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Effectively encapsulating perovskite solar cells (PSCs) to enhance the external reliability is the key towards commercialization. We herein propose a facile encapsulation method by introducing conductive ribbons and a polyethylene terephthalate (PET) backsheet on both sides of PSC. Via applying thermoplastic polyolefin (TPO) encapsulant, we implemented PSCs with fine encapsulation, enabling considerable durability in the ambient atmosphere and even with water immersion, demonstrating almost no degradation in the device output, which is ascribed to the low water vapor transmission rate as well as the high chemical stability of TPO. The operation reliability of the encapsulated cell is also significantly increased, maintaining 80% of the initial efficiency after 770 hours' light illumination in an ambient atmosphere. This novel encapsulation route provides a feasible idea for the commercial application of PSCs in the future. [ABSTRACT FROM AUTHOR]

Reducing the interfacial defects between the perovskite/electron transport layer (ETL) is the key point to improving the efficient and stable performance of perovskite solar cells (PSCs). In this study, two self-assembled molecules ((aminomethyl)phosphonic acid and glycine) with different functional groups (phosphonic acid (-H2PO3) and carboxylic acid (-COOH)) were mixed to form the buried bottom interface of PSCs. The synergistic effect of -H2PO3 with its higher anchoring ability and -COOH with its fast carrier transport improved the performance of PSCs. Additionally, the SnO2 modified by mixed self-assembly molecules (M-SAM) showed a more appropriate energy level alignment, favoring charge transport and minimizing energy loss. In addition, the amine group (-NH2) on the two small molecules effectively interacted with uncoordinated Pb2+ in perovskite and improved the quality of the perovskite films. Consequently, the (FAPbI3)0.992(MAPbBr3)0.008 PSCs with M-SAM reached a PCE of 24.69% (0.08 cm2) and the perovskite modules achieved a champion efficiency of 18.57% (12.25 cm2 aperture area). Meanwhile, it still maintained more than 91% of its initial PCE after being placed in nitrogen atmosphere at 25 °C for 1500 h, which is better than that of the single-SAM and control devices. Further reference is provided for the future commercialization of perovskite with efficient and stable characteristics. [ABSTRACT FROM AUTHOR]

In this study, we investigated two waveform design problems for a dual-functional radar communication (DFRC) system, taking into consideration different constrained communication quality-of-service (QoS) requirements. Our objective was to minimize the mean-square error (MSE) of radar beampattern matching as the cost function. To this end, the multi-user interference (MUI) energy constraint and constructive interference (CI) constraint were, respectively, formulated to ensure the communication QoS. It is important to note that we designed a strict per-user MUI energy constraint at each sampling moment to achieve more accurate control over communication performance. Additionally, we introduced a constant-modulus constraint to optimize the efficiency of the radio frequency (RF) amplifier. To tackle the nonconvex waveform design problems encountered, we employed the alternative direction methods of multipliers (ADMM) technique. This allowed us to decompose the original problem into two solvable subproblems, which were then solved using the majorization–minimization (MM) method and geometrical structure. Finally, we obtained extensive simulation results which demonstrate the effectiveness and superiority of the proposed algorithm. [ABSTRACT FROM AUTHOR]