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W n O 3n-1 nanotiles, with multiple stoichiometries within one nanotile, were synthesized via the chemical vapour transport method. They grow along the [010] crystallographic axis, with the thickness ranging from a few tens to a few hundreds of nm, with the lateral size up to several µm. Distinct surface corrugations, up to a few 10 nm deep appear during growth. The {102} r crystallographic shear planes indicate the W n O 3n-1 stoichiometries. Within a single nanotile, six stoichiometries were detected, namely W 16 O 47 (WO 2.938 ), W 15 O 44 (WO 2.933 ), W 14 O 41 (WO 2.928 ), W 13 O 38 (WO 2.923 ), W 12 O 35 (WO 2.917 ), and W 11 O 32 (WO 2.909 ), with the last three never being reported before. The existence of oxygen vacancies within the crystallographic shear planes resulted in the observed non-zero density of states at the Fermi energy.

The paper reports the synthesis of nickel tellurides via a mechanochemical method from elemental precursors. NiTe, NiTe 2 , and Ni 2 Te 3 were prepared by milling in stainless steel vials under nitrogen, using milling times from 1 h to 12 h. The products were characterized by powder X-ray diffraction (pXRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDX), dynamic light scattering (DLS), vibrating sample magnetometer (VSM), UV-VIS spectrometry, and thermal analysis (TGA and DSC). The products were obtained in the form of aggregates, several hundreds of nanometers in size, consisting of smaller nanosized crystallites. The magnetic measurements revealed a ferromagnetic behavior at room temperature. The band gap energies calculated using Tauc plots for NiTe, NiTe 2 , and Ni 2 Te 3 were 3.59, 3.94, and 3.70 eV, respectively. The mechanochemical process has proved to be a simple and successful method for the preparation of binary nickel tellurides, avoiding the use of solvents, toxic precursors, and energy-consuming reaction conditions.