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Soil visible and near–infrared reflectance spectroscopy is an effective tool for the rapid estimation of soil organic carbon (SOC). The development of spectroscopic technology has increased the application of spectral libraries for SOC research. However, the direct application of spectral libraries for SOC prediction remains challenging due to the high variability in soil types and soil–forming factors. This study aims to address this challenge by improving SOC prediction accuracy through spectral classification. We utilized the European Land Use and Cover Area frame Survey (LUCAS) large–scale spectral library and employed a geographically weighted principal component analysis (GWPCA) combined with a fuzzy c–means (FCM) clustering algorithm to classify the spectra. Subsequently, we used partial least squares regression (PLSR) and the Cubist model for SOC prediction. Additionally, we classified the soil data by land cover types and compared the classification prediction results with those obtained from spectral classification. The results showed that (1) the GWPCA–FCM–Cubist model yielded the best predictions, with an average accuracy of R2 = 0.83 and RPIQ = 2.95, representing improvements of 10.33% and 18.00% in R2 and RPIQ, respectively, compared to unclassified full sample modeling. (2) The accuracy of spectral classification modeling based on GWPCA–FCM was significantly superior to that of land cover type classification modeling. Specifically, there was a 7.64% and 14.22% improvement in R2 and RPIQ, respectively, under PLSR, and a 13.36% and 29.10% improvement in R2 and RPIQ, respectively, under Cubist. (3) Overall, the prediction accuracy of Cubist models was better than that of PLSR models. These findings indicate that the application of GWPCA and FCM clustering in conjunction with the Cubist modeling technique can significantly enhance the prediction accuracy of SOC from large–scale spectral libraries. [ABSTRACT FROM AUTHOR]

The loss functions are softmax cross entropy (softmax), weighted log loss, dice coefficient (dice), and dice coefficient added with binary cross entropy (bce). The loss functions are softmax cross entropy (softmax), weighted log loss, dice coefficient (dice), and dice coefficient added with binary cross entropy (bce). Figures and Tables Graph: Figure 9 Progression of loss values (A) and training accuracy (B) for four loss functions used with Nested SE-Deeplab during training. [Extracted from the article]

Soil pollution by potentially toxic elements (PTEs) has become a core issue around the world. Knowledge of the spatial distribution of PTEs in soil is crucial for soil remediation. Portable X-ray fluorescence spectroscopy (p-XRF) provides a cost-saving alternative to the traditional laboratory analysis of soil PTEs. In this study, we collected 293 soil samples from Fuyang County in Southeast China. Subsequently, we used several geostatistical methods, such as inverse distance weighting (IDW), ordinary kriging (OK), and empirical Bayesian kriging (EBK), to estimate the spatial variability of soil PTEs measured by the laboratory and p-XRF methods. The final maps of soil PTEs were outputted by the model averaging method, which combines multiple maps previously created by IDW, OK, and EBK, using both lab and p-XRF data. The study results revealed that the mean PTE content measured by the laboratory methods was as follows: Zn (127.43 mg kg−1) > Cu (31.34 mg kg−1) > Ni (20.79 mg kg−1) > As (10.65 mg kg−1) > Cd (0.33 mg kg−1). p-XRF measurements showed a spatial prediction accuracy of soil PTEs similar to that of laboratory analysis measurements. The spatial prediction accuracy of different PTEs outputted by the model averaging method was as follows: Zn (R2 = 0.71) > Cd (R2 = 0.68) > Ni (R2 = 0.67) > Cu (R2 = 0.62) > As (R2 = 0.50). The prediction accuracy of the model averaging method for five PTEs studied herein was improved compared with that of the laboratory and p-XRF methods, which utilized individual geostatistical methods (e.g., IDW, OK, EBK). Our results proved that p-XRF was a reliable alternative to the traditional laboratory analysis methods for mapping soil PTEs. The model averaging approach improved the prediction accuracy of the soil PTE spatial distribution and reduced the time and cost of monitoring and mapping PTE soil contamination. [ABSTRACT FROM AUTHOR]

Automatic road extraction from very-high-resolution remote sensing images has become a popular topic in a wide range of fields. Convolutional neural networks are often used for this purpose. However, many network models do not achieve satisfactory extraction results because of the elongated nature and varying sizes of roads in images. To improve the accuracy of road extraction, this paper proposes a deep learning model based on the structure of Deeplab v3. It incorporates squeeze-and-excitation (SE) module to apply weights to different feature channels, and performs multi-scale upsampling to preserve and fuse shallow and deep information. To solve the problems associated with unbalanced road samples in images, different loss functions and backbone network modules are tested in the model's training process. Compared with cross entropy, dice loss can improve the performance of the model during training and prediction. The SE module is superior to ResNext and ResNet in improving the integrity of the extracted roads. Experimental results obtained using the Massachusetts Roads Dataset show that the proposed model (Nested SE-Deeplab) improves F1-Score by 2.4% and Intersection over Union by 2.0% compared with FC-DenseNet. The proposed model also achieves better segmentation accuracy in road extraction compared with other mainstream deep-learning models including Deeplab v3, SegNet, and UNet. [ABSTRACT FROM AUTHOR]

Wise soil management requires detailed soil information, but conventional soil class mapping in a rather coarse spatial resolution cannot meet the demand for precision agriculture. With the advantages of non-destructiveness, rapid cost-efficiency, and labor savings, the spectroscopic technique has proved its high potential for success in soil classification. Previous studies mainly focused on predicting soil classes using a single sensor. In this study, we attempted to compare the predictive ability of visible near infrared (vis-NIR) spectra, mid-infrared (MIR) spectra, and their fused spectra for soil classification. A total of 146 soil profiles were collected from Zhejiang, China, and the soil properties and spectra were measured by their genetic horizons. Along with easy-to-measure auxiliary soil information (soil organic matter, soil texture, color and pH), four spectral data, including vis-NIR, MIR, their simple combination (vis-NIR-MIR), and outer product analysis (OPA) fused spectra, were used for soil classification using a multiple objectives mixed support vector machine model. The independent validation results showed that the classification model using MIR (accuracy of 64.5%) was slightly better than that using vis-NIR (accuracy of 64.2%). The predictive model built on vis-NIR-MIR did not improve the classification accuracy, having the lowest accuracy of 61.1%, which likely resulted from an over-fitting problem. The model based on OPA fused spectra performed best with an accuracy of 68.4%. Our results prove the potential of fusing vis-NIR and MIR using OPA for improving prediction ability for soil classification. [ABSTRACT FROM AUTHOR]

Soil salinization is a global issue resulting in soil degradation, arable land loss and ecological environmental deterioration. Over the decades, multispectral and hyperspectral remote sensing have enabled efficient and cost-effective monitoring of salt-affected soils. However, the potential of hyperspectral sensors installed on an unmanned aerial vehicle (UAV) to estimate and map soil salinity has not been thoroughly explored. This study quantitatively characterized and estimated field-scale soil salinity using an electromagnetic induction (EMI) equipment and a hyperspectral camera installed on a UAV platform. In addition, 30 soil samples (0~20 cm) were collected in each field for the lab measurements of electrical conductivity. First, the apparent electrical conductivity (ECa) values measured by EMI were calibrated using the lab measured electrical conductivity derived from soil samples based on empirical line method. Second, the soil salinity was quantitatively estimated using the random forest (RF) regression method based on the reflectance factors of UAV hyperspectral images and satellite multispectral data. The performance of models was assessed by Lin's concordance coefficient (CC), ratio of performance to deviation (RPD), and root mean square error (RMSE). Finally, the soil salinity of three study fields with different land cover were mapped. The results showed that bare land (field A) exhibited the most severe salinity, followed by dense vegetation area (field C) and sparse vegetation area (field B). The predictive models using UAV data outperformed those derived from GF-2 data with lower RMSE, higher CC and RPD values, and the most accurate UAV-derived model was developed using 62 hyperspectral bands of the image of the field A with the RMSE, CC, and RPD values of 1.40 dS m−1, 0.94, and 2.98, respectively. Our results indicated that UAV-borne hyperspectral imager is a useful tool for field-scale soil salinity monitoring and mapping. With the help of the EMI technique, quantitative estimation of surface soil salinity is critical to decision-making in arid land management and saline soil reclamation. [ABSTRACT FROM AUTHOR]

Soil organic matter (SOM) and pH are essential soil fertility indictors of paddy soil in the middle-lower Yangtze Plain. Rapid, non-destructive and accurate determination of SOM and pH is vital to preventing soil degradation caused by inappropriate land management practices. Visible-near infrared (vis-NIR) spectroscopy with multivariate calibration can be used to effectively estimate soil properties. In this study, 523 soil samples were collected from paddy fields in the Yangtze Plain, China. Four machine learning approaches—partial least squares regression (PLSR), least squares-support vector machines (LS-SVM), extreme learning machines (ELM) and the Cubist regression model (Cubist)—were used to compare the prediction accuracy based on vis-NIR full bands and bands reduced using the genetic algorithm (GA). The coefficient of determination (R2), root mean square error (RMSE), and ratio of performance to inter-quartile distance (RPIQ) were used to assess the prediction accuracy. The ELM with GA reduced bands was the best model for SOM (SOM: R2 = 0.81, RMSE = 5.17, RPIQ = 2.87) and pH (R2 = 0.76, RMSE = 0.43, RPIQ = 2.15). The performance of the LS-SVM for pH prediction did not differ significantly between the model with GA (R2 = 0.75, RMSE = 0.44, RPIQ = 2.08) and without GA (R2 = 0.74, RMSE = 0.45, RPIQ = 2.07). Although a slight increase was observed when ELM were used for prediction of SOM and pH using reduced bands (SOM: R2 = 0.81, RMSE = 5.17, RPIQ = 2.87; pH: R2 = 0.76, RMSE = 0.43, RPIQ = 2.15) compared with full bands (R2 = 0.81, RMSE = 5.18, RPIQ = 2.83; pH: R2 = 0.76, RMSE = 0.45, RPIQ = 2.07), the number of wavelengths was greatly reduced (SOM: 201 to 44; pH: 201 to 32). Thus, the ELM coupled with reduced bands by GA is recommended for prediction of properties of paddy soil (SOM and pH) in the middle-lower Yangtze Plain. [ABSTRACT FROM AUTHOR]

Heavy metal (HM) contamination and accumulation is a serious problem around the world due to the toxicity, abundant sources, non-biodegradable properties, and accumulative behaviour of HMs. The degree of soil HM contamination in China, especially in the Yangtze River Delta, is prominent. In this study, 1822 pairs of soil and crop samples at corresponding locations were collected from the southern Yangtze River Delta of China, and the contents of Ni, Cr, Zn, Cd, As, Cu, Hg, and Pb were measured. The single pollution index in soil (SPI) and Nemerow composite pollution index (NCPI) were used to assess the degree of HM pollution in soil, and the crop pollution index (CPI) was used to explore the degree of HM accumulation in crops. The bioaccumulation factor (BAF) was used to investigate the translocation of heavy metals in the soil-crop system. The health risks caused by HMs were calculated based on the model released by the U.S. Environmental Protection Agency. The SPIs of all elements were at the unpolluted level. The mean NCPI was at the alert level. The mean CPIs were in the following decreasing order: Ni (1.007) > Cr (0.483) > Zn (0.335) > Cd (0.314) > As (0.232) > Cu (0.187) > Hg (0.118) > Pb (0.105). Only the mean content of Ni in the crops exceeded the national standard value. The standard exceeding rates were used to represent the percentage of samples whose heavy metal content is higher than the corresponding national standard values. The standard exceeding rates of Cu, Hg, and Cd in soil were significantly higher than corresponding values in crops. Meanwhile, the standard exceeding rates of Ni, As, and Cr in crops were significantly higher than corresponding values in soil. The chronic daily intake (CDI) of children (13.8 × 10 -3 ) was the largest among three age groups, followed by adults (6.998 × 10 -4 ) and seniors (5.488 × 10 -4 ). The bioaccumulation factors (BAFs) of all crops followed the order Cd (0.249) > Zn (0.133) > As (0.076) > Cu (0.064) > Ni (0.018) > Hg (0.011) > Cr (0.010) > Pb (0.001). Therefore, Cd was most easily absorbed by crops, and different crops had different capacities to absorb HMs. The hazard quotient (HQ) represents the potential non-carcinogenic risk for an individual HM and it is an estimation of daily exposure to the human population that is not likely to represent an appreciable risk of deleterious effects during a lifetime. All the HQs of the HMs for the different age groups were significantly less than the alert value of 1.0 and were at a safe level. This indicated that citizens in the study area face low potential non-carcinogenic risk caused by HMs. The total carcinogens risks (TCRs) for children, adults, and seniors were 5.24 × 10 -5 , 2.65 × 10 -5 , and 2.08 × 10 -5 , respectively, all of which were less than the guideline value but at the alert level. Ingestion was the main pathway of carcinogen risk to human health., Competing Interests: The authors have declared that no competing interests exist. The founding sponsors had no role in the design of the study; in the collection, analyses, or interpretation of data; in the writing of the manuscript; or in the decision to publish the results.