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The combustion process is complex and harsh, and the supersonic combustion flow field is also characterized by short duration and supersonic speed, which makes the real-time diagnostic technology for the transient environment extremely demanding. It is of great significance to realize high time-resolved accurate measurement of temperature, component concentration, and other parametric information of the combustion field to study the transient chemical reaction dynamics of the combustion field. Femtosecond CARS spectroscopy can effectively avoid the collision effect between particles in the measurement process and reduce the influence of the non-resonant background to improve the measurement accuracy and realize the time-resolved measurement on a millisecond scale. This paper introduces the development history of femtosecond CARS spectroscopy, points out its advantages and disadvantages, and looks forward to the future development trend to carry out high time-resolved measurements, establish a database of temperature changes in various complex combustion fields, and provide support for the study of engine mechanisms.

In the past 20 years, perovskite-related research has attracted wide attention. The related research into two-dimensional/quasi-two-dimensional perovskite has propelled the research of perovskite materials to a new height. To improve the properties of quasi-2D perovskite, improve the stability of materials, and achieve specific functions, using different types, volumes, and lengths of organic spacers is an essential method. In this paper, quasi-2D perovskites with EDA (ethylene diammonium), PDA (1,3-propanediammonium), and BDA (1,4-butanediammonium) (m = 2–4) as organic spacers were prepared, and the effects of different organic spacers on the 2D perovskite were investigated. The results show that the length of the organic spacer significantly impacts the perovskite’s properties. A shorter organic spacer can effectively reduce the quantum confinement and dielectric confinement in perovskite. It should be noted that if the organic spacer is too short, the stability of the quasi-2D perovskite will be greatly reduced.

Coal fire remains one of the main hazards of underground work. Spontaneous coal fires cause serious casualties and property losses. At present, most of the studies on coal spontaneous combustion have been conducted on working faces shorter than 200 m. However, the ultra-long working face gob of shallow buried coal seam is much larger, the distribution of its flow field is more complex, and, thus, risk of spontaneous combustion in the gob is higher. Exploring the evolution law of the gob flow field of ultra-long working face to quickly determine the range of the coal spontaneous combustion hazardous zone is of great significance to the safe production of similar mines. In this study, the gas flow field distribution in the gob of an ultra-long working face was measured by buried pipeline method and oxygen concentration was used as the index. It is found that the oxygen concentration decreases with the advance of the working face. Based on the flow field distribution, the oxidation zone of the gob was determined. Meanwhile, a three-dimensional (3D) numerical model of the working face was established, and the overlying stratum collapse and porosity evolution in the gob were simulated using the particle flow software, PFC3D discrete element software, for the porosity distribution law of the gob. The obtained porosity data were then imported into FLUENT using the custom function UDF to construct a 3D grid model. The flow field distribution in the gob was then numerically simulated for the seepage and migration law of the wind flow in the gob. The results reveal an arch-shaped wind flow field distribution with a swirl shape on the intake airway side. In the strike direction, the wind flow gradually becomes weaker with the advance of the working face. In the dip direction, the wind flow seepage range on the return airway side is obviously higher than that on the intake airway side. In the vertical direction, the wind flow range in the upper gob is larger than that in the middle and lower gob. The spontaneous combustion and oxidation zone of the gob is determined to be at 140.4–313.3 m on the intake airway side, 201.2–351.6 m in the middle of the gob, and 153.2–328.1 m on the return airway side. Finally, the residual coal distribution was superimposed onto the oxygen concentration distribution to obtain the spontaneous residual coal combustion hazardous zone in the gob.

Ephedra species were erect, branching shrubs found in desert or arid regions worldwide as the source of ephedrine alkaloids. In this study, the complete chloroplast genome of Ephedra przewalskii and E. monosperma on the Qinghai-Tibet Plateau were sequenced, assembled, and annotated. Compared with the other four published Ephedra species, the chloroplast genomes of Ephedra species were highly conservative, with a quadripartite structure. The length of the chloroplast genome was 109,569 bp in E. przewalskii with 36.6% GC and 109,604 bp in E. monosperma with 36.6% GC. We detected 118 genes in both Ephedra species, including 73 PCGs, 37 tRNA genes, and eight rRNA genes. Among them, the ndh family genes were lost, which could be used to study the phylogeny and genetic diversity of the genus Ephedra, combined with multiple highly variable intergenic spacer (IGS) regions. Codon usage preference of Ephedra species was weak. The ratio of non-synonymous substitutions and synonymous substitutions was low, showing that the PCGs of Ephedra may be under the pressure of purifying selection. ML and BI analysis showed similar phylogenetic topologies. Ephedra species clustered together in a well-supported monophyletic clade. E. przewalskii and E. monosperma were not gathered in one clade, consistent with the classification system by Flora of China. This study reveals differences in the chloroplast genomes of Ephedra, providing valuable and abundant data for the phylogenetic analysis and species identification of Ephedra.