The main objective of this research was to investigate tropical wood sorptive properties. For selected tropical wood species (courbaril, ipe, light red meranti, merbau, tatajuba, and teak), the equilibrium moisture content was determined at 20 °C and 9, 30, 55, 70, and 97% relative humidity. The experimentally determined values were analysed using the Hailwood-Horrobin sorption model to compute the fibre saturation point and mono- and multi-layer sorption. There were significant differences in the sorption behaviour of different wood species. Generally, the fibre saturation point of tropical wood species is lower than in wood species from moderate climate zones. The lowest values of fibre saturation point were found for ipe (18.7%), courbaril (20.4%), and tatajuba (20.5%). Furthermore, chloroform-ethanol extractives content was correlated with multilayer sorption and the fibre saturation point, such that a higher content of chloroform-ethanol extractives was associated with a lower equilibrium moisture content. Therefore, chemisorption was not influenced by chloroform-ethanol extractives. Ethanol extracts showed an influence on monomolecular-bound water. [ABSTRACT FROM AUTHOR]