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Coal gangue and aluminum ash emerge as quintessential constituents within the ambit of coal-derived solid waste and industrial residue, respectively. Leveraging coal gangue as a primary substrate and aluminum ash as an adjunct aluminum source, molecular sieves can be synthesized through hydrothermal means. By modulating the dosage of aluminum ash, molecular sieves with varying crystalline structures can be obtained. The synthesized LTA-type molecular sieves manifest in two distinct morphologies: regular tetrahedral and stratified spherical stacking, evincing commendable Cu2+ adsorption efficacy. The Cu2+ adsorption phenomenon predominantly transpires via chemisorption, albeit with ancillary manifestations of physical adsorption. The valorization of coal gangue and aluminum ash towards the synthesis of molecular sieves not only underscores the elevation of industrial solid waste towards high-value utility, but also underscores the praxis of waste remediation through upcycling. [ABSTRACT FROM AUTHOR]

Landslide susceptibility mapping based on static influence factors often exhibits issues of low accuracy and classification errors. To enhance the accuracy of susceptibility mapping, this study proposes a refined approach that integrates categorical boosting (CatBoost) with small baseline subset interferometric synthetic-aperture radar (SBAS-InSAR) results, achieving more precise and detailed susceptibility mapping. We utilized optical remote sensing images, the information value (IV) model, and fourteen influencing factors (elevation, slope, aspect, roughness, profile curvature, plane curvature, lithology, distance to faults, land use type, normalized difference vegetation index (NDVI), topographic wetness index (TWI), distance to rivers, distance to roads, and annual precipitation) to establish the IV-CatBoost landslide susceptibility mapping method. Subsequently, the Sentinel-1A ascending data from January 2021 to March 2023 were utilized to derive the deformation rates within the city of Lishui in the southern region of China. Based on the outcomes derived from IV-CatBoost and SBAS-InSAR, a discernment matrix was formulated to rectify inaccuracies in the partitioned regions, leading to the creation of a refined information value CatBoost integration (IVCI) landslide susceptibility mapping model. In the end, we utilized optical remote sensing interpretations alongside surface deformations obtained from SBAS-InSAR to cross-verify the excellence and accuracy of IVCI. Research findings indicate a distinct enhancement in susceptibility levels across 165,784 grids (149.20 km2) following the integration of SBAS-InSAR correction. The enhanced susceptibility classes and the spectral characteristics of remote sensing images closely correspond to the trends of SBAS-InSAR cumulative deformation, reflecting a high level of consistency with field-based conditions. These improved classifications effectively enhance the refinement of landslide susceptibility mapping. The refined susceptibility mapping approach proposed in this paper effectively enhances landslide prediction accuracy, providing valuable technical reference for landslide hazard prevention and control in the Lishui region. [ABSTRACT FROM AUTHOR]

Anisotropic permeability is of great significance for assessing the consolidation and drainage mode of soil layers in reclamation areas, as well as for preventing and controlling ground settlement after project construction. This paper analyzes the anisotropic permeability of the inland and nearshore soil layers in Chongming East Shoal, Shanghai, and the formation mechanism of anisotropic permeability through permeability and scanning electron microscope (SEM) tests. The results highlight that compared with dredger fill and sandy silt, the horizontal permeability coefficient of underlying soft clay (USC) is significantly higher than its vertical permeability coefficient, which is more significant in nearshore USC. Interestingly, the upper clay (21.5 m) in the thickest clay layer shows greater anisotropic permeability than the lower clay (41.5 m). Due to the instability of seepage channels, the USC anisotropic permeability increases in a fluctuating manner as the hydraulic gradient increases. Microstructural parameters are used to reveal the mechanism of anisotropic permeability, which shows that a simple soil skeleton and structure, strong particle orientation, decreased particle abundance, increased particle roundness, decreased particle contact area, and increased pore area all contribute to the enhancement of permeability. Moreover, micro-parameters have been proposed to evaluate anisotropic permeability in terms of the effective seepage-pore area. This approach addresses the constraint of water films on the permeability efficiency of USC particles. [ABSTRACT FROM AUTHOR]

Snow plays an important role in catastrophic weather, climate change, and water recycling. In order to analyze the ability of different land surface models to simulate snow depth in China, we used atmospheric forcing data from the China Meteorological Administration (CMA) Land Data Assimilation System (CLDAS) to drive the CLM3.5 (the Community Land Model version 3.5), Noah (NCEP, OSU, Air Force and Office of Hydrology Land Surface Model), and Noah-MP (the community Noah land surface model with multi-parameterization options) land surface models. We also used 2380 daily snow-depth site observations of CMA to analyze the simulation effects of different models on the snow depth in China and different regions during the periods of snow accumulation and snowmelt from 2015 to 2019. The results show that CLM3.5, Noah, and Noah-MP can simulate the spatial distribution of the snow depth in China, but there are some differences between the models. In particular, the snow depth and snow cover simulated by CLM3.5 are lower than those simulated by Noah and Noah-MP in Northwest China and the Tibetan Plateau. From the overall quantitative assessment results for China, the snow depth simulated by CLM3.5 is underestimated, while that simulated by Noah is overestimated. Noah-MP has the best overall performance; for example, the biases of the three models during the snow-accumulation periods are −0.22 cm, 0.27 cm, and 0.15 cm, respectively. Furthermore, the three models perform differently in the three snowpack regions of Northeast China, Northwest China, and the Tibetan Plateau; Noah-MP has the best snow-depth performance in Northeast China, while CLM3.5 has the best snow-depth performance in the Tibetan Plateau region. Noah-MP performs best in the snow-accumulation period, and Noah performs best in the snowmelt period for Northwest China. In conclusion, no single model can perform optimally for snow simulations in different regions of China and at different times of the year, and the multi-model integration of snow may be an effective way to obtain high-quality snow simulation results. So this study provides some scientific references for the spatiotemporal evolution of snow in the context of climate change, monitoring and analysis of snow, the study of land surface models for snow, and the sustainable development and utilization of snow resources in China and other regions. [ABSTRACT FROM AUTHOR]

Artificial reclamation is one of the main means of land expansion in coastal cities. However, the permeability of underlying soft clay (USC), derived from the dredged load, has not been paid enough attention, although it is closely related to the long-term deformation and stability of foundation soil. Hence, this paper analyzes the relationship between permeability characteristics and microscopic pore characteristics of USC in Chongming East Shoal (CES), a typical multi-phase reclamation area, through a variable head permeability test, mercury intrusion porosimetry (MIP) test, and scanning electron microscope (SEM) test. Furthermore, grey relation entropy and Pearson correlation analysis are implemented to analyze the influence of micropore parameters on permeability. The results revealed that the seepage process of clay showed a transition from unstable seepage to relatively stable seepage. Meanwhile, the permeability coefficient (PC) attenuated with time cyclically, indicating the alternating effect of the closed and opened unstable seepage channels. During seepage, clay particles could be entrained by pore water and intercepted by pores, thus clogging seepage channels. Then, the increased pore water pressure could break through new seepage channels. The degree of pore clogging was positively correlated with the average cycle period of PCs, and this was also present in the relatively stable stage of PCs. A lower mesopores content, higher fractal dimension, and aggregated flocculate microstructure could promote the clogging effect and result in lower permeability efficiency. Affected by unstable seepage channels, soft clay may face long-term potential deformation in the future, which needs further investigation. [ABSTRACT FROM AUTHOR]

In this paper, the influence of calcium on coal gangue and fly ash geopolymer is explored, and the problem of low utilization of unburned coal gangue is analyzed and solved. The experiment took uncalcined coal gangue and fly ash as raw materials, and a regression model was developed with the response surface methodology. The independent variables were the CG content, alkali activator concentration, and Ca(OH)2 to NaOH ratio (CH/SH). The response target value was the coal gangue and fly-ash geopolymer compressive strength. The compressive strength tests and the regression model obtained by the response surface methodology showed that the coal gangue and fly ash geopolymer prepared with the content of uncalcined coal gangue is 30%, alkali activator content of 15%, and the value of CH/SH is 1.727 had a dense structure and better performance. The microscopic results demonstrated that the uncalcined coal gangue structure is destroyed under an alkali activator's action, and a dense microstructure is formed based on C(N)-A-S-H and C-S-H gel, which provides a reasonable basis for the preparation of geopolymers from the uncalcined coal gangue. [ABSTRACT FROM AUTHOR]

The iron and steel industry is a high-energy consumption and high-pollution industry. Energy recovery in its process is of great significance. Converter gas is an important by-product in the process of iron and steel production. It is difficult to take effective measures to recover waste heat from converter gas due to its flammability. In this paper, a new technology is proposed based on waste heat recovery by a filled bulb regenerator. The mathematical model of heat transfer and flow in the compound regenerator for converter gas containing dust is established. The effects of the diameter and concentration of dust to heat transfer and flow are discussed. The results show that the temperature of converter gas declined to 132 °C, and recovery efficiency was above 90% using this technology system. Resistance loss increased by 25% due to the dust; with the increase in the diameter and initial concentration of dust, the heat transfer rate in the regenerator was reinforced. At the entrance of the regenerator, dust's effects are more obvious, and the efficiency of heat transfer is increased by 4.5–8.5%. The results can provide a theoretical basis for a new converter gas waste heat recovery method. [ABSTRACT FROM AUTHOR]

Land reclamation has been increasingly employed in many coastal cities to resolve issues associated with land scarcity and natural hazards. Especially, land subsidence is a non-negligible environmental geological problem in reclamation areas, which is essentially caused by soil consolidation. However, spatial-scale evaluation on the average degree of consolidation (ADC) of soil layers and the effects of soil consolidation on land subsidence have rarely been reported. This study aims to carry out the integrated analysis on soil consolidation and subsidence mechanism in Chongming East Shoal (CES) reclamation area, Shanghai, at spatial-, macro-, and micro-scale so that appropriate guides can be provided to resist the potential environmental hazards. The interferometric synthetic aperture radar (InSAR) technique was utilized to retrieve the settlement curves of the selected onshore (Ra) and offshore (Rb) areas. Then, the hyperbolic (HP) model and three-point modified exponential (TME) model were combined applied to predict the ultimate settlement and to determine the range of ADC rather than a single pattern. With two boreholes Ba and Bb set within Ra and Rb, conventional tests, MIP test, and SEM test were conducted on the collected undisturbed soil to clarify the geological features of exposed soil layers and the micro-scale pore and structure characteristics of representative compression layer. The preliminary results showed that the ADC in Rb (93.1–94.1%) was considerably higher than that in Ra (60.8–78.7%); the clay layer was distinguished as the representative compression layer; on micro-scale, the poor permeability conditions contributed to the low consolidation efficiency and slight subsidence in Rb, although there was more compression space. During urbanization, the offshore area may suffer from potential subsidence when it is subjected to an increasing ground load, which requires special attention. [ABSTRACT FROM AUTHOR]

Perforation behavior of 3 mm/3 mm double-spaced aluminum plates by PTFE/Al/W (Polytetrafluoroethylene/Aluminum/Tungsten) reactive projectiles with densities ranging from 2.27 to 7.80 g/cm3 was studied experimentally and theoretically. Ballistic experiments show that the failure mode of the front plate transforms from petalling failure to plugging failure as projectile density increases. Theoretical prediction of the critical velocities for the reactive projectiles perforating the double-spaced plates is proposed, which is consistent with the experimental results and well represents the perforation performance of the projectiles. Dimensionless formulae for estimating the perforation diameter and deflection height of the front plates are obtained through dimensional analysis, indicating material density and strength are dominant factors to determine the perforation size. High-speed video sequences of the perforation process demonstrate that high-density reactive projectiles make greater damage to the rear plates because of the generation of projectile debris streams. Specifically, the maximum spray angle of the debris streams and the crater number in the debris concentration area of the rear plate both increase with the projectile density and initial velocity. [ABSTRACT FROM AUTHOR]

Two different preparation methods, viz. incipient impregnation and mechanical mixing, have been used to prepare V-based oxygen carriers with different V loadings for chemical looping oxidative dehydrogenation of propane. The effect of the preparation method, V loading, and reaction temperature on the performance of these oxygen carriers have been measured and discussed. It was found that the VOx species can be well distributed on the support when the V loading is low (5 wt.% and 10 wt.%), but they may become aggregated at higher loadings. For oxygen carriers with a higher V loading, the oxygen transport capacity of the oxygen carrier, propane conversion and COx selectivities increase, while the propylene selectivity decreases. With a V-loading of 10 wt.%, the maximum propylene yield was achieved. The VOx species were better distributed over the support when applying the impregnation method; however, at higher V loadings the V-based oxygen carriers prepared by mechanical mixing showed a larger oxygen transport capacity. The oxygen carriers prepared by impregnation showed a better performance for the oxidative dehydrogenation of propane (ODHP) and re-oxidation reactions compared to oxygen carriers prepared by mechanical mixing. Higher reaction temperatures are favorable for the re-oxidation reaction, but unfavorable for the propylene production. [ABSTRACT FROM AUTHOR]

In this research, the bulk density homogenization and impact initiation characteristics of porous PTFE/Al/W reactive materials were investigated. Cold isostatic pressed (CIPed) and hot temperature sintered (HTSed) PTFE/Al/W reactive materials of five different theoretical maximum densities were fabricated via the mixing/pressing/sintering process. Mesoscale structure characteristics of the materials fabricated under different molding pressures were compared while the effect of molding pressures on material bulk densities was analyzed as well. By using the drop weight testing system, effects of the theoretical maximum densities (TMDs), drop heights and molding pressures on the impact initiation characteristics were studied. Quantitatively, characteristic drop heights (H50) for different types of materials were obtained. The two most significant findings of this research are the density homogenization zone and the sensitivity transition zone, which would provide meaningful guides for further design and fabrication of reactive materials. [ABSTRACT FROM AUTHOR]

With the development of the economy, land reclamation, as a result of dredged soil, has become an effective measure to alleviate land scarcity in many coastal cities around the world. Chongming East Shoal (CES), a typical reclamation area in Shanghai that is formed by multi-phase reclamation projects, was selected as the study area. The small baseline subset–interferometry synthetic aperture radar (SBAS-InSAR) method was applied to derive the map of velocity distribution and accumulated deformation with 70 Sentinel-1 synthetic aperture radar (SAR) images collected from 22 March 2015 to 2 December 2019. In addition, 25 undisturbed soil samples, including dredger fill and underlying soil layers, were collected from five boreholes (maximum depth 55 m) through a field investigation. Laboratory tests were then performed on all soil samples in order to facilitate an understanding of geological features, including the measurement of basic physical properties, cation exchange capacity, compressibility, microscale structure, and pores. The present results show that the whole CES was undergoing differential ground deformation, with a velocity ranging from −47.5 to 34.6 mm/y. Fast (−3.4 mm/y) to slow (−0.3 mm/y) mean subsidence velocities were detected in multi-phase reclamation areas from inland areas to the coastline, and were controlled by building load and geological features of soil layers. Urbanization is the main factor that triggers accelerated subsidence and should receive special attention for reclamation areas that have been finished for a long time (over 20 years in this study). The geological features indicated that poor drainage conditions in offshore soil layers resulted in slow subsidence. The field investigation and laboratory test can be powerful explanatory tools to monitor the results from a mechanical perspective. [ABSTRACT FROM AUTHOR]

In this paper, the reaction characteristic of a novel reactive material, which introduced bismuth trioxide (Bi2O3) into traditional polytetrafluoroethylene/aluminum (PTFE/Al), is studied. The effect of Bi2O3 with different content and particle size on the reaction behaviors of PTFE/Al/Bi2O3 are investigated by drop-weight test and X-ray diffractometer (XRD), including impact sensitivity, energy release performance under a certain impact, and reaction mechanism. The experimental results show that the content of Bi2O3 increased from 0% to 35.616%, the characteristic drop height of impact sensitivity (H50) of PTFE/Al/Bi2O3 reactive materials decreased first and then increased, and the minimum H50 of all types of materials in the experiment is 0.74 times that of PTFE/Al, and the particle size of Bi2O3 affects the rate of H50 change with Bi2O3 content. Besides, with the increase of Bi2O3 content, both the reaction intensity and duration first increase and then decrease, and there is optimum content of Bi2O3 maximizing the reaction degree of the PTFE/Al/Bi2O3. Furthermore, a prediction model for the impact sensitivity of PTFE-based reactive material is developed. The main reaction products include AlF3, xBi2O3·Al2O3, and Bi. [ABSTRACT FROM AUTHOR]

The traditional polytetrafluoroethylene (PTFE)/Al reactive material liner shaped charge generally produces insufficient penetration depth, although it enlarges the penetration hole diameter by chemical energy release inside the penetration crater. As such, a novel high-density reactive material liner based on the PTFE matrix was fabricated, and the corresponding penetration performance was investigated. Firstly, the PTFE/W/Cu/Pb high-density reactive material liner was fabricated via a cold pressing/sintering process. Then, jet formation and penetration behaviors at different standoffs were studied by pulse X-ray and static experiments, respectively. The X-ray results showed that the PTFE/W/Cu/Pb high-density reactive material liner forms an excellent reactive jet penetrator, and the static experimental results demonstrated that the penetration depth of this high-density reactive jet increased firstly and then decreased by increasing the standoff. When the standoff was 1.5 CD (charge diameter), the penetration depth of this reactive jet reached 2.82 CD, which was significantly higher than that of the traditional PTFE/Al reactive jet. Moreover, compared with the conventional metal copper jet penetrating steel plates, the entrance hole diameter caused by this high-density reactive jet improved 29.2% at the same standoff. Lastly, the chemical reaction characteristics of PTFE/W/Cu/Pb reactive materials were analyzed, and a semi-empirical penetration model of the high-density reactive jet was established based on the quasi-steady ideal incompressible fluid dynamics theory. [ABSTRACT FROM AUTHOR]

The penetration enhancement behaviors of a reactive material double-layered liner (RM-DLL) shaped charge against thick steel targets are investigated. The RM-DLL comprises an inner copper liner, coupled with an outer PTFE (polytetrafluoroethylene)/Al reactive material liner, fabricated via a cold pressing/sintering process. This RM-DLL shaped charge presents a novel defeat mechanism that incorporates the penetration capability of a precursor copper jet and the chemical energy release of a follow-thru reactive material penetrator. Experimental results showed that, compared with the single reactive liner shaped charge jet, a deeper penetration depth was produced by the reactive material-copper jet, whereas the penetration performance and reactive material mass entering the penetrated target strongly depended on the reactive liner thickness and standoff. To further illustrate the penetration enhancement mechanism, numerical simulations based on AUTODYN-2D code were conducted. Numerical results indicated that, with increasing reactive liner thickness, the initiation delay time of the reactive materials increased significantly, which caused the penetration depth and the follow-thru reactive material mass to increase for a given standoff. This new RM-DLL shaped charge configuration provides an extremely efficient method to enhance the penetration damage to various potential targets, such as armored fighting vehicles, naval vessels, and concrete targets. [ABSTRACT FROM AUTHOR]

In this paper, the reaction characteristic of a novel reactive material, which introduced bismuth trioxide (Bi 2 O 3 ) into traditional polytetrafluoroethylene/aluminum (PTFE/Al), is studied. The effect of Bi 2 O 3 with different content and particle size on the reaction behaviors of PTFE/Al/Bi 2 O 3 are investigated by drop-weight test and X-ray diffractometer (XRD), including impact sensitivity, energy release performance under a certain impact, and reaction mechanism. The experimental results show that the content of Bi 2 O 3 increased from 0% to 35.616%, the characteristic drop height of impact sensitivity ( H 50 ) of PTFE/Al/Bi 2 O 3 reactive materials decreased first and then increased, and the minimum H 50 of all types of materials in the experiment is 0.74 times that of PTFE/Al, and the particle size of Bi 2 O 3 affects the rate of H 50 change with Bi 2 O 3 content. Besides, with the increase of Bi 2 O 3 content, both the reaction intensity and duration first increase and then decrease, and there is optimum content of Bi 2 O 3 maximizing the reaction degree of the PTFE/Al/Bi 2 O 3 . Furthermore, a prediction model for the impact sensitivity of PTFE-based reactive material is developed. The main reaction products include AlF 3 , xBi 2 O 3 ·Al 2 O 3 , and Bi.