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Impurity removal and modification of rare earth concentrate powder were conducted by roasting weak acid-weak alkali leaching to obtain the active components of denitrification catalysts. NH3 selective catalytic reduction catalyst samples were prepared by mixing and kneading with pseudo-γ-Al2O3 boehmite as carrier. The results showed that the Ce7O12 content in the active component samples increased and dispersed more evenly. The grain size of the samples was refined, the specific surface area increased, and the active sites exposed more. Ce coexists in the form of Ce3+ and Ce4+. Fe coexists in the form of Fe3+ and Fe2+, but Fe3+ is abundant. Some Ce, La, Nd, Pr, Fe, Mn, and other components formed solid melts during preparation, which increased the synergistic catalytic effect. The denitrification efficiency of the catalyst sample was 92.8% under the conditions of reaction temperature 400 °C, NO content was 600 ppm, NH3/NO ratio was 1.5, and O2 concentration was 4%. [ABSTRACT FROM AUTHOR]

Spray cooling is a key technology in the continuous casting process and has a marked influence on the product quality. In order to obtain the heat transfer characteristics, which are closer to the actual continuous casting to serve the design, prediction and simulation, we created an experimental laboratory setup to investigate heat transfer characteristics of air mist spray cooling during the continuous casting secondary cooling process. A 200-mm thick sample of carbon steel was heated above 1000 °C, and then cooled in a water flux range of 0.84 to 3.0 L/(m2∙s). Determination of the boundary conditions involved experimental work comprising an evaluation of the thermal history and the heat flux and heat transfer coefficient (HTC) at the casting surface using inverse heat conduction numerical schemes. The results show that the heat fluxes were characterized via boiling curves that were functions of the slab surface temperatures. The heat flux was determined to be 2.9 × 105 W/m2 in the range of 1100 to 800 °C with a water flux of 2.1 L/(m2∙s). The critical heat flux increased with the increase of water flux. The HTC was close to a linear function of water flux. We also obtained the relation between the HTC and the water flux in the transition boiling region for surface temperatures of 850 to 950 °C. [ABSTRACT FROM AUTHOR]

Acid leaching and alkali roasting were used to remove impurities such as Ca and Si in Baiyun Obo rare earth concentrate. The effects of acid-base treatment on the physical and chemical properties of the samples were analyzed by scanning electron microscopy, X-ray diffraction, Brunauer-Emmett-Teller characterization, X-ray photoelectron spectroscopy, H 2 -temperature-programmed reduction, NH 3 -temperature-programmed desorption (TPD), and NO-TPD. Results showed that the content of Ce 7 O 12 in the rare earth concentrates increased and the dispersion was uniform. The grains became smaller, the specific surface area of rare earth concentrates increased, and the active sites were more exposed. Ce coexisted in the form of Ce 3+ and Ce 4+ , whereas Fe coexisted in the form of Fe 3+ and Fe 2+ . The content of Fe 3+ was increased. The acid-base-treated rare earth concentrates had a denitration efficiency of 87.4% at a reaction temperature of 400 °C., Competing Interests: The authors declare no conflict of interest.