1. Direct synthesis as a new approach to heteropolynuclear complexes.
- Author
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Kokozay, Volodymyr N. and Shevchenko, Denis V.
- Subjects
- *
COMPLEX compounds synthesis , *COORDINATION compounds , *OXIDES , *CRYSTAL growth , *TRANSITION metals - Abstract
The idea of direct synthesis of coordination compounds -- use of elemental metals or their oxides as starting materials - has been developed into "Salt route", "Ammonium salt route" and "Direct template synthesis", methods to synthesize heteropolynuclear complexes. The advantages of this approach in obtaining heterobi-, heterotrimetallic and mixed-anion heteropolynuclear coordination compounds are shown taking complexes of transition metals (Cu, Ni, Co, Mn, Zn, Cd) with aminoalcohols and ethylenediamine ligand as an example. The results of the X-ray crystal structure analysis and magnetic properties of the most interesting complexes are presented. [ABSTRACT FROM AUTHOR]
- Published
- 2005