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This paper presents a novel waste-heat-powered, wireless, and battery-less Industrial Internet of Things (IIoT) device designed for predictive maintenance in Industry 4.0 environments. With a focus on real-time quality data, this device addresses the limitations of current battery-operated IIoT devices, such as energy consumption, transmission range, data rate, and constant quality of service. It is specifically developed for heat-intensive industries (e.g., iron and steel, cement, petrochemical, etc.), where self-heating nodes, low-power processing platforms, and industrial sensors align with the stringent requirements of industrial monitoring. The presented IIoT device uses thermoelectric generators based on the Seebeck effect to harness waste heat from any hot surface, such as pipes or chimneys, ensuring continuous power without the need for batteries. The energy that is recovered can be used to power devices using mid-range wireless protocols like Bluetooth 5.0, minimizing the need for extensive in-house wireless infrastructure and incorporating light-edge computing. Consequently, up to 98% of cloud computation efforts and associated greenhouse gas emissions are reduced as data is processed within the IoT device. From the environmental perspective, the deployment of such self-powered IIoT devices contributes to reducing the carbon footprint in energy-demanding industries, aiding their digitalization transition towards the industry 5.0 paradigm. This paper presents the results of the most challenging energy harvesting technologies based on an all-silicon micro thermoelectric generator with planar architecture. The effectiveness and self-powering ability of the selected model, coupled with an ultra-low-power processing platform and Bluetooth 5 connectivity, are validated in an equivalent industrial environment to monitor vibrations in an electric machine. This approach aligns with the EU’s strategic objective of achieving net zero manufacturing capacity for renewable energy technologies, enhancing its position as a global leader in renewable energy technology (RET).

The enhancement of solid oxide cell (SOC) oxygen electrode performance through the generation of nanocomposite electrodes via infiltration using wet-chemistry processes has been widely studied in recent years. An efficient oxygen electrode consists of a porous backbone and an active catalyst, which should provide ionic conductivity, high catalytic activity and electronic conductivity. Inkjet printing is a versatile additive manufacturing technique, which can be used for reliable and homogeneous functionalization of SOC electrodes via infiltration for either small- or large-area devices. In this study, we implemented the utilization of an inkjet printer for the automatic functionalization of different gadolinium-doped ceria scaffolds, via infiltration with ethanol:water-based La1−xSrxCo1−yFeyO3−δ (LSCF) ink. Scaffolds based on commercial and mesoporous Gd-doped ceria (CGO) powders were used to demonstrate the versatility of inkjet printing as an infiltration technique. Using yttrium-stabilized zirconia (YSZ) commercial electrolytes, symmetrical LSCF/LSCF–CGO/YSZ/LSCF–CGO/LSCF cells were fabricated via infiltration and characterized by SEM-EDX, XRD and EIS. Microstructural analysis demonstrated the feasibility and reproducibility of the process. Electrochemical characterization lead to an ASR value of ≈1.2 Ω cm2 at 750 °C, in the case of nanosized rare earth-doped ceria scaffolds, with the electrode contributing ≈0.18 Ω cm2. These results demonstrate the feasibility of inkjet printing as an infiltration technique for SOC fabrication.