1. Isothermal Crystallization Kinetics of Poly(ethylene terephthalate) Copolymerized with Various Amounts of Isosorbide
- Author
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Florian Fernandez, Nicolas Jacquel, Nicolas Descamps, Pierre Heijboer, and René Saint-Loup
- Subjects
Isosorbide ,Materials science ,crystallization ,isosorbide ,Kinetics ,02 engineering and technology ,010402 general chemistry ,01 natural sciences ,lcsh:Technology ,Isothermal process ,law.invention ,lcsh:Chemistry ,law ,medicine ,General Materials Science ,Crystallization ,Thermal analysis ,poly(ethylene-co-isosorbide terephthalate) ,Instrumentation ,lcsh:QH301-705.5 ,Fluid Flow and Transfer Processes ,copolyester ,lcsh:T ,Process Chemistry and Technology ,General Engineering ,Isothermal crystallization ,021001 nanoscience & nanotechnology ,Copolyester ,lcsh:QC1-999 ,0104 chemical sciences ,Computer Science Applications ,lcsh:Biology (General) ,lcsh:QD1-999 ,lcsh:TA1-2040 ,kinetics ,Melting point ,0210 nano-technology ,lcsh:Engineering (General). Civil engineering (General) ,lcsh:Physics ,Nuclear chemistry ,medicine.drug - Abstract
Poly(ethylene-co-isosorbide terephthalate) (PEIT) copolyesters could be used in various applications depending on their ability to crystallize. Moreover, the possibility to carry out solid-state post-condensation (SSP) is conditioned by its ability to sufficiently crystallize. The present study, thus, gives a systematic investigation of isothermal crystallization of these statistical copolyesters with isosorbide contents ranging from 4.8 to 20.8 mol.%. For each copolyester composition, the lowest isothermal half crystallization times and the highest Avrami constant (K) were obtained around 170 °, C. Over the range of composition that was studied, both melting points and melting enthalpies decreased with increasing amounts of isosorbide (from 250 to 207 °, C and from 55 to 28 J/g, respectively). On the contrary, half crystallization time displayed an exponential increase when increasing isosorbide contents in the studied range. Finally, structural and thermal analysis of PIT homopolyester are reported for the first time, showing that only ET moieties crystallized when PEIT was subjected to isothermal crystallization at 170 °, C.
- Published
- 2020
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