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Structural lightweight concrete (SLWC) is crucial for reducing building weight, reducing structural loads, and enhancing energy efficiency through lower thermal conductivity. This study explores the effects of incorporating silica fume (SF), micro-polypropylene (micro-PP), and macro-PP fibers on the workability, thermal properties, and strength of SLWC. SF was added to all mixtures, substituting 10% of the Portland cement (PC), except for the control mixture. Macro-PP fibers were introduced alone or in combination with micro-PP fibers at volumetric ratios of 0.3% and 0.6%. The study evaluated various parameters, including slump, Vebe time, density, water absorption (WA), ultrasonic pulse velocity (UPV), thermal conductivity coefficients (k), compressive strength (CS), and splitting tensile strength (STS) across six different SLWC formulations. The results indicate that while SF negatively impacted the workability of SLWC mortars, it improved CS and STS due to the formation of calcium silicate hydrate (C-S-H) gels from SF's high pozzolanic activity. Additionally, using micro-PP fibers in combination with macro-PP fibers rather than solely macro-PP fibers enhanced the workability, CS, and STS of the SLWC samples. Although SF had a minor effect on reducing thermal conductivity, the use of macro-PP fibers alone was more effective for improving thermal properties by creating a more porous structure compared to the hybrid use of micro-PP fibers. Moreover, increasing the ratio of micro- and macro-PP fibers from 0.3% to 0.6% resulted in lower CS values but a significant increase in STS values. [ABSTRACT FROM AUTHOR]

The present study focuses on the mechanical performance of steel and polyvinyl alcohol fibers embedded in the geopolymer matrix. A high-strength geopolymer concrete with fly ash, slag and silica fume as precursors and sodium hydroxide and sodium silicate solutions as activators has been tested for its strength in compression and flexure. The influence of fibers on flowability, long-term shrinkage and sulphuric acid attack on the geopolymer concrete has also been studied. The dosage of fibers was maintained at 1%, 2% and 3% by volume, and fibers of length 13 mm have been used in the study. Results indicate that slag with 3% steel fibers by volume had a predominant influence on the strength development of steel fiber-reinforced geopolymer concrete, yielding a compressive strength of 107 MPa after 28 days. Blast furnace slag resulted in increasing the shrinkage of concrete due to rapid gel formation owing to the presence of calcium ions, although the fibers helped reduce the shrinkage to some extent. The strength of steel fiber geopolymer concrete was superior to PVA fiber geopolymer concrete; however, after an acid attack, the strength of steel fiber geopolymer concrete was reduced more than PVA fiber geopolymer concrete due to the enhanced corrosion resistance of PVA fibers. [ABSTRACT FROM AUTHOR]

This study aimed to utilize the hydration characteristics of cement through wet grinding techniques to efficiently and conveniently prepare a stable C-S-H seed suspension, providing key parameters and a scientific basis for their large-scale production, which ensures the stability of the C-S-H suspension during production, transportation, and application. This preparation aimed to mitigate the adverse effects of high-volume silica fume on the early mechanical properties of high-performance cement concrete. The properties of C-S-H seed were characterized in detail by SEM, XRD, and TD. In the concrete performance test, silica fume was used to replace part of the cement, and different contents of C-S-H seed were added to test its effect on the compressive strength of concrete, with XRD and SEM used to analyze the performance differences. The results show that the particle size and hydration degree of cement no longer developed after 90 min of wet grinding. Polycarboxylate ether (PCE) superplasticizer can increase the fluidity of the crystal C-S-H seed suspension when the content exceeds 1.5%. When the content of PCE exceeded 2%, the C-S-H seed suspension precipitated. Adding 5% C-S-H seed can increase the compressive strength of cement concrete by 10% under the condition of reducing the amount of cement and increasing the amount of silica fume. And Ca(OH)2 (CH) was produced by cement hydration consumed by silica fumes to generate C-S-H gel, by which the concrete became denser with more strength. However, when the amount of C-S-H seed exceeded 7%, the compressive strength of the concrete decreased. [ABSTRACT FROM AUTHOR]

Extensive research has been conducted on the sulfate attack of concrete structures; however, the need to adopt the use of more sustainable materials is driving a need for a quicker test method to assess sulfate resistance. This work presents accelerated methods that can reduce the time required for assessing the sulfate resistance of mixtures by 70%. Class F fly ash has historically been used in concrete mixtures to improve sulfate resistance. However, environmental considerations and the evolving energy industry have decreased its availability, requiring the identification of economically viable and environmentally friendly alternatives to fly ash. Another challenge in addressing sulfate attack durability issues in concrete is that the standard sulfate attack test (ASTM C1012) is time-consuming and designed for only standard mortars (not concrete mixtures). To expedite the testing process, accelerated testing methods for both mortar and concrete mixtures were adopted from previous work to further the development of the accelerated tests and to assess the feasibility of testing the sulfate resistance of mortar and concrete mixtures rapidly. This study also established criteria for interpreting sulfate resistance for each of the test methods used in this work. A total of 14 mortar mixtures and four concrete mixtures using two types of Portland cement (Type I and Type I/II) and various supplementary cementitious materials (SCMs) were evaluated in this study. The accelerated testing methods significantly reduced the evaluation time from 12 months to 21 days for mortar mixtures and from 6 months to 56 days for concrete mixtures. The proposed interpretation method for mortar accelerated test results showed acceptable consistency with the ACI 318-19 interpretations for ASTM C1012 results. The interpretation methods proposed for the two concrete sulfate attack tests demonstrated excellent consistency with the ASTM C1012 results from mortar mixtures with the same cementitious materials combinations. Metakaolin was shown to improve sulfate resistance for both mortar and concrete mixtures, while silica fume and natural pozzolan had a limited impact. Using 15% metakaolin in mortar or concrete mixtures with Type I/II cement provided the best sulfate resistance. [ABSTRACT FROM AUTHOR]

The growing consumption of natural resources to meet the needs of road construction has become a significant challenge to environmental sustainability. Additionally, the increase in industrial by-products has raised global concerns due to their environmental impacts. The utilization of industrial by-products in asphalt mixtures offers an effective solution for promoting sustainable practices. The objective of this article is to conduct a bibliometric analysis and citation-based review to characterize and analyze the scientific literature on the use of steel slag aggregates, copper slag, phosphorus slag, bottom ash, fly ash, red mud, silica fume, and foundry sand in asphalt mixtures. Another aim is to identify research gaps and propose recommendations for future studies. The bibliometric analysis was conducted using VOSviewer software version 1.6.18, focusing on authors, co-authorship, bibliographic coupling, and countries. A total of 909 articles were selected for the bibliometric analysis. The findings indicate that more effort is needed to expand the application of industrial by-products in asphalt mixtures. Furthermore, these by-products should be utilized in different types of asphalt mixtures. The incorporation of industrial by-products into asphalt mixes also requires field validation and further laboratory investigations, particularly concerning aging and moisture resistance. In addition, the effects of chemical reactions involving industrial by-products on the long-term performance of asphalt layers should be evaluated. Finally, this article encourages engineers and researchers to intensify their efforts in utilizing industrial by-products for environmental sustainability. [ABSTRACT FROM AUTHOR]

Developing green, low-carbon building materials has become a viable option for managing bulk industrial solid waste. This paper presents a kind of all solid waste cementitious material (SWCM), which is made entirely from six common industrial wastes, including carbide slag and silica fume, that demonstrate strong mechanical properties and effectively stabilize aeolian sand (AS). Initially, we investigated the mechanical strength of waste-based cementitious materials in various mix ratios, focusing on their ability to stabilize river sand (RS) and aeolian sand. The results show that it is necessary to use alkaline solid waste carbide slag to provide a suitable reaction environment to achieve the desired strength. In contrast, the low reactivity of coal gangue powder did not contribute effectively to the strength of the cementitious material. Further orthogonal experiments determined the impact of different waste dosages on the strength of stabilized AS. It was found that increasing the amounts of carbide slag, silica fume, and blast furnace slag powder improved strength, while increasing fly ash first increased and then decreased strength. In contrast, higher additions of desulfurization gypsum and coal gangue powder led to a continuous decrease in strength. The optimized mix is carbide slag—desulfurization gypsum—fly ash—silica fume—blast furnace slag powder in a ratio of 4:2:2:3:3. The experimental results using SWCM to stabilize AS indicated a proportional relationship between strength and SWCM content. When the content is ≥20%, it meets the strength requirements for road subbases. The primary hydration products of stabilized AS are C-(A)-S-H, AFt, and CaCO3. Increasing the SWCM content enhances the reaction degree of the materials, thereby improving mechanical strength. This study highlights the mechanical properties of cementitious materials made entirely from waste for stabilizing AS. It provides a reference for the large-scale utilization of industrial solid waste and practical applications in desert road construction. [ABSTRACT FROM AUTHOR]

Foam concrete has been used in various real-life applications for decades. Simple manufacturing methods, lightweight, high flowability, easy transportability, and low cost make it a useful construction material. This study aims to develop foam concrete mixtures for various civil and geotechnical engineering applications, such as in-fill, wall backfill and soil replacement work. A blended binder mix containing cement, fly ash and silica fume was produced for this study. Its compressive strength performance was compared against conventional general purpose (GP) cement-based foam concrete. Polypropylene (PP) fibre was used for both mixtures and the effect of various percentages of foam content on the compressive strength was thoroughly investigated. Additionally, two types of foaming agents were used to examine their impact on density, strength and setting time. One foaming agent was conventional, whereas the second foaming agent type can be used to manufacture permeable foam concrete. Results indicate that an increase in foam content significantly decreases the strength; however, this reduction is higher in GP mixes than in blended mixes. Nevertheless, the GP mixes attained two times higher compressive strength than the blended mix's compressive strengths at any foam content. It was also found that the foaming agent associated with creating permeable foam concrete lost its strength (reduced by more than half), even though the density is comparable. The compressive stress–deformation behaviour showed that densification occurs in foam concrete due to its low density, and fibres contributed significantly to crack bridging. These two effects resulted in a long plateau in the compressive stress–strain behaviour of the fibre-reinforced foam concrete. [ABSTRACT FROM AUTHOR]

The performance of ultra-high-performance concrete (UHPC) allows for the design and creation of thinner elements with superior overall durability. The compressive strength of UHPC is a value that can be reached after a certain period of time through a series of tests and cures. However, this value can be estimated by machine-learning methods. In this study, multilayer perceptron (MLP) and Stacking Regressor, an ensemble machine-learning models, is used to predict the compressive strength of high-performance concrete. Then, the ML model's performance is explained with a feature importance analysis and Shapley additive explanations (SHAPs), and the developed models are interpreted. The effect of using different random splits for the training and test sets has been investigated. It was observed that the stacking regressor, which combined the outputs of Extreme Gradient Boosting (XGBoost), Category Boosting (CatBoost), Light Gradient Boosting Machine (LightGBM), and Extra Trees regressors using random forest as the final estimator, performed significantly better than the MLP regressor. It was shown that the compressive strength was predicted by the stacking regressor with an average R2 score of 0.971 on the test set. On the other hand, the average R2 score of the MLP model was 0.909. The results of the SHAP analysis showed that the age of concrete and the amounts of silica fume, fiber, superplasticizer, cement, aggregate, and water have the greatest impact on the model predictions. [ABSTRACT FROM AUTHOR]

Herein, we present an elegant and simple method for significant improvement of eugenol water solubility using the polymers Soluplus® and Lutrol F 127 as carriers and spray drying as an encapsulation method. The formulations were optimized by adding myo-inositol—a sweetening agent—and Aerosil® 200 (colloidal, fumed silica)—an anticaking agent. The highest encapsulation efficiency of 97.9–98.2% was found for the samples containing 5% eugenol with respect to the mass of Soluplus®. The encapsulation efficiencies of the spray-dried samples with 15% eugenol are around 90%. Although lowering the yield, the addition of Lutrol F 127 results in a more regular particle shape and enhanced powder flowability. The presence of Aerosil® 200 and myo-inositol also improves the rheological powder properties. The obtained formulations can be used in various dosage forms like powders, granules, capsules, creams, and gels. [ABSTRACT FROM AUTHOR]

Silica fume (SF) is an essential component in ultra-high-performance concrete (UHPC) to compact the matrix, but the nucleus effect also causes rapid hydration, which results in high heat release and large shrinkage. In this paper, the carboxylic agents, including polyacrylic acid and polycarboxylate superplasticizer, were used to surface modify SF to adjust the activity to mitigate hydration at an early time and to promote continuous hydration for a long period. The surface and dispersion properties of modified SF (MSF), as well as the strength and pore structure of UHPC, were studied, and the stability of the modification was also investigated. The results demonstrated that, after treatment, the carboxylic groups were grafted on the SF surface, the dispersion of SF was improved due to the increased negative pentanal of the particle surface and the steric hindrance effect, the early hydration was delayed about 3–5 h, and the hydration heat release was also mitigated. The compressive strength of UHPC with MSF reached a maximum of 138.7 MPa at 3 days, which decreased about 3.7% more than the plain group, while flexural strength varied insignificantly. More pores and cracks were observed in the matrix with MSF, and the hydration degree was promoted with MSF addition. The grafted group on SF fell off under an alkali environment after 1 h. [ABSTRACT FROM AUTHOR]

The geoenergy industry has challenging demands on cements used as downhole materials. Once placed in the annular space, the cement sheath must be very low permeability and mechanically durable. Its characteristics are strongly influenced by its microstructure. A holistic approach, including combined mineralogical, physical, and mechanical investigations, provides a better understanding of how these characteristics interplay. Class G cement was investigated and compared to cement formulations containing carbon black or silica fu me, trying to tailor its performance. The addition of carbon black and silica fume has some effect on the modal and chemical phase composition and results in a much denser microstructure. Furthermore, porosity is reduced while the pore size distribution remains similar. Samples containing carbon black have a reduced Young's modulus, indicating a more plastic behavior. The addition of silica fume increased both mechanical strength and permeability. However, comparable results can also be achieved by carefully tuning the water/cement ratio of the initial slurry. [ABSTRACT FROM AUTHOR]

Currently, enterprises producing crystalline silicon are facing the formation and accumulation of large volumes of microsilica, a technogenic dusty waste formed during the melting of silicon alloys. Due to its chemical composition, this waste can be a significant raw material for metallurgical production. Therefore, this study is aimed to solve the problem of recycling microsilica. For these studies, a technology for the combined briquetting of microsilica and a carbonaceous reducing agent was developed for the production of a pilot batch of briquettes. This paper presents the results obtained from the process of testing the melting of crystalline (technical) silicon from briquetted monocharge obtained from microsilica. The tests were conducted under large-scale laboratory conditions on a 200 kVA ore-thermal furnace, where 30, 50, and 100% replacements of the traditional charge mixture with briquettes were tested. The results of this study showed that briquettes in the melting process of technical silicon can be successfully used in the range of 0 to 50%. The use of briquettes can significantly improve the technological indicators. The maximum extraction of silicon (approximately 83%) was achieved at 30% replacement. The technical and economic indicators of the process also improved. In particular, an increase in productivity was observed in comparison with tests on a traditional charge. [ABSTRACT FROM AUTHOR]

Based on an in-depth analysis of the factors influencing the compressive strength of ultra-high-performance concrete (UHPC), this study examined the impact of both single factorsand combined factors on UHPC performance using experimental data. The correlation analysis indicates that cement content, water content, steel fiber, and fly ash significantly affect the strength of UHPC, whereas silica fume, superplasticizers, and slag powder have a relatively smaller influence. This analysis provides a scientific basis for model development. Furthermore, the support vector regression (SVR) model was optimized using the arithmetic optimization algorithm (AOA). The superior performance and computational efficiency of the AOA–SVR model in predicting UHPC compressive strength were validated. Compared to SVR, support vector machine (SVM), and other single models, the AOA–SVR model achieves the highest R2 value and the lowest error rates. The results demonstrate that the optimized AOA–SVR model possesses excellent generalization ability and can more accurately predict the compressive strength of UHPC. [ABSTRACT FROM AUTHOR]

This review explores the mechanical behavior of high-strength concrete-filled steel tubes (CFSTs), focusing on their structural integrity and failure mechanisms. This study highlights the crucial role of the steel tube in providing passive confinement, which limits crack progression and enhances the ductility of the concrete. The concept of concrete as a structural system composed of micro- and mini-pillars, derived from rock mechanics, can be a useful approach to understanding CFST behavior. The review identifies that the strength index (SI) can, in some cases, decrease with an increase in the confinement factor (ξ), particularly in high-strength and ultrahigh-strength concrete (HSC and UHSC), which seems to be different to the common understanding of confinement. The experimental results show that different crack patterns and concrete compositions significantly impact the CFST performance. For example, silica fume in concrete mixtures can reduce the strength enhancement despite increasing the unconfined compressive strength. This work advocates for a mechanistic approach to better comprehend the interaction between concrete and steel tubes, emphasizing the need for optimized concrete mixtures and improved mechanical interaction. Future research should focus on the potential of HSC and UHSC in CFST, addressing factors such as crack progression, confinement effects, and concrete–steel interaction. [ABSTRACT FROM AUTHOR]

This research provides a comparative analysis of the optimization of ultra-high-performance concrete (UHPC) using artificial neural network (ANN) and response surface methodology (RSM). By using ANN and RSM, the yield of UHPC was modeled and optimized as a function of 22 independent variables, including cement content, cement compressive strength, cement type, cement strength class, fly-ash, slag, silica-fume, nano-silica, limestone powder, sand, coarse aggregates, maximum aggregate size, quartz powder, water, super-plasticizers, polystyrene fiber, polystyrene fiber diameter, polystyrene fiber length, steel fiber content, steel fiber diameter, steel fiber length, and curing time. Two statistical parameters were examined based on their modeling, i.e., determination coefficient (R2) and mean square error (MSE). ANN and RSM were evaluated for their predictive and generalization capabilities using a different dataset from previously published research. Results show that RSM is computationally efficient and easy to interpret, whereas ANN is more accurate at predicting UHPC characteristics due to its nonlinear interactions. Results show that the ANN model (R = 0.95 and R2 = 0.91) and RSM model (R = 0.94, and R2 = 0.90) can predict UHPC compressive strength. The prediction error for optimal yield using an ANN and RSM was 3.5% and 7%, respectively. According to the ANN model's sensitivity analysis, cement and water have a significant impact on compressive strength. [ABSTRACT FROM AUTHOR]

The use of silico-manganese slag as a substitute for cement in the preparation of concrete will not only reduce pollution in the atmosphere and on land due to solid waste but also reduce the cost of concrete. To explore this possibility, silico-manganese slag concrete was prepared by using silico-manganese slag as an auxiliary cementitious material instead of ordinary silicate cement. The mechanical properties of the silico-manganese slag concrete were investigated by means of slump and cubic compressive strength tests. The rates of mass loss and strength loss of silico-manganese slag concrete were tested after 25, 50, and 75 cycles. The effect of the silica–manganese slag admixture on the microfine structure and properties of concrete was also investigated using scanning electron microscopy (SEM). Finally, the damage to the silica–manganese slag concrete after numerous salt freezing cycles was predicted using the Weibull model. The maximum enhancement of slump and compressive strength by silica–manganese slag was 17.64% and 11.85%, respectively. The minimum loss of compressive strength after 75 cycles was 9.954%, which was 34.96% lower than that of the basic group. An analysis of the data showed that the optimal substitution rate of silica–manganese slag is 10%. It was observed by means of electron microscope scanning that the matrix structure was denser and had less connected pores and that the most complete hydration reaction occurred with a 10% replacement of silica–manganese slag, where an increase in the number of bladed tobermorite and flocculated C-S-H gels was observed to form a three-dimensional reticulated skeleton structure. We decided to use strength damage as a variable, and the two-parameter Weibull theory was chosen to model the damage. The final comparison of the fitted data with the measured data revealed that the model has a good fitting effect, with a fitting parameter above 0.916. This model can be applied in real-world projects and provides a favorable basis for the study of damage to silica–manganese slag concrete under the action of salt freezing. [ABSTRACT FROM AUTHOR]

This study investigated the effect of low-concentration fumed silica (FS) in polyethersulfone (PES) membranes. The PES/FS blend membrane was fabricated using a wet phase inversion technique as a flat sheet membrane. Scanning electron microscopy analysis revealed improved pore connectivity and rounder middle structures due to the addition of fumed silica. The experimental results indicated that the fabricated membranes fell within the ultrafiltration range, with pure water flux increasing as fumed silica concentration rose. The pure water flux improved by 64% compared to the native PES membrane. Furthermore, the blend membranes exhibited better selectivity, rejecting pepsin and lysozyme 11% and 19% more efficiently, respectively. Although the low concentration of fumed silica had minimal impact on the water contact angles of the membrane surface, all membranes demonstrated hydrophilicity. This cost-effective approach enhances permeability while maintaining separation characteristics, making it suitable for clean water applications. [ABSTRACT FROM AUTHOR]

High-Performance Concrete (HPC) and Ultra-High-Performance Concrete (UHPC) have many applications in civil engineering industries. These two types of concrete have as many similarities as they have differences with each other, such as the mix design and additive powders like silica fume, metakaolin, and various fibers, however, the optimal percentages of the mixture design properties of each element of these concretes are completely different. This study investigated the differences and similarities between these two types of concrete to find better mechanical behavior through mixture design and parameters of each concrete. In addition, this paper studied the correlation matrix through the machine learning method to predict the mechanical properties and find the relationship between the concrete mix design elements and the mechanical properties. In this way, Linear, Ridge, Lasso, Random Forest, K-Nearest Neighbors (KNN), Decision tree, and Partial least squares (PLS) regressions have been chosen to find the best regression types. To find the accuracy, the coefficient of determination (R2), mean absolute error (MAE), and root-mean-square error (RMSE) were selected. Finally, PLS, Linear, and Lasso regressions had better results than other regressions, with R2 greater than 93%, 92%, and 92%, respectively. In general, the present study shows that HPC and UHPC have different mix designs and mechanical properties. In addition, PLS, Linear, and Lasso regressions are the best regressions for predicting mechanical properties. [ABSTRACT FROM AUTHOR]

This study compares the workability, mechanical, and thermal characteristics of structural self-compacting lightweight concrete (SCLWC) formulations using pumice aggregate (PA), expanded perlite aggregate (EPA), fly ash (FA), and silica fume (SF). FA and SF were used as partial substitutes for cement at a 10% ratio in various mixes, impacting different aspects: According to the obtained results, FA enhanced the workability but SF reduced it, while SF improved the compressive and splitting tensile strengths more than FA. EPA, used as a fine aggregate alongside PA, decreased the workability, compressive strength, and splitting tensile strength compared to the control mix (K0). The thermal properties were altered by FA and SF similarly, while EPA notably reduced the thermal conductivity coefficients. The thermal conductivity coefficients (TCCs) of the K0–K4 SCLWC mixtures ranged from 0.275 to 0.364 W/mK. K0 had a TCC of 0.364 W/mK. With 10% FA, K1 achieved 0.305 W/mK; K2 with 10% SF reached 0.325 W/mK. K3 and K4, using EPA instead of PA, showed significantly lower TCC values: 0.275 W/mK and 0.289 W/mK, respectively. FA and SF improved the thermal conductivity compared to K0, while EPA further reduced the TCC values in K3 and K4 compared to K1 and K2. The compressive strength (CS) values of the K0–K4 SCLWC mixtures at 7 and 28 days reveal notable trends. Using 10% FA in K1 decreased the CS at both 7 days (12.16 MPa) and 28 days (22.36 MPa), attributed to FA's gradual pozzolanic activity. Conversely, K2 with SF showed increased CS at 7 days (17.88 MPa) and 28 days (29.89 MPa) due to SF's rapid pozzolanic activity. Incorporating EPA into K3 and K4 reduced the CS values compared to PA, indicating EPA's lower strength contribution due to its porous structure. [ABSTRACT FROM AUTHOR]

Towards a sustainable future in construction, worldwide efforts aim to reduce cement use as a binder core material in concrete, addressing production costs, environmental concerns, and circular economy criteria. In the last decade, numerous studies have explored cement substitutes (e.g., fly ash, silica fume, clay-based materials, etc.) and methods to mimic the mechanical performance of cement by integrating polymeric meshes into their matrix. In this study, a systemic approach incorporating computer aid and biomimetics is utilized for the development of 3D-printed clay-based composite mortar reinforced with advanced polymeric bioinspired lattice structures, such as honeycombs and Voronoi patterns. These natural lattices were designed and integrated into the 3D-printed clay-based prisms. Then, these configurations were numerically examined as bioinspired lattice applications under three-point bending and realistic loading conditions, and proper Finite Element Models (FEMs) were developed. The extracted mechanical responses were observed, and a conceptual redesign of the bioinspired lattice structures was conducted to mitigate high-stress concentration regions and optimize the structures' overall mechanical performance. The optimized bioinspired lattice structures were also examined under the same conditions to verify their mechanical superiority. The results showed that the clay-based prism with honeycomb reinforcement revealed superior mechanical performance compared to the other and is a suitable candidate for further research. The outcomes of this study intend to further research into non-cementitious materials suitable for industrial and civil applications. [ABSTRACT FROM AUTHOR]

Understanding how poly(carboxylate)s of chemical admixtures interact with calcium ions in cement pore solutions in the presence of silica fume is fundamental to developing better chemical admixtures for concrete production. In this work, the intermolecular interactions of calcium ions with a poly(carboxylate) superplasticizer type of chemical admixture was investigated via classical all-atom molecular dynamics (MD) simulations and Density Functional Theory (DFT) calculation methods in the presence of silica fume. The classical all-atom MD simulation and DFT calculation results indicate that calcium ions are interacting with oxygen atoms of the carboxylate group of PCE. The better interaction energy could mean an improved adsorption of the PCE segment with calcium ions. In this regard, it can be noted that the ester-based PCE segment could have a better adsorption onto calcium ions in comparison with the ether-based PCE segment. Moreover, the presence of silicon dioxide could improve the adsorption of the PCE segment onto calcium ions. [ABSTRACT FROM AUTHOR]

Due to the molding-free property and dry shrinkage of extrusion-based three-dimensional printable concrete (3DPC), the precision issues of 3DPC have not been solved effectively. One of the viable solutions for 3DPC precision improvement is to print using ultra-thin filaments. The challenges of ultra-thin-filament printing are extrudability, flowability, and fast solidification. To overcome these challenges and enhance precision, a customized 3D concrete printer with an ultra-thin diameter nozzle (6 mm) and fully sealed extrusion system was developed, and the mix design of ultra-thin-filament 3DPC (UTF-3DPC) was studied, including ingredients such as fly ash (FA), silica fume (SF), ordinary Portland cement (OPC), sodium dodecyl sulfate and cellulose (SDSC), water reducer, water, and sand. The function of UTF-3DPCs flowability and fast solidification with the proportion of water and SDSC was explored to obtain the optimal mix design. The standard compressive and flexural strengths of UTF-3DPC specimens were compared with the mold-cast vibrated and the mold-cast non-vibrated concrete. Their meso-scale and micro-scale structures were analyzed to expose the strength mechanism, according to the scanning electron microscope (SEM) images. A suitable mix design of UTF-3DPC was obtained and UTF-3DPC strength reached 80% of standard mold-cast concrete. The findings reported here provide a pathway to improve the precision of 3DPC and extend the application of 3D printing technology in engineering. [ABSTRACT FROM AUTHOR]

This paper investigates the high temperature resistance performance and mechanism of potassium-activated blended precursor geopolymer with silica fume. The failure morphology, volume, and mass loss, compressive strength deterioration, hydration production, and pore structure are measured and analyzed. The results show that introducing slag into fly ash-based geopolymer could greatly improve the 28 d compressive strength but reduce the thermal stability. In contrast, the partial substitution of fly ash by metakaolin contributes to excellent high temperature resistance with slightly enhanced 28 d compressive strength. After being exposed at 800 °C, the residual compressive strength of F7M3 remains at 37 MPa, almost 114% of the initial ambient-temperature strength. An appropriately enlarged silica fume content in geopolymer results in increased compressive strength and enhanced thermal stability. However, an excessive silica fume content is detrimental to the generation of alkali-aluminosilicate gels and ceramic-like phases and thus exacerbates the high temperature damage. [ABSTRACT FROM AUTHOR]

Ternary blended cements, made with silica fume and limestone, provide significant benefits such as improved compressive strength, chloride penetration resistance, sulfates attack, etc. Furthermore, they could be considered low-carbon cements, and they contribute to reducing the depletion of natural resources in reference to water usage, fossil fuel consumption, and mining. Limestone (10%, 15%, and 20%) with different fineness and coarse silica fume (3%, 5%, and 7%) was used to produce ternary cements. The average size of coarse silica fume used was 238 μm. For the first time, the carbonation resistance of ternary Portland cements made with silica fume and limestone has been assessed. The carbonation resistance was assessed by natural carbonation testing. The presence of coarse silica fume and limestone in the blended cement led to pore refinement of the cement-based materials by the filling effect and the C-S-H gel formation. Accordingly, the carbonation resistance of these new ternary cements was less poor than expected for blended cements. [ABSTRACT FROM AUTHOR]

Concrete, as one of the most widely applied materials in buildings, has high environmental impacts. Researchers are continually seeking solutions to mitigate these environmental issues while enhancing the mechanical strength and durability of concrete. However, there is a lack of studies on the effect of combining silica fume (SF) as pozzolanic materials and shape memory alloy (SMA) fibers on the mechanical properties of concrete. Moreover, there is very limited research on the influence of these materials on concrete mixtures after primary failure cracks using the secondary compressive strength test. In this research, 0.1, 0.2, and 0.3% SMA and 5, 7.5, and 10% SF were applied and then subjected to compressive strength, splitting tensile strength, flexural strength, secondary compressive strength, and ultrasonic pulse velocity tests. According to the results, 10% SF is more economical, which increases the compressive, splitting tensile, and flexural strength by 14%, 7%, and 10%, respectively. Also, using 0.3% SMA improves the compressive, splitting tensile, and flexural strength by 2%, 5%, and 8%, respectively. Furthermore, SMA has the ability to reduce the secondary compressive strength compared to other samples, indicating the quality of this material in controlling stress after cracking. Finally, it was indicated that the combined use of these two materials increases the strength parameters. [ABSTRACT FROM AUTHOR]

Zeolites have a well-ordered crystalline network with pores controlled in the synthesis process. Their composition comprises silicon and aluminum, so industrial residues with this composition can be used for the synthesis of zeolites. The use of zeolites for CO2 adsorption is feasible due to the characteristics that these materials have; in particular, zeolites with a low Si/Al ratio have greater gas adsorption capacities. In this work, the synthesis of LTA (Linde Type A) zeolites from silica fumes obtained from the industrial LIASA process and light coal ash is presented. We explore three different synthesis routes, where the synthesized materials undergo cation exchange and are applied in CO2 adsorption processes. Studying the synthesis processes, it is observed that all materials present characteristic diffractions for the LTA zeolite, as well as presenting specific areas between 6 and 19 m2/g and average pore distributions of 0.50 nm; however, the silica fume yielded better synthesis results, due to its lower impurity content compared to the light coal ash (which contains impurities such as quartz present in the zeolite). When applied for CO2 adsorption, the standard materials after cation exchange showed greater adsorption capacities, followed by the zeolites synthesized from silica fume and, finally, the zeolites synthesized from coal ash. By analyzing the selectivity of the materials for CO2/N2, it is observed that the materials in sodium form present greater selectivity when compared to the calcium-based materials. [ABSTRACT FROM AUTHOR]

Dumped non-biodegradable tires present a significant environmental threat, with overflowing landfills and associated health risks highlighting the urgency of tire waste disposal. Current disposal methods, such as stacking tires in open spaces, exacerbate the problem. The large-scale recycling of tire rubber waste offers environmental benefits. This study examines the effects of pre-treatment using NaOH and micro-silica as a mineral admixture on the mechanical strength of crumb rubber concrete (CRC) with partial replacement of natural sand. Samples of M20 and M30 grade were prepared with varying levels of crumb rubber (CR) replacement and evaluated at 28 days. CRC prepared with pre-treated NaOH solution and micro-silica showed improved workability and strength compared to conventional concrete and untreated CRC, with the highest strength observed for 5% CR replacement using micro-silica. Predictive models and micro-structural analysis validated these findings. Life Cycle Assessment (LCA) using OpenLCA v2.10 software and the ecoinvent database revealed that incorporating micro-silica into CRC did not significantly increase environmental impacts, compared to conventional concrete across different mixes. [ABSTRACT FROM AUTHOR]

The production of flue gas desulfurization gypsum poses a serious threat to the environment. Thus, utilizing gypsum-based self-leveling mortar (GSLM) stands out as a promising and effective approach to address the issue. β-hemihydrate gypsum, cement, polycarboxylate superplasticizer, hydroxypropyl methyl cellulose ether (HPMC), retarder, and defoamer were used to prepare GSLM. The impact of mineral admixtures (steel slag (SS), silica fume (SF), and fly ash (FA)) on the physical, mechanical, and microstructural properties of GSLM was examined through hydration heat, X-ray diffractometry (XRD), Raman spectroscopy, and scanning electron microscopy (SEM) analyses. The GSLM benchmark mix ratio was determined as follows: 94% of desulfurization building gypsum, 6% of cement, 0.638% each of water reducer and retarder, 0.085% each of HPMC and defoamer (calculated additive ratio relative to gypsum), and 0.54 water-to-cement ratio. Although the initial fluidity decreased in the GSLM slurry with silica fume, there was minimal change in 30 min fluidity. Notably, at an SS content of 16%, the GSLM exhibited optimal flexural strength (6.6 MPa) and compressive strength (20.4 MPa). Hydration heat, XRD, and Raman analyses revealed that a small portion of SS actively participated in the hydration reaction, while the remaining SS served as a filler. [ABSTRACT FROM AUTHOR]

The objective of this research is to enhance the high-temperature antirutting and antiaging characteristics of bioasphalt. In this study, silica fume (SF) was selected to modify bioasphalt. The dosage of bio-oil in bioasphalt was 5%, and the dosage of SF was 2%, 4%, 6%, 8%, and 10% of bioasphalt. The high- and low-temperature characteristics, aging resistance, and temperature sensitivity of Bio + SF were evaluated by temperature sweep (TS), the multiple stress creep recovery (MSCR) test, the bending beam rheology (BBR) test, and the viscosity test. Meanwhile, the road behavior of the Bio + SF mixture was evaluated using the rutting test, low-temperature bending beam test, freeze–thaw splitting test, and fatigue test. The experimental results showed that the dosage of SF could enhance the high-temperature rutting resistance, aging resistance, and temperature stability of bioasphalt. The higher the dosage of SF, the more significant the enhancement effect. However, incorporating SF weakened bioasphalt's low-temperature cracking resistance properties. When the SF dosage was less than 8%, the low-temperature cracking resistance of Bio + SF was still superior to that of matrix asphalt. Compared with matrix asphalt mixtures, the dynamic stability, destructive strain, freeze–thaw splitting strength ratio, and fatigue life of 5%Bio + 8%SF mixtures increased by 38.4%, 49.1%, 5.9%, and 68.9%, respectively. This study demonstrates that the development of SF-modified bioasphalt could meet the technical requirements of highway engineering. Using SF and bio-oil could decrease the consumption of natural resources and positively reduce environmental pollution. [ABSTRACT FROM AUTHOR]

To enhance the physical and mechanical characteristics of steam-cured concrete, an orthogonal experimental design was utilized to examine the effects of varying contents of fly ash (0 wt%, 10 wt%, 15 wt%, 20 wt%), silica fume (0 wt%, 5 wt%, 10 wt%, 15 wt%), basalt fiber (0 vol%, 0.05 vol%, 0.1 vol%, 0.2 vol%), and polypropylene fiber (0 vol%, 0.05 vol%, 0.1 vol%, 0.2 vol%) on its mechanical properties. Utilizing range and variance analyses, this study identified four preliminary optimized compositions of concrete incorporating fly ash, silica fume, basalt fiber, and polypropylene fiber. On this basis, in order to determine the optimal mix proportion, the mechanical performances, the pore characteristics, and the microstructure of four optimized mix proportions were analyzed. According to the results of macroscopic, fine, and microscopic multi-scale tests, the addition of 15 wt% fly ash, 10 wt% silica ash, 0.2 vol% basalt fiber, and 0.1 vol% polypropylene fiber to the steamed concrete is the best to improve the performance of the steamed concrete. Compared to ordinary concrete, the compressive strength increases by 28%, the tensile strength increases by 40%, and the porosity decreases by 47.2%. [ABSTRACT FROM AUTHOR]

This study aims at the evaluation of different formulations of concrete made with calcined clays and limestone (LC3 cement) exposed to aggressive environments. The study includes the evaluation of fresh and hardened properties and a comprehensive evaluation of durability over 24 months. The inclusion of calcined clays in cement increases the specific surface area of the cements, and thus the water demand. However, the high reactivity of calcined clays compared to any other pozzolan, and the synergy that occurs with limestones, enables the use of cements with very low clinker content that achieve strengths similar to those of Portland. Comparisons of LC3 formulations with Portland cement and with concrete containing silica fume prove the superiority of calcined clays in terms of strength and durability. The best results are obtained with LC3-50 cement with 50% clinker produced through co-grinding. Results of concrete made with a blend of 70% Portland cement with 30% LC2 (60% calcined clay, 35% limestone, 5% gypsum, separate ground) are also promising. All concretes made with LC3 show good durability in terms of the results of effective porosity, chloride permeability, and resistivity tests. [ABSTRACT FROM AUTHOR]

Abundant tuff mineral resources offer a promising solution to the shortage of fly ash (FA) and silica fume (SF) resources as emerging supplementary cementitious materials. However, a lack of clarity on its hydration mechanism has hindered its practical engineering application. In this study, high SiO2-content tuff powder (TP) was examined to assess the mechanical and workability performance of mortar specimens with varying particle sizes of the TP as complete replacements for FA or SF. Microscopic analysis techniques, including X-ray diffraction (XRD), differential thermal analysis (DTG), and energy-dispersive X-ray spectroscopy (EDS), were employed to elucidate the hydration mechanism of the TP and its feasibility as a substitute for SF or FA. Results indicated that TP primarily functions as nuclei and filler, promoting cement hydration, with smaller particle sizes amplifying the hydration ability and increasing Ca(OH)2 and C-S-H gel content. The specimens with TP (median particle size 7.58 μm) demonstrated 9.2% and 29.9% higher flexural and compressive strengths at 28 days, respectively, compared to the FA specimens of equal mass. However, fluidity decreased by 23.1% accordingly. Due to TP's smaller specific surface area compared to SF, the TP specimens exhibited higher fluidity but with decreased strength relative to the SF specimens. Overall, TP shows potential as a replacement for FA with additional measures to ensure workability. [ABSTRACT FROM AUTHOR]

A geopolymer is an inorganic amorphous cementitious material, emerging as an alternative sustainable binder for greener concrete production over Ordinary Portland Cement (OPC). Geopolymer concrete production promotes waste reuse since the applicable precursor materials include agricultural and industrial waste that requires disposal, helping to reduce waste in landfills and ensuring sustainable environmental protection. This study investigates the development of an environmentally friendly sodium silicate alternative (SSA) derived from pumice powder (PP) in place of a commercial Na2SiO3 solution at a 10 M concentration. Six concrete batches were produced at alkaline/precursor (A/P) ratios of 0.1, 0.2, 0.3, 0.4, and 0.5. The geopolymer mix AF4, with an A/P ratio of 0.4, became the optimum geopolymer concrete design; however, it recorded lower compressive, tensile splitting, and flexural strengths, respectively, against the control OPC concrete. The geopolymer formulations, however, obtained 28-day-hardened concrete densities comparable to the control concrete. The 28-day compressive strength of the OPC concrete was 29.4 MPa, higher than the 18.8 MPa recorded for AF4. However, the 56-day strength of AF4 improved to 22.4 MPa, an around 19% increase compared to the 30.8 MPa achieved by the control mix on day 56, having experienced only a 5% strength increase. The low mechanical performances of the geopolymer formulation could be attributed to extra water added to the original geopolymer design to improve the workability of the geopolymer mix. Therefore, the SSA alkaline solution using PP showed some potential for developing geopolymer concrete for low-strength construction applications. [ABSTRACT FROM AUTHOR]

The coal gangue coarse-aggregate content in ordinary concrete should not be too large. In order to further improve the utilization rate of coal gangue coarse aggregate, this study used the principle of "strong wrapped weak" to prepare high-performance concrete. This study considered four factors, namely, water–binder (W/B) ratios, non-spontaneous combustion coal gangue (NCCG) coarse-aggregate contents, fly ash–slag mass ratios, and silica fume coating to prepare high-performance concrete. The workability, mechanical, and durability properties were studied, and the changes in the interfacial transition zone (ITZ) of concrete before and after sulfate attack and freeze–thaw cycles were analyzed based on the SEM test. The life prediction of NCCG coarse-aggregate high-performance concrete was carried out based on the grey system GM(1,1) prediction model. The results show that the NCCG coarse-aggregate contents have the greatest effect on compressive strength, sulfate resistance, and frost resistance. The W/B ratio has the greatest effect on the anti-carbonization properties. Fly ash–slag mixing can obtain better durability. Considering the effect on the design service life of high-performance concrete, NCCG coarse aggregate is used to prepare high-performance concrete in North China, and the recommended content is 60%; in the Northwest and Northeast regions, the recommended content is 45%. This study provides a basis for the preparation of high-performance concrete with NCCG coarse aggregate. [ABSTRACT FROM AUTHOR]

Using sustainable cement-based alternatives, such as secondary cementitious raw materials (SCMs), could be a viable option to decrease CO2 emissions resulting from cement production. Previously conducted studies to determine the optimal mix designs of concrete primarily focused on either experimental approaches or empirical modeling techniques. However, in these experimental approaches, few tests could be performed for optimization due to time restrictions and lack of resources, and empirical modeling methods cannot be relied on without external validation. The machine learning-based approaches are further characterized by certain shortcomings, including a smaller number of data points, a less robust connection among the controlling factors, and a lack of comparative analyses among machine learning models. Furthermore, the literature on predicting the performance of concrete utilizing binary SCMs (silica fume (SF) and ground granulated blast furnace slag (GGBS)) is not available. Therefore, to address these drawbacks, this research aimed to integrate ML-based models with experimental validations for accurate predictions of the compressive strength (CS) and tensile strength (TS) of concrete that includes SF and GGBS as SCMs. Three soft computing techniques, namely the ANN, ANFIS, and GEP methods, were used for prediction purposes. Eight major input parameters, including the W/B ratio, cement, GGBS, SF, coarse aggregates, fine aggregates, superplasticizer, and the age of the specimens, were considered for modeling. The validity of the established models was assessed by using external experimental validation criteria, statistical metrics, and performance measures. In addition, sensitivity and parametric analyses were performed. Based on statistical measures, the ANFIS models outperformed other models with higher correlation and lower statistical error values. However, the GEP models exhibited superior performance compared to ANFIS and ANN with respect to the closeness of the RMSE, MAE, RSE, and R2 values between the training, validation, and testing sets for both the CS and TS models. Experimental validation showed strong evidence for the applicability of the proposed models with an R2 of 0.88 and error percentages of less than 10%. Sensitivity and parametric investigations demonstrated that the input variables exhibited the patterns described in the experimental dataset and the available literature. Hence, the proposed models are accurate, have better prediction performance, and can be used for design purposes. [ABSTRACT FROM AUTHOR]

To overcome limitations inherent in existing mechanical performance prediction models for pervious concrete, including material constraints, limited applicability, and inadequate accuracy, this study employs a deep learning approach to construct a Convolutional Neural Network (CNN) model with three convolutional modules. The primary objective of the model is to precisely predict the 28-day compressive strength of pervious concrete. Eight input variables, encompassing coarse and fine aggregate content, water content, admixture content, cement content, fly ash content, and silica fume content, were selected for the model. The dataset utilized for both model training and testing consists of 111 sample sets. To ensure the model's coverage within the practical range of pervious concrete strength and to enhance its robustness in real-world applications, an additional 12 sets of experimental data were incorporated for training and testing. The research findings indicate that, in comparison to the conventional machine learning method of Backpropagation (BP) neural networks, the developed CNN prediction model in this paper demonstrates a higher coefficient of determination, reaching 0.938, on the test dataset. The mean absolute percentage error is 9.13%, signifying that the proposed prediction model exhibits notable accuracy and universality in predicting the 28-day compressive strength of pervious concrete, regardless of the materials used in its preparation. [ABSTRACT FROM AUTHOR]

Alkali–silica reaction (ASR) occurs when alkali oxides coming from the cement composition in concrete come together with reactive silica and moisture coming from the aggregate. Additional maintenance and repair costs caused by the development of ASR in concrete cause the cost to increase. However, thanks to the measures taken against ASR in the early period, it contributes to the creation of sustainable and durable concrete structures. The article investigated the usability of cherts with eight different chemical compositions as aggregates in ready-mixed concrete plants in Gümüşhane. Cherts have been investigated for alkaline reactivity and are intended to be used largely as a source for concrete plants. ASR length changes of the samples prepared according to ASTM C1260 standard were determined after 3, 7, 14, and 28 days of the curing period. Microstructural examination, ultrasonic P-wave velocity, and bending and compressive strength experiments supporting ASR were carried out. The obtained test results were compared between the reference (limestone) sample and each other, as well as with the values specified in the standards. The compressive and bending strength values of the samples increase depending on their ASR. It was observed that the crack structures and types increased depending on the increase in the crack values. [ABSTRACT FROM AUTHOR]

Ground Granulated Blast-Furnace Slag (GGBS) and silica fume (SF) are frequently utilized in gel materials to produce environmentally sustainable concrete. The blend of the two components contributes to an enhancement in the pore structure, which, in turn, increases the mechanical strength of the material and the compactness of the pore structure and decreases the permeability, thereby improving the durability of the concrete. In this study, the pore structures of GGBS and SF blends are assessed using Nuclear Magnetic Resonance (NMR) and Mercury Intrusion Porosimetry (MIP) tests. These methodologies provide a comprehensive evaluation of the effect of GGBS and SF on the pore structure of cementitious materials. Results showed that the addition of SF and GGBS reduces the amount of micro-capillary pores (10 < d < 100 nm) and the total pore volume. The results indicate that the transport properties are related to the pore structure. The incorporation of SF reduced the permeability of the concrete by an order of magnitude. The pore distribution and pore composition had a significant effect on the gas permeability. The difference in porosity obtained using the MIP and NMR tests was large due to differences in testing techniques. [ABSTRACT FROM AUTHOR]

The effective use of waste materials is one of the key drivers in ensuring sustainability within the construction industry. This paper investigates the viability and efficacy of sustainably incorporating a polylactic acid-type plastic (WP) as a 10 mm natural coarse aggregate (NA) replacement in geopolymer concrete. Two types of concrete (ordinary Portland cement—OPC and geopolymer) were produced for completeness using a concrete formulation ratio of 1:2:3. The ordinary concrete binder control was prepared using 100% OPC at a water/binder ratio of 0.55, while the geopolymer concrete control used an optimum alkaline activator/precursor—A/P ratio (0.5) and sodium silicate to sodium hydroxide—SS/SH volume ratio (1.2/0.8). Using the same binder quantity as the control, four concrete batches were developed by replacing 10 mm NA with WP at 30 and 70 wt% for ordinary and geopolymer concrete. The mechanical performance of the developed concrete was assessed according to their appropriate standards, while a microstructural investigation was employed after 28 days of curing to identify any morphological changes and hydrated phases. The results illustrate the viability of incorporating WP in geopolymer concrete production at up to 70 wt% replacement despite some negative impacts on concrete performance. From a mechanical perspective, geopolymer concrete indicated a 46.7–58.3% strength development superiority over ordinary concrete with or without WP. The sample composition and texture quantified using automated scanning electron microscopy indicated that adding WP reduced the presence of pores within the microstructure of both concrete types. However, this was detrimental to the ordinary concrete due to the low interfacial zone (ITZ) between calcium silicate hydrate (CSH) gel and WP, resulting in the formation of cracks. [ABSTRACT FROM AUTHOR]

Recently, the manufacturing of porous polydimethylsiloxane (PDMS) with engineered porosity has gained considerable interest due to its tunable material properties and diverse applications. An innovative approach to control the porosity of PDMS is to use transient liquid phase water to improve its mechanical properties, which has been explored in this work. Adjusting the ratios of deionized water to the PDMS precursor during blending and subsequent curing processes allows for controlled porosity, yielding water emulsion foam with tailored properties. The PDMS-to-water weight ratios were engineered ranging from 100:0 to 10:90, with the 65:35 specimen exhibiting the best mechanical properties with a Young's Modulus of 1.17 MPa, energy absorption of 0.33 MPa, and compressive strength of 3.50 MPa. This led to a porous sample exhibiting a 31.46% increase in the modulus of elasticity over a bulk PDMS sample. Dowsil SE 1700 was then added, improving the storage capabilities of the precursor. The optimal storage temperature was probed, with −60 °C resulting in great pore stability throughout a three-week duration. The possibility of using these water emulsion foams for paste extrusion additive manufacturing (AM) was also analyzed by implementing a rheological modifier, fumed silica. Fumed silica's impact on viscosity was examined, revealing that 9 wt% of silica demonstrates optimal rheological behaviors for AM, bearing a viscosity of 10,290 Pa·s while demonstrating shear-thinning and thixotropic behavior. This study suggests that water can be used as pore-formers for PDMS in conjunction with AM to produce engineered materials and structures for aerospace, medical, and defense industries as sensors, microfluidic devices, and lightweight structures. [ABSTRACT FROM AUTHOR]

In order to improve the mechanical properties and durability of lightweight aggregate concrete in extreme environments, this study utilized Inner Mongolia pumice as the coarse aggregate to formulate pumice lightweight aggregate concrete (P-LWAC) with a silica powder content of 0%, 2%, 4%, 6%, 8%, and 10%. Under sulfate dry–wet cycling conditions, this study mainly conducted a mass loss rate test, compressive strength test, NMR test, and SEM test to investigate the improvement effect of silica powder content on the corrosion resistance performance of P-LWAC. In addition, using grey prediction theory, the relationship between pore characteristic parameters and compressive strength was elucidated, and a grey prediction model GM (1,3) was established to predict the compressive strength of P-LWAC after cycling. Research indicates that under sulfate corrosion conditions, as the cycle times and silica powder content increased, the corrosion resistance of P-LWAC showed a trend of first increasing and then decreasing. At 60 cycles, P-LWAC with a content of 6% exhibited the lowest mass loss rate and the highest relative dynamic elastic modulus, compressive strength, and corrosion resistance coefficient. From the perspective of data distribution, various durability indicators showed a clear mirror symmetry towards both sides with a silica powder content of 6% as the symmetrical center. The addition of silica fume reduced the porosity and permeability of P-LWAC, enhanced the saturation degree of bound fluid, and facilitated internal structural development from harmful pores towards less harmful and harmless pores, a feature most prominent at the 6% silica fume mixing ratio. In addition, a bound fluid saturation and pore size of 0.02~0.05 μm/% exerted the most significant influence on the compressive strength of P-LWAC subjected to 90 dry–wet cycles. Based on these two factors, grey prediction model GM (1,3) was established. This model can accurately evaluate the durability of P-LWAC, improving the efficiency of curing decision-making and construction of concrete materials. [ABSTRACT FROM AUTHOR]

The effects of octaphenylsilsesquioxane (OPS), fumed silica, and silica aerogel on the thermal insulation properties of ethylene propylene diene monomer (EPDM) rubber were studied. On this basis, two kinds of fillers with good performances were selected to study the thermal insulation of an EPDM full-formula system. The results show that the addition of fumed silica or silica aerogel had a positive effect on the thermal insulation performance of EPDM rubber and its composite. A 30 wt% silica aerogel can be well dispersed in the EPDM rubber system and with a lower thermal conductivity compared with fumed silica. EPDM composite with 23.4 wt% fumed silica can produce more char residues at 1000 °C than at 500 °C in a burn-through test and formed the compact and porous char at 1000 °C, which had a lowest thermal conductivity. EPDM composite with fumed silica cannot be burned through 1000 °C burning, and comparison with silica aerogel revealed that it achieved the lowest back temperature and had a temperature of 388 °C after 800 s. [ABSTRACT FROM AUTHOR]

To solve the problem of the poor abrasion resistance of concrete pavement surface mortar, this study substituted cement with equal amounts of styrene–butadiene rubber (SBR) latex and silica fume (SF) to investigate the effects of organic/inorganic material composite modification on the fluidity, drying shrinkage, mechanical properties, and abrasion resistance of cement mortar. Also in this study, the microstructure, product, and pore structure characteristics of the composite modified cement mortar were investigated using scanning electron microscope (SEM), X-Ray diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR), and the Brunauer–Emmett–Teller (BET) method. This research found that the sole substitution of SF negatively impacted the mortar's fluidity and drying shrinkage yet enhanced its mechanical strength and abrasion resistance; the incorporation of SBR latex improved fluidity, reduced shrinkage, and increased flexural strength but adversely affected the compressive strength of the mortar. Additionally, the enhancement of the mortar's abrasion resistance with SBR latex was significantly greater than that with SF. When SBR latex and SF were used together as substitutes, the latex struggled to offset the negative impact of SF on mortar fluidity but effectively reduced shrinkage; SF compensated for the detrimental effect of the latex on compressive strength. Moreover, the primary role in enhancing the mortar's abrasion resistance was played by the latex. Microscopic tests showed that SBR latex and SF could increase the content of calcium silicate hydrate (C-S-H) gel, inhibit the formation of ettringite (AFt) and reduce carbonation, refine the pore size of cement mortar, and effectively improve the microstructure of mortar. [ABSTRACT FROM AUTHOR]

The demand for lightweight aggregates in concrete compositions for diverse structural and non-structural applications in contemporary building construction has increased. This is to achieve a controllable low-density lightweight concrete, which reduces the overall structural weight. However, the challenge lies in achieving an appropriate strength in lightweight concrete while maintaining a lower unit weight. This research aims to evaluate the performance of lightweight concrete by integrating expanded polystyrene (EPS) as a partial replacement for coarse aggregate. Test specimens were cast by blending EPS with coarse aggregate at varying proportions of 0%, 15%, 30%, and 45%, while maintaining a constant water-to-binder ratio of 0.60. To enhance the bonding and structural capabilities of the proposed lightweight concrete mixes, reinforcement with 2% and 4% steel fibers by volume of the total concrete mix was incorporated. Silica fume was introduced into the mix to counteract the water hydrophobicity of EPS material and enhance the durability of lightweight concrete, added at a rate of 10% by weight of cement in all specimens. A total of 60 samples, including cylinders and beams, were prepared and cured over 28 days. The physical and mechanical properties of the lightweight EPS-based concrete were systematically examined through experimental testing and compared against a standard concrete mix. The analysis of the results indicates that EPS-based concrete exhibits a controllable low density. It also reveals that incorporating reinforcement materials, such as steel fibers, enhances the overall strength of lightweight concrete. [ABSTRACT FROM AUTHOR]

This study investigated how the water–cement ratio and silica fume concentration affect the compressive strength of cement mortars. This comprehensive study delved into the intricate interplay between water–cement ratio and silica fume concentration, examining their influence on cement-based mortars' compressive strength and water absorption characteristics. The silica fume concentration was investigated, ranging from 5% to 15% of the cement weight. The investigation employed two distinct mixing techniques, mixing cement and silica fume, before extracting appropriate samples; alternatively, a magnetic stirrer was used to prepare samples by dissolving silica fume in water. The cement mortars were also prepared with three different water–cement ratios: 0.44, 0.47, and 0.5. The interesting findings of compressive tests illuminated a consistent trend across all curing days and mixing methods—a reduction in the water–cement ratio corresponded with a notable increase in compressive strength. However, it is essential to note that the influence of the mixing method on the compressive strength of cement-based mortars is based on the water–cement ratio. The results show that by using the suggested technological method, it was observed that samples prepared with water–cement ratios (W/C) of 0.47 and 0.44 exhibited higher compressive strengths compared to those prepared using the well-known standard mixing method. The compressive test results underscored that the water–cement ratio reduction consistently enhanced the compressive strength in every combination of curing days and mixing techniques. Furthermore, this reduction in the water–cement ratio was correlated with a decrease in water absorption of the mortar. Conversely, the water–cement ratio itself played a pivotal role in defining how the mixing technique affected the compressive strength and water absorption of cement-based mortars. This multifaceted exploration underscores the nuanced relationships between key variables, emphasizing the need for a comprehensive understanding of the intricate factors influencing the mechanical and absorptive properties of cement-based materials. [ABSTRACT FROM AUTHOR]

It is known that 3D printable concrete mixtures can be costly because they contain high dosages of binder and that the drying-shrinkage performance may be adversely affected. Mineral additives and fibers are generally used to control these negative aspects. In this study, the use of silica fume, a natural viscosity modifying admixture, was investigated to improve the rheological and thixotropic behavior of 3D printable concrete mixtures reinforced with polypropylene fiber (FR-3DPC). The effect of increasing the silica fume utilization ratio in FR-3DPC on the compressive strength (CS), flexural strength (FS), and drying-shrinkage (DS) performance of the mixtures was also examined. A total of five FR-3DPC mixtures were produced using silica fume at the rate of 3, 6, 9, and 12% of the cement weight, in addition to the control mixture without silica fume. As a result of the tests, the dynamic yield stress value decreased with the addition of 3% silica fume to the control mixture. However, it was found that the dynamic yield stress and apparent viscosity values of the mixtures increased with the addition of 6, 9, and 12% silica fume. With the increase in the use of silica fume, the CS values of the mixtures were generally affected positively, while the FS and DS behavior were affected negatively. [ABSTRACT FROM AUTHOR]

Geopolymer concrete (GC), also known as green concrete, contains slag, silica fume, and fly ash as binders. The absence of cement in concrete is critical to protect the world from the environmental impacts of cement production. In addition, exposure to high temperatures is a critical parameter that causes loss of strength in concrete. In this study, Geopolymer concrete samples were prepared with 10 different samples containing different proportions of slag, silica fume, and porous ash and subjected to various physical, mechanical, and optical tests. The sample (GS90) with optimum workability and compressive strength, which also showed high performance in water absorption, freeze-thaw, and UPV tests, was used in high-temperature tests. Portland cement concrete (PCC) was used as a control sample. This study investigated the effect of high temperatures on the physical and mechanical properties of fiber-free GCs containing 2%, 5%, and 10% by volume of ceramic fibers. Therefore, fiber-reinforced, fiber-free, and PCC specimens were subjected to high-temperature tests at 100, 300, 600, and 900 °C. As a result of the observation of crack growth, color changes, and compressive strength parameters in the samples subjected to high-temperature tests, the thermal resistance of the 10% ceramic fiber geopolymer concrete sample was 2.5% higher than other samples. There is no study in the literature that examines the behavior of ceramic fiber-reinforced geopolymer concrete at high temperatures. This research revealed an important finding by proving that ceramic fiber reinforcement increases the compressive strength of geopolymer concretes at a remarkable rate after high-temperature impact. [ABSTRACT FROM AUTHOR]

Pervious concrete is an innovative eco-friendly construction material. Through the application of mineral admixtures and microscopic analysis to optimize its performance and analyze its mechanisms, its traits as a sustainable building option may be further improved. This study primarily examines the impact of the optimal blend quantities of fly ash, silica fume, and reinforcing agent on the attributes, micro-morphology, and phase composition of porous concrete. The optimal admixture was chosen after analyzing the effects of various factors on the mix ratio and properties of permeable concrete. To understand the degree of impact, performance tests were conducted on the 28-day compressive strength, water permeability coefficient, and porosity. Furthermore, the micro-mechanisms of the admixtures and reinforcing agents on the properties of permeable concrete were analyzed from a microscopic point of view using scanning electron microscopy (SEM) and X-ray diffraction (XRD) analysis. This research found that the advantageous properties of permeable concrete were enhanced by the simultaneous integration of appropriate quantities of fly ash, silica fume, and reinforcing agent. This resulted in a 28-day compressive strength of 18.33 MPa and a permeability coefficient of 8.27 mm/s. Compared with the unadulterated mineral admixture, the optimal admixture of fly ash, silica fume, and reinforcing agent at the same time increased the 28-day compressive strength by about double; the permeability coefficient was reduced by 36%, but it was still at a high level; and the measured porosity did not differ much from the designed porosity. Through thorough microanalysis, the hydration reaction was significantly improved, which could enhance the microstructure and pore structure of the concrete. This was supported by a substantial increase in the macroscopic compressive strength and a decrease in the water permeability coefficient, which were consistent with the aforementioned enhancement found in the microanalysis. [ABSTRACT FROM AUTHOR]

Geopolymer enhances mechanical properties with polyvinyl alcohol (PVA) fibers, but there has been limited research exploring low PVA fiber dosages for mechanical properties in 3D printing or shotcrete. This study experimentally investigated slag and fly ash-based geopolymer mixtures reinforced with 0.1%, 0.15%, and 0.2% PVA fiber by volume as well as a control group without PVA fibers. These mixtures were prepared using fly ash, quartz sand, slag powder, silica fume, and an aqueous sodium silicate solution as the alkali activator, with the addition of PVA fiber to enhance composite toughness. The mechanical properties of the composites, encompassing dog-bone tensile properties, cubic compressive strength, bending and post-bending compressive strength, and prism compressive properties, were evaluated. Significantly, specimens with 0.15% PVA fibers exhibited optimal performance, revealing a notable 28.57% increase in tensile stress, a 36.45% surge in prism compressive strain, and a 47.59% rise in tensile strain compared to fiber-free specimens. Furthermore, environmental scanning electron microscopy observations were employed to scrutinize the microscopic mechanisms of composites incorporating PVA fibers, slag, and fly ash. In comparison to fiber-free specimens, prism compressive specimens with 0.15% PVA fibers demonstrated a 27.17% increase in post-cracking loading capacity, a 44.07% increase in post-cracking ductility, a 50.00% increase in peak strain energy, and a 76.36% increase in strain energy ratio. [ABSTRACT FROM AUTHOR]

In order to investigate the influence of igneous rock powder and silica fume on the performance of cement mortar, facilitate the application of igneous rock powder in engineering, and promote the greening of the cement industry, this study examined the pozzolanic activity of three different types of igneous rock powders: granite, andesite, and tuff. It explored the workability and mechanical properties of both binary systems (igneous rock–cement) and ternary systems (igneous rock–silica fume–cement). Microscopic techniques including X-ray diffraction (XRD), thermogravimetric analysis–differential thermal analysis (TG-DTA), scanning electron microscopy (SEM), and nitrogen adsorption were used to investigate the mechanisms of how different types of igneous rock and silica fume affect the cementitious systems. The results showed that the pozzolanic activity of igneous rock powders was relatively weak, and their inclusion at levels below 20% had minimal impact on the flowability of cement mortar. In fact, within the 20% inclusion range, andesite powder even increased the flowability. Co-blending igneous rock powders with silica fume promoted the early hydration of cement, resulting in reduced calcium hydroxide (CH) content in the hydration products. The most significant increase in strength of the cement mortar system was observed when 5% to 10% (by mass) of igneous rock powder and 5% to 10% of silica fume were used as replacements for cement. The highest cement mortar strength was achieved when 10% andesite and 10% silica fume were used as replacements, resulting in a compressive strength of 52.2 MPa. [ABSTRACT FROM AUTHOR]