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The exceptional optical, electrical, and mechanical capabilities of layered transition metal carbides, nitrides, and carbonitrides, called MXenes, revolutionized materials science. Among them, Ti 3 C 2 received the most attention owing to the developed synthesis and processing methods, high conductivity, and pronounced plasmonic response. The latter, however, remains controversial with the open question of whether the peak around 800 nm has plasmonic or interband transition origin. To address this issue, we combine spectroscopic ellipsometry and transmittance results with first-principle computations. Their combination reveals that although Ti 3 C 2 is a metal, its optical response becomes plasmonic (Re ε < 0) above 1415 nm, in contrast to the previous understanding. In addition to fundamental significance, this dual dielectric/plasmonic optical response opens a path for theranostic applications, as we demonstrated on the example of Ti 3 C 2 nanospheres. Thus, our study revisits broadband (300-3300 nm) optical constants of Ti 3 C 2 and broadens its application scope in photonics.

The recently developed plasmonic and photonic metal-semiconductor nanolasers feature unique properties, such as ultra-small mode volume and footprint, high Purcell factor, and ultra-fast modulation. However, it is often difficult to recognize when the transition to lasing occurs, while the most important feature of laser radiation, i.e., coherence, is available only above the lasing threshold. Here we systematically study the second-order coherence properties of metal-semiconductor nanolasers at both low- and high-pump rates. We find the lasing threshold using a clear coherence definition and derive a simple expression for the threshold pump current (optical pump power), which can be applied to most thresholdless and non-thresholdless metal-semiconductor nanolasers.