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The coordinated promotion of urban digitalization and green development is an inevitable requirement for sustainable development in the digital age. Based on the coupling mechanism of urban digitalization and green development, in this study, we took 282 cities at the prefecture level and above in China from 2011 to 2019 as the research object, and we constructed the evaluation index system and calculated the coupling coordination degree (CD&GDD) of the two through the coupling coordination degree model. We further used the Dagum Gini coefficient, kernel density estimation, Markov chain and Moran’s I to assess the spatial effects of the regional differences, dynamic evolution trends and degree of coupling coordination. The results show the following: (1) The level of urban digitalization and green development show a fluctuating upward trend, and the interaction between the two is obvious. (2) Although the CD&GDD of most cities is continuously improving, it is still at a low level. There are large differences in the levels between the regions. (3) The inter-regional differences are the main source of the large overall differences in the CD&GDD in China, and these are mainly composed of the hypervariable density and net differences between the regions. (4) The phenomenon of “club convergence” exists in the CD&GDD. (5) The coupling coordination relationship between cities has a substantial spatial effect, and the spatial effect has obvious regional heterogeneity. The results and conclusions provide a reference for developing countries to promote green and low-carbon urban development.