization, with a focus on the interaction between SOC and nutrient/microbial communities. The physical processes, such as the association of minerals and occlusion of aggregate and pores, were paid less attention relative to biotic processes despite their importance in SOC mineralization. Through an in-depth analysis of agricultural SOC mineralization research, this study provides a better understanding of development trends that have emerged in this field over the past 22 years. In future studies, more attention should be paid to the physical processes to understand the physical protection mechanism of agricultural SOC mineralization. [ABSTRACT FROM AUTHOR]

Climate change is one of the main problems currently strongly conditioning ecosystems all over the world. Coastal lagoons are amongst the most vulnerable habitats, and they are undergoing extensive human impact due to their high production rates and the close proximity of urban and agricultural centers. The Mar Menor, the largest saltwater lagoon in Europe, is an example of a highly impacted ecosystem. In December 2016 and September 2019, climate change-induced DANA (upper-level isolated atmospheric depression) flooding events took place there, temporarily altering the lagoon oceanographic properties. Data gathered throughout the lagoon (11 stations inside and 1 outside the lagoon) from 2016 to 2021 were analyzed in order to assess the variability of seawater parameters: salinity, density, chlorophyll-a, turbidity, and dissolved oxygen, due to DANA events. Results showed a change in seawater parameters that were reestablished at different rates, 4 and 10 months in 2016 and 2019, respectively, following a description of the environmental conditions and effects that have been reported after extreme rainfall in the lagoon. The amount of rainfall correlated with changes in the analyzed seawater parameters, such as an increase in turbidity and chlorophyll-a values. Furthermore, turbidity correlated with chlorophyll-a and oxygen saturation, while density correlated with salinity. Such extreme weather events are worsened by climate change, growing more frequent and between shorter intervals in time. In order to decelerate ecosystem decline, comprehensive management plans are needed to address the various factors that might add to anthropic impacts in natural environments. [ABSTRACT FROM AUTHOR]

With the continuous increase in plantation areas, the reduction of natural forest areas, and the unreasonable management of plantations by human beings, the service function of forest ecosystems has gradually reduced. Therefore, close-to-natural forestry has become important for the sustainable development of modern forestry. However, the differences in soil properties, enzyme activities, microbial diversities, and undergrowth vegetation species diversities have not been systematically explained for Chinese fir (Cunninghamia lanceolata). How do these indicators interact? The purpose of this paper was to study the difference in soil properties and biodiversity in different aged Chinese fir plantations and close-to-natural forests to explore their interactions and to provide direction for close-to-nature management. The results showed that the above indicators were significantly different in different aged Chinese fir plantations, soil pH, organic matter, total nitrogen, total phosphorus, total potassium, alkali-hydrolyzed nitrogen, available phosphorus concentrations, and urease activities in close-to-natural forests were significantly higher than plantations. It is worth mentioning that the richness of undergrowth vegetation species diversity (especially shrubs) and soil microbial diversities (especially fungi) in the close-to-natural forests were obviously higher than those in plantations. The correlation analysis results showed that the diversity of shrub species with respect to soil properties presented a higher correlation than herb species, the diversity of fungi with respect to soil properties presented a higher correlation than that observed for bacteria, and the diversity of fungi were significantly correlated with the diversity of undergrowth vegetation species diversities, but the correlation between bacteria and undergrowth vegetation species diversities was not significant. Our results suggest that the above factors are fundamental factors for the transformation of Chinese fir plantations to close-to-natural forests. To realize close-to-natural forestry, we must change the tree structure, combine the difference of those factors in different aged plantations, restore undergrowth vegetation species diversity, and thus improve microbial diversity and increase decomposition, transformation, and improvement of soil properties. [ABSTRACT FROM AUTHOR]

Vanadium dioxide (VO2), due to its electrically induced metal-to-insulator transition with dramatic changes in electrical and optical properties, is considered to be a powerful material for electro-optical devices. However, there are still some controversies about phase transition mechanism under voltage. Here, based on optical characterizations on VO2 crystal nanofilm during the whole process of phase transition, temporal evolution and spatial distribution of changes in electricity, optic and temperature are investigated simultaneously, to explore the mechanism. The variations of Raman spectrum and reflected spectrum, and changes in current and temperature are evidences for occurrence of phase transition, which exhibit different changing behaviors with time and space. These results offer a better understanding of the phase transition mechanism, implying that lattice structure of VO2 changes gradually after applying voltage until the structure is completely converted to metallic structure, which causes a rapid increase in carrier density, resulting in a rapid change in current, reflected spectrum and temperature. Temperature rise before phase transition and applied electric field alone are not enough for triggering metal-insulator transition, but these two factors can act synergistically on structural transformation to induce phase transition. [ABSTRACT FROM AUTHOR]

The aim of this review is to shed light on time and irreversibility, in order to link macroscopic to microscopic approaches to these complicated problems. After a brief summary of the standard notions of thermodynamics, we introduce some considerations about certain fundamental aspects of temporal evolution of out-of-equilibrium systems. Our focus is on the notion of entropy generation as the marked characteristic of irreversible behaviour. The concept of time and the basic aspects of the thermalization of thermal radiation, due to the interaction of thermal radiation with matter, are explored concisely from complementary perspectives. The implications and relevance of time for the phenomenon of thermal radiation and irreversible thermophysics are carefully discussed. The concept of time is treated from a different viewpoint, in order to make it as clear as possible in relation to its different fundamental problems. [ABSTRACT FROM AUTHOR]

The review is devoted to two important quantities characterizing many-body systems, order indices and the measure of entanglement production. Order indices describe the type of order distinguishing statistical systems. Contrary to the order parameters characterizing systems in the thermodynamic limit and describing long-range order, the order indices are applicable to finite systems and classify all types of orders, including long-range, mid-range, and short-range orders. The measure of entanglement production quantifies the amount of entanglement produced in a many-partite system by a quantum operation. Despite that the notions of order indices and entanglement production seem to be quite different, there is an intimate relation between them, which is emphasized in the review. [ABSTRACT FROM AUTHOR]

The purpose of this study is to illustrate intrinsic correlations and their temporal evolution between hydro-meteorological elements by building three-element-composed system, including precipitation (P), runoff (R), air temperature (T), evaporation (pan evaporation, E), and sunshine duration (SD) in the Wuding River Basin (WRB) in Loess Plateau, China, and to provide regional experience to correlational research of global hydro-meteorological data. In analysis, detrended partial cross-correlation analysis (DPCCA) and temporal evolution of detrended partial-cross-correlation analysis (TDPCCA) were employed to demonstrate the intrinsic correlation, and detrended cross-correlation analysis (DCCA) coefficient was used as comparative method to serve for performance tests of DPCCA. In addition, a novel way was proposed to estimate the contribution of a variable to the change of correlation between other two variables, namely impact assessment of correlation change (IACC). The analysis results in the WRB indicated that (1) DPCCA can analyze the intrinsic correlations between two hydro-meteorological elements by removing potential influences of the relevant third one in a complex system, providing insights on interaction mechanisms among elements under changing environment; (2) the interaction among P, R, and E was most strong in all three-element-composed systems. In elements, there was an intrinsic and stable correlation between P and R, as well as E and T, not depending on time scales, while there were significant correlations on local time scales between other elements, i.e., P-E, R-E, P-T, P-SD, and E-SD, showing the correlation changed with time-scales; (3) TDPCCA drew and highlighted the intrinsic correlations at different time-scales and its dynamics characteristic between any two elements in the P-R-E system. The results of TDPCCA in the P-R-E system also demonstrate the nonstationary correlation and may give some experience for improving the data quality. When establishing a hydrological model, it is suitable to only use P, R, and E time series with significant intrinsic correlation for calibrating model. The IACC results showed that taking pan evaporation as the representation of climate change (barring P), the impacts of climate change on the non-stationary correlation of P and R was estimated quantitatively, illustrating the contribution of climate to the correlation variation was 30.9%, and that of underlying surface and direct human impact accounted for 69.1%., Competing Interests: The authors declare no conflict of interest.

In urban areas, fine particulate matter (PM2.5) associated with local vehicle emissions can cause respiratory and cardiorespiratory disease and increased mortality rates, but less so in rural areas. However, Hong Kong may be a special case, since the whole territory often suffers from regional haze from nearby mainland China, as well as local sources. Therefore, to understand which areas of Hong Kong may be affected by damaging levels of fine particulates, PM2.5 data were obtained from March 2005 to February 2009 for urban, suburban, and rural air quality monitoring stations; namely Central (city area, commercial area, and urban populated area), Tsuen Wan (city area, commercial area, urban populated, and residential area), Tung Chung (suburban and residential area), Yuen Long (urban and residential area), and Tap Mun (remote rural area). To evaluate the relative contributions of regional and local pollution sources, the study aimed to test the influence of weather conditions on PM2.5 concentrations. Thus, meteorological parameters including temperature, relative humidity, wind speed, and wind directions were obtained from the Hong Kong Observatory. The results showed that Hong Kong's air quality is mainly affected by regional aerosol emissions, either transported from the land or ocean, as similar patterns of variations in PM2.5 concentrations were observed over urban, suburban, and rural areas of Hong Kong. Only slightly higher PM2.5 concentrations were observed over urban sites, such as Central, compared to suburban and rural sites, which could be attributed to local automobile emissions. Results showed that meteorological parameters have the potential to explain 80% of the variability in daily mean PM2.5 concentrations—at Yuen Long, 77% at Tung Chung, 72% at Central, 71% at Tsuen Wan, and 67% at Tap Mun, during the spring to summer part of the year. The results provide not only a better understanding of the impact of regional long-distance transport of air pollutants on Hong Kong's air quality but also a reference for future regional-scale collaboration on air quality management. [ABSTRACT FROM AUTHOR]

In this study, we investigated the characteristics of scour at complex bridge piers in close proximity. The experiments were performed under both clear-water and live-bed flow regimes. We compare our results with those for a single complex pier. Further, the performance of existing predictors is discussed. In this study, four typical pier arrangements were adopted, including side-by-side with aligned or 30° skewed flow, staggered, and tandem. The results show that the skew angle for a side-by-side arrangement significantly accelerates the clear-water scour development at all the vertical piles as well as between the piers, and the most scoured pile shifts from the upstream end to the downstream end of the upstream pier flank. The staggered and tandem pier arrangement show significant protection to the downstream pier for both the developing rate and the equilibrium scour depth. When the flow velocity exceeds the threshold for general bed motion, the clear-water scour pattern for all the pier arrangements may be altered significantly due to the upstream sediment supply, the weakened protection effect, and the enhanced flow contraction. The bed-forms migrate via the bridge opening and are damped gradually by the flow, and thus the response of the bed morphology under live-bed conditions is quite unsteady. [ABSTRACT FROM AUTHOR]

Despite achieving remarkable development, China's agricultural economy has been under severe environmental pressure. Based on previous studies, the present study further considers the sources of agricultural carbon emissions in depth, estimates China's agricultural carbon emissions from 1997 to 2016, and analyzes the agricultural pollution faced by China and its provinces. The study estimates the amount and intensity of agricultural carbon emissions in China from five carbon sources-agricultural materials, rice planting, soil N 2 O, livestock and poultry farming, and straw burning-and analyzes their spatial and temporal characteristics. The following results were obtained: (1) between 1997 and 2016, the amount of agricultural carbon emissions in China generally increased, while the intensity of agricultural carbon emissions decreased; (2) in the same period, the amount of carbon emissions from each category of carbon source generally increased, with the exception of rice planting; however, the amount of emissions fluctuated; (3) the amount and intensity of carbon emissions varied greatly among provinces; (4) the emissions from different categories of carbon source showed different concentration trends and agglomeration forms; (5) China's agricultural carbon emissions showed obvious spatial correlation, which overall was high-high agglomeration; however, its carbon emissions gradually weakened, and the spatial agglomeration of agricultural carbon emissions in each province changed between 1997 and 2016.

Improvements of manufacturability and living standard driven by industrialization and urbanization typically cause a spike in total energy consumption (TEC) and related carbon emissions (TCEM). However, there have been few comparative studies to include industrial and residential energy consumption (IEC and REC, respectively) and related carbon emissions (ICEM and RCEM, respectively). Since China is a major emerging industrial country wherein urbanization is still ongoing, the present study was conducted in an attempt to analyze the temporal evolution of China's continued energy consumption and related carbon emissions regarding both industrialization and urbanization. The influencing factors of TCEM, RCEM and ICEM are determined via the log-mean divisia index (LMDI) model. The results showed that both TEC and TCEM gradually increased (apart from a slight decrease in 2014); REC and RCEM increased steadily with no sharp peak; while IEC and ICEM declined sharply. TCEM was positively affected by economic output, consumption level, and population size; the influence of consumption level became more and more significant. Per capita GDP and per capita expenditure were the most significant driving factors for RCEM, while industrial added value (IAV) was the main driving factor for ICEM. The temporal evolution and influencing factors of energy consumption and carbon emissions had stage-related characteristics in accordance with Shanghai's three stages of development. The Shanghai case study provided a comprehensive understanding of energy consumption and related carbon emissions from the dual perspective of industrialization and urbanization. [ABSTRACT FROM AUTHOR]