Search

The thermal and optical properties of multilayered dental tissue structure, the result of the surface-grown prismless layer on enamel, were evaluated simultaneously using multiparameter fits of photothermal radiometry frequency responses. Tim photothermal field generated in a tooth sample with near-infrared laser excitation was described using a coupled diffuse-photon-density and thermal wave model. The optical (absorption and scattering) coefficients and thermal parameters (spectrally averaged infrared emissivity, thermal diffusivity and conductivity) of each layer, as well as the thickness of the upper prismless enamel layer, were fitted using a multiparameter simplex downhill minimization algorithm. The results show that the proposed tilting approach can increase robustness of the multiparameter estimation of tissue properties in the case of ill-defined multiparameter fits, which are unavoidable in in vivo tissue evaluation. The described method can readily be used for noninvasive in vitro or in two characterization of a wide range of layered biological tissues. of America OCIS codes: 170.1850, 170.7050, 160.4760, 170.5270, 170.6935.

We describe a novel approach developed for the National Polar-Orbiting Operational Environmental Satellite System/Visible Infrared Imaging Radiometer Suite (VIIRS) to retrieve pixel-level mixed-phase cloud optical thicknesses and effective particle sizes using 0.67, 1.6, 2.25, and 3.7 [micro]m bands reflectance/ radiance. This approach utilizes lookup tables of reflectances constructed from radiative transfer simulations and a numerical iterative search method. The capability of this new approach was demonstrated using Moderate Resolution Imaging Spectroradiometer (MODIS) data as proxy to VIIRS. Two proxy scenes, 14 October 2001 over North Platte, Nebraska, during the ninth Cloud Layer Experiment (CLEX-9) and 9 November 2006 over the Great Lakes and Eastern Canada during the Canadian CloudSat/Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations Validation Project (C3VP), were analyzed. The performance of the mixed-phase retrieval algorithm was assessed by comparison with the MODIS retrieval products, airborne in situ observations during CLEX-9 and CloudSat data during C3VP. OCIS codes: 010.1615, 280.1310.

The Remote Sensing Group at the University of Arizona has developed multispectral ground-viewing radiometers that use light-emitting diodes as detectors. This work describes the optical design, electrical design, and laboratory calibration of a three-channel radiometer that operates in the visible and near-infrared region of the spectrum. The optical and electrical design of the radiometer is introduced, and then the calibration and characterization of the radiometer are described. Laboratory measurements include the spectral responsivity for each channel of the radiometer, the temperature dependence of the total responsivity for each channel, system linearity, field of view, and finally, the absolute radiometric calibration. A solar-radiation-based calibration is used to determine the absolute responsivity. OCIS codes: 230.0040, 230.3670, 280.4788, 280.4991.

Combined measurements of diffuse-to-global radiation ratio and global spectral irradiances in the UV are used to derive cosine-corrected UV irradiances and aerosol optical depth (AOD). The diffuse-to-global radiation ratio is used first in the cosine correction of the global irradiance, then to calculate absolutely calibrated direct irradiances. The Beer--Lambert law is applied to derive the UVAOD using independent measurements of the extraterrestrial solar flux. The AOD can be derived with an uncertainty of about 0.03 at 60[degrees] solar zenith angle. The method was applied to measurements obtained with two UV multi-filter rotating shadowband radiometers (UV-MFRSRs) and a MK III Brewer spectrophotometer on the Island of Lampedusa in the Central Mediterranean during two periods of 2002 and 2004. The derived AOD at 318 and 332 nm was compared with UV AOD measured at 318, 320, and 368 nm with different techniques. The retrieved AOD, combining MFRSR and Brewer measurements, is in good agreement with the optical depth derived with the other methods. OCIS codes: 010.1110, 010.5620, 120.0280, 120.6200.

The Clouds and the Earth's Radiant Energy System (CERES) is a program that measures the Earth radiation budget (ERB) from two polar orbiting satellite platforms. CERES radiometers are designed to make stable broadband measurements of scattered solar and emitted thermal radiative flux leaving Earth with an accuracy of 1% or better. Using versatile and programmable scan modes, it is also possible for every CERES instrument to view the Moon on each orbit. However, until now, it has not been possible to derive absolute measurements of lunar irradiance using CERES because the Moon's disk fills only 10% of the telescope field of view. This work presents a method of integrating CERES raster-scan data in order to obtain a measurement of the average scattered solar and emitted thermal radiance from the entire lunar disk. The technique results in excellent agreement between CERES instruments on different satellites as to lunar albedo and emitted thermal flux. The average broadband Moon albedo is measured by CERES at a value of 0.1362 ([+ or -] 2-3%) when normalized to a static lunar phase angle of 7[degrees] using the U.S. Geological Survey lunar irradiance Robotic Lunar Observatory model. The method for the first time also yields very accurate measurements of the thermal irradiance emitted from the Moon. These suggest an average long-wave flux of 977 W[m.sup.-2] ([+ or -] 2-3% at 7[degrees] phase), implying an approximate mean surface temperature of around 92[degrees]C. Statistical analysis on available data suggests that a CERES instrument performing monthly lunar measurements could utilize the Moon as a stability target and reduce calibration drills to 0.3% per decade or less within an instrument's lifetime. Given the success of the technique, a solar calibration system is proposed that will allow precise tracking of an ERB instrument's optical degradation using the Sun. OCIS codes: 040.0040, 280.0280, 010.0280, 040.6808, 120.6085, 350.1270.

The energy transfer integral between radiating rectangular and detecting circular parallel plates having nonideal angular characteristics is solved for modeling the distance dependence of the irradiance signal. The equation derived for the irradiance signal, which is called the modified inverse-square law, depends on the position, shape, size, and angular characteristics of the light source and the detector. We apply the new model equation to the calibration of a spectroradiometer to determine accurately the distance offsets, which fix the positions of the effective receiving apertures of diffusers used in the entrance optics of spectroradiometers. Earlier measurement results, e.g., for solar UV irradiance, may include uncorrected effects and can be corrected reliably as diffuser offsets and other correction factors are determined with the modified inverse-square law. Simplifications of the modified inverse-square law for analyzing the distance offsets and the correction factors are studied. Simplified equations for the diffuser offset analysis may be used without losing the accuracy when the cosine response of the diffuser is reasonably good. However, for diffusers whose angular responsivities deviate much from the cosinusoidal angular responsivity, large approximation errors in the diffuser offset values may appear if the angular effects are not properly taken into account. OCIS codes: 010.1290, 080.0080, 120.5630, 230.1980.

Multifilter rotating shadowband radiometer (MFRSR) calibration values for aerosol optical depth (AOD) retrievals were determined by means of the general method formulated by Forgan [Appl. Opt. 33, 4841 (1994)] at a polluted urban site. The obtained precision is comparable with the classical method, the Langley plot, applied on clean mountaintops distant of pollution sources. The AOD retrieved over Sao Paulo City with both calibration procedures is compared with the Aerosol Robotic Network data. The observed results are similar, and, except for the shortest wavelength (415 nm), the MFRSR's AOD is systematically overestimated by ~0.03. OCIS codes: 010.1100, 010.1290, 280.1100, 280.1120.

Shadow-band radiometers in general, and especially the Multi-Filter Rotating Shadow-band Radiometer (MFRSR), are widely used for atmospheric optical depth measurements. The major programs running MFRSR networks in the United States include the Department of Energy Atmospheric Radiation Measurement (ARM) Program, U.S. Department of Agriculture UV-B Monitoring and Research Program, National Oceanic and Atmospheric Administration Surface Radiation (SURFRAD) Network, and NASA Solar Irradiance Research Network (SIRN). We discuss a number of technical issues specific to shadowband radiometers and their impact on the optical depth measurements. These problems include instrument tilt and misalignment, as well as some data processing artifacts. Techniques for data evaluation and automatic detection of some of these problems are described. OCIS codes: 120.4640, 120.5240, 120.5630, 120.0280, 010.1100, 010.1120.

The in situ procedure for determining the solar calibration constants, originally developed for the PREDE Sun--sky radiometers and based on a modified version of the Langley plot, was applied to a CIMEL instrument located in Valencia, Spain, not integrated into AERONET. Taking into account the different mechanical and electronic characteristics of the two radiometers, the method was adapted to the characteristics of the CIMEL instrument. The iterative procedure for the determination of the solar calibration constants was applied to a 3-year data set. The results were compared with the two sets of experimental calibration constants determined during this period using the standard Langley plot method. The agreement was found to be consistent with the experimental errors, and the method can definitely also be used to determine the solar calibration constant for the CIMEL instrument, improving its calibration. The method can be used provided the radiometer is previously calibrated for diffuse radiance using a standard lamp. a OCIS codes: 010.1290, 010.1110.

We describe what is believed to be a new approach developed for the National Polar-Orbiting Operational Environmental Satellite System (NPOESS) to retrieve pixel-level, cirrus cloud top temperatures (CTTs) from radiances observed in the 8.55 and 12.0 [micro]m bandpasses. The methodology solves numerically a set of nonlinear algebraic equations derived from the theory of radiative transfer based upon the correlation between emissivities in these two bandpasses. This new approach has been demonstrated using NASA's Moderate Resolution Imaging Spectroradiometer (MODIS) as a proxy to Visible Infrared Imager Radiometer Suite (VIIRS) data. Many scenes have been analyzed covering a wide range of geophysical conditions, including single-layered and multilayered cirrus cloud situations along with diverse backgrounds and seasons. For single-layer clouds, the new approach compares very favorably with the MODIS 5 km resolution cloud products; the mean CTT for both methods are very close, while the standard deviation for the new approach is smaller. However, in multilayered cloud situations, the mean CTTs for the new approach appear to be colder than the CTTs from MODIS cloud products, which are acknowledged to be too warm. Finally, partly because the new approach is applied at the pixel level, CTTs do not increase toward cloud edges as is seen in the MODIS products. Based upon these initial results, the new approach to retrieve improved VIIRS cloud top properties has been incorporated into the ground-based data processing segment of the NPOESS system where prelaunch testing of all VIIRS algorithms continues. OCIS codes: 280.0280, 120.0280.

The temporal stability of the National Institute of Standards and Technology (NIST) spectral irradiance scale as measured with broadband filter radiometers calibrated for absolute spectral irradiance responsivity is described. The working standard free-electron laser (FEL) lamps and the check standard FEL lamps have been monitored with radiometers in the ultraviolet and the visible wavelength regions. The measurements made with these two radiometers reveal that the NIST spectral irradiance scale as compared with an absolute thermodynamic scale has not changed by more than 1.5% in the visible from 1993 to 1999. Similar measurements in the ultraviolet reveal that the corresponding change is less than 1.5% from 1995 to 1999. Furthermore, a check of the spectral irradiance scale by six different filter radiometers calibrated for absolute spectral irradiance responsivity based on the high-accuracy cryogenic radiometer shows that the agreement between the present scale and the detector-based scale is better than 1.3% throughout the visible to the near-infrared wavelength region. These results validate the assigned spectral irradiance of the widely disseminated NIST or NIST-traceable standard sources. OCIS codes: 120.3930, 120.3940, 120.4800, 120.5630.

We compare the spectral sky radiance measured by three ground-based optical radiometers during the second Aerosol Characterization Experiment (ACE-2) to estimate the total uncertainty of the radiance in field experimental conditions. The propagation of this uncertainty on the column-integrated aerosol single-scattering albedo [[omega].sub.0] at 868 nm is investigated. The radiance measurements are affected by a systematic gain uncertainty of less than 2% in the visible spectral region and within 6% in the near-IR region. Correcting the measured radiance by a systematic uncertainty reduces the dispersion of the [[omega].sub.0] from 0.07 to 0.03. Besides, the total relative uncertainty of the radiance measurements in field experimental conditions is within 4% at any wavelength. The corresponding uncertainty [DELTA][[omega].sub.0] is 4% for an aerosol optical thickness of 0.2. OCIS codes: 120.5630, 170.1290, 280.1100.

The U.S. Department of Agriculture UV-B Monitoring Program measures ultraviolet light at seven wavelengths from 300 to 368 nm with an ultraviolet multifilter rotating shadow-band radiometer (UV-MFRSR) at 25 sites across the United States, including Mauna Loa, Hawaii. Column ozone has been retrieved under all-sky conditions near Boulder, Colorado (40.177 [degrees] N, 105.276 [degrees] W), from global irradiances of the UV-MFRSR 332- and 305-nm channels (2 nm FWHM) using lookup tables generated from a multiple-scattering radiative transfer code suitable for solar zenith angles (SZA's) up to 90 [degrees]. The most significant sources of error for UV-MFRSR column ozone retrievals at SZA's less than 75 [degrees] are the spectral characterizations of the filters and the absolute calibration uncertainty, which together yield an estimated uncertainty in ozone retrievals of [+ or -]4.0%. Using model sensitivity studies, we determined that the retrieved column ozone is relatively insensitive (

We present the results of a comparison of the total extinction altitude profiles measured at the same time and at same location by the ORA (Occultation Radiometer) and Stratospheric Aerosol and Gas Experiment II solar occultation experiments at three different wavelengths. A series of 25 events for which the grazing points of both experiments lie within a 2 [degrees] window has been analyzed. The mean relative differences observed over the altitude range 15-45 km are -8.4%, 1.6%, and 3% for the three channels (0.385, 0.6, and 1.02 [[micro]meter]). Some systematic degradation occurs below 20 km (as the result of signal saturation and possible cloud interference) and above 40 km (low absorption). The fair general agreement between the extinction profiles obtained by two different instruments enhances our confidence in the results of the ORA experiment and of the recently developed vertical inversion algorithm applied to real data.

The zero-frequency gain of nonimaging radiometers used in Earth radiation-budge applications is usually verified by a procedure that allows the instrument to view the Sun through an appropriate attenuating aperture and then equates its response to the known attenuated solar constant. However, channel intercomparison often requires that data from a low-resolution, relatively slow instrument such as an active-cavity radiometer be compared with data from a high-resolution, fast instrument such as a scanning thermistor-bolometer radiometer. In such a case, consideration of the difference in the dynamic responses of the two channels may be important. A novel technique for in-flight measurement of the radiometric transfer function of such instruments is described and then demonstrated through the use of a high-order dynamic model o the total, wide-field-of-view, nonscanning channel of NASA's Earth Radiation Budget Experiment (ERBE).

Optical depth retrieval by means of Langley regression is complicated by cloud transits and other time-varying interferences. An algorithm is described that objectively selects data points from a continuous time series and performs the required regression. The performance of this algorithm is compared by a double-blind test with an analysis done subjectively. The limits to accuracy imposed by time-averaged data are discussed, and an additional iterative postprocessing algorithm is described that improves the accuracy of optical depth inferences made from data with time-averaging periods longer than 5 min. Such routine algorithms are required to provide intercomparable retrievals of optical depths from widely varying historical data sets and to support large networks of instruments such as the multifilter rotating shadow-band radiometer.

The multifilter rotating shadow-band radiometer is a ground-based instrument that uses independent interference-filter-photodiode detectors and the automated rotating shadow-band technique to make spectrally resolved measurements at seven wavelength passbands (chosen at the time of manufacture between 350 nm and 1.7 [[micro]meter]) of direct-normal, total-horizontal, and diffuse-horizontal irradiances. This instrument achieves an accuracy in direct-normal spectral irradiance comparable with that of tracking radiometers, and it is more accurate than conventional instruments for the determination of the diffuse and total-horizontal spectral irradiances because the angular acceptance function of the instrument closely approximates the ideal cosine response, and because the measured direct-normal component can be corrected for the remaining angular acceptance error. The three irradiance components are measured with the same detector for a given wavelength. Together with the automated shadow-band technique, this guarantees that the calibration coefficients are identical for each, thus reducing errors when one compares them (as opposed to measurements made with independent instruments). One can use the direct-normal component observations for Langley analysis to obtain depths and to provide an ongoing calibration against the solar constant by extrapolation to zero air mass. Thus the long-term stability of all three measured components can be tied to the solar constant by an analysis of the routinely collected data.

A fiber-optic radiometer is used to monitor and control, in real time, the temperature of samples of biological tissue irradiated with a CO2 laser. Several control algorithms are investigated and the optimal control mode is obtained. A silver halide infrared fiber is used both to deliver the CO2 laser radiation needed to irradiate the target and to deliver the thermal radiation emitted from the target back to the radiometer. Such a system can be useful in medical applications of CO2 lasers.

Two procedures are used to establish calibration of the visible and near-infrared channels of the National Oceanic and Atmospheric Administration-11 (NOAA-II) Advanced Very High Resolution Radiometer (AVHRR). The first procedure for visible spectra, uses satellite data, ground measurements of atmospheric conditions during satellite overpass, and historical surface reflectance values at White Sands Missile Range (WSMR) in New Mexico. The second procedure, for the near-infrared, uses knowledge of the reflective properties at the WSMR and of a low-reflectance area, as determined from the first method, that yields satellite-gain values without a requirement for ground measurements of atmospheric conditions. The accuracy of gain values is estimated at + or - 7% for the two methods. The WSMR combines accessibility, a wide range of surface reflectances, and generally good observing conditions, making it a desirable location for satellite calibration.

We describe the design, the development, and the calibration of a radiometer to measure water vapor abundance in the middle atmosphere, using the solar occultation technique from an orbiting platform. The use of gas cells containing water vapor and carbon dioxide leads to a relatively simple, but sensitive, design. This radiometer is shown to be capable of detecting water vapor in the mesosphere, where, because of dissociation by the Sun, the amounts are very small, of the order of 1 part per 10 to the sixth power or less. A flight version of the instrument will be launched in 1992 on board the European Retrievable Carrier space platform, and the data will be employed for a better understanding of the Earth's water budget.

We develop a retrieval scheme by using advanced very-high-resolution radiometer (AVHRR) 3.7- and 10.9-micrometer data to compute simultaneously the temperature, optical depth, and mean effective ice-crystal size for cirrus clouds. The methodology involves the numerical solution of a set of nonlinear algebraic equations derived from the theory of radiative transfer. The solution requires the correlation of emissivities of two channels in terms of the effective extinction ratio. The dependence of this ratio on ice-crystal size distribution is examined by using an adding-doubling radiative transfer program. Investigation of the effects of cirrus parameters on upwelling radiances reveals that the brightness-temperature difference between the two channels becomes larger for colder cirrus and smaller ice-crystal sizes. We apply the current retrieval scheme to satellite data collected at 0930 UTC, 28 October 1986, over the region of the First International Satellite Cloud Climatology Project Regional Experiment Cirrus Intensive Field Observation. We select the data over an area (approximately 44 degrees N, 92 degrees W) near Fort McCoy, Wisconsin, for analysis. The retrieved cirrus heights compare reasonably well with lidar measurements taken at Fort McCoy 2 h after a satellite overpass at the target region. The retrieved mean effective crystal size is close to that derived from in situ aircraft measurements over Madison, Wisconsin, six hours after a satellite overpass.

The New Zealand Meteorological Service has used a Robertson-Berger meter (RB meter) to monitor solar UV-B radiation for the past decade. The radiometric properties of the instrument have been analyzed and agree with the standard values published by Berger. A detailed theoretical treatment of the RB meter response that fully accounts for its cosine response is presented. Field measurements made with the RB meter and with a double monochromator spectral radiometer were used to validate the theoretical model and to derive a calibration for the RB meter. Only cloud-free data were considered so that the downward radiation field at the surface could be modeled as the sum of direct solar and isotropic diffuse components. The imperfect cosine responses of both instruments were modeled. A RB meter count was found to equate to 0.25 plus or minus 0.02 Jm to the -2 power referenced to 300-nm radiation at vertical incidence.

We carry out the calibration of an ultraviolet spectrometer by using a cryogenic electrical-substitution radiometer and intensity-stabilized laser sources. A comparison of the error budgets for the laser-based calibration described here and for a calibration using a type-FEL tungsten spectral-irradiance standard indicates that this technique could provide an improvement of a factor of approximately 3 in the uncertainty of the spectrometer calibration, resulting in an absolute accuracy (standard deviation of 3) of approximately 1% at 257 nm. The technique described here might significantly improve the accuracy of calibrations on NASA ozone-monitoring and solar ultraviolet-monitoring spectrophotometers when used to complement present procedures that employ lamps and the SURF II synchrotron ultraviolet radiation facility at the National Institute of Standards and Technology.

We describe a vertically scanning infrared radiometer for measuring the air-sea temperature difference without disturbing the water skin layer. The radiometer operates with a single wavelength channel that is 1.1 [micro]m wide, centered on 14.2 [micro]m, on the short-wavelength edge of a [CO.sub.2] atmospheric absorption band. The resulting high atmospheric absorption enables calibration of the horizontal-viewing signal with an in situ air-temperature sensor. The signal at all other scan angles is measured relative to that at the horizontal, providing a differential air-sea temperature measurement that is nearly independent of calibration offsets that can be a problem with independent air- and water-temperature sensors. We show data measured on a ship in the Tropical Western Pacific Ocean during July 1999, which exhibit important discrepancies from in situ data using bulk air- and water-temperature sensors. These discrepancies illustrate important differences between bulk versus skin water temperature. OCIS codes: 010.0010, 120.0120, 120.5630, 120.0280.

A methodology for direct-Sun ozone retrieval using the ultraviolet multifilter rotating shadow-band radiometer (UV-MFRSR) is presented. Total vertical column ozone was retrieved in three stations: Mauna Loa, Hawaii, in the U.S., and Regina, Saskatchewan, and Toronto, Ontario, in Canada, from direct solar irradiances of the UV-MFRSR at 325-, 305-, 332-, and 311-nm channels (2-nm FWHM). The total uncertainty of ozone retrievals in this study is [+ or -] 2.0%. For Mauna Loa the mean ratios of the UV-MFRSR column ozone retrievals to the collocated Dobson and Brewer were 0.998 and 0.986 between May and September of 1999. The mean ratio of UV-MFRSR retrievals to the collocated Brewer retrievals was 1.012 in Toronto between April and August of 1999, and the mean ratio of retrievals of the UV-MFRSR to the collocated Brewer was 0.988 in Regina between June and September of 1999. Total vertical column ozone values for solar zenith angles of [is greater than] 70 [degrees] were not considered, because of the signal-to-noise ratio and the angular response of the instruments, and were not used in the evaluation. The advantages of total vertical column ozone retrieval using UV-MFRSR include relatively low cost, computer-controlled operation, automated calibration stability checks, and minimal maintenance. It allows for the real-time measurement of total vertical column ozone. The UV-MFRSR is being used at 28 sites across the United States and 2 sites in Canada that form the U.S. Department of Agriculture UV-B Radiation Monitoring and Research Program. This constitutes a unique network of total vertical column ozone measurement. OCIS codes: 010.4950, 040.7190, 060.4250, 120.2440, 120.6200, 350.5610.

Ultraviolet light was measured at four channels (305, 311, 318, and 332 nm) with a precision filter radiometer (UV-PFR) at Arosa, Switzerland (46.78 [degrees], 9.68 [degrees], 1850 m above sea level), within the instrument trial phase of a cooperative venture of the Swiss Meteorological Institute (MeteoSwiss) and the Physikalisch-Meteorologisches Observatorium Davos/World Radiation Center. We retrieved ozone-column density data from these direct relative irradiance measurements by adapting the Dobson standard method for all possible single-difference wavelength pairs and one double-difference pair (305/311 and 305/318) under conditions of cloud-free sky and of thin clouds (cloud optical depth [is less than] 2.5 at 500 nm). All UV-PFR retrievals exhibited excellent agreement with those of collocated Dobson and Brewer spectrophotometers for data obtained during two months in 1999. Combining the results of the error analysis and the findings of the validation, we propose to retrieve ozone-column density by using the 305/311 single difference pair and the double-difference pair. Furthermore, combining both retrievals by building the ratio of ozone-column density yields information that is relevant to data quality control. Estimates of the 305/311 pair agree with measurements by the Dobson and Brewer instruments within 1% for both the mean and the standard deviation of the differences. For the double pair these values are in a range up to 1.6%. However, this pair is less sensitive to model errors. The retrieval performance is also consistent with satellite-based data from the Earth Probe Total Ozone Mapping Spectrometer (EP-TOMS) and the Global Ozone Monitoring Experiment instrument (GOME). [C] 2001 Optical Society of America OCIS codes: 120.0120, 120.5630, 010.4950, 040.7190, 350.2460.

Errors in measurements of sea-surface skin temperature (SSST) caused by inappropriate measurements of sky radiance are discussed; both model simulations and in situ data obtained in the Atlantic Ocean are used. These errors are typically caused by incorrect radiometer view geometry (pointing), temporal mismatches between the sea surface and atmospheric views, and the effect of wind on the sea surface. For clear-sky, overcast, or high-humidity atmospheric conditions, SSST is relatively insensitive ([is less than]0.1 K) to sky-pointing errors of [+ or -] 10 [degrees] and to temporal mismatches between the sea and sky views. In mixed-cloud conditions, SSST errors greater than [+ or -] 0.25 K are possible as a result either of poor radiometer pointing or of a temporal mismatch between the sea and sky views. Sea-surface emissivity also changes with sea view pointing angle. Sea view pointing errors should remain below 5 [degrees] for SSST errors of [is less than]0.1K. We conclude that the clear-sky requirement of satellite infrared SSST observations means that sky-pointing errors are small when one is obtaining in situ SSST validation data at zenith angles of [is less than] 40 [degrees]. At zenith angles greater than this, large errors are possible in high-wind-speed conditions. We recommend that high-resolution inclinometer measurements always be used, together with regular alternating sea and sky views, and that the temporal mismatch between sea and sky views be as small as possible. These results have important implications for the development of operational autonomous instruments for determining SSST for the long-term validation of satellite SSST. OCIS codes: 010.4450, 010.1290, 260.3060, 120.5630, 120.0280, 120.6780.

We present the retrieval of temperature and [O.sub.3] volume mixing ratio profiles in the middle atmosphere from a single strong [O.sub.3] line. We performed the study using simulated limb-sounding measurements in the frame of the submillimeter radiometer (SMR) instrument that will be carried by the Odin satellite that is due to be launched in early 2001. This study is interesting for the Odin SMR data analysis because we first provide additional temperature measurements, and second reduce significantly the [O.sub.3] retrieval error that is due to the temperature and pressure uncertainties. Nonlinear retrievals are performed to retrieve the [O.sub.3], CO, [H.sub.2]O, and temperature profiles simultaneously from the spectral band 576.27--576.67 GHz. The pressure profile is deduced from the hydrostatic equilibrium equation after each iteration. Temperature and [O.sub.3] can be retrieved throughout the stratosphere from 15--50 and 20--50 km, respectively, with a vertical resolution of 3 km. The altitude domain corresponds to the parts of the atmosphere where the signal intensity saturates in some spectrometer channels. A total error of 4--6 K has been found in the temperature profile, mainly because of the instrumental thermal noise and to a lesser extent the calibration. The total error in the [O.sub.3] profile is 5--10% and is dominated by the [O.sub.3] line-broadening parameter. The total error on the retrieved pressure profile is 2--10% because of the errors in calibration and reference pressure. OCIS codes: 280.0280, 010.4950.

A ground-based remote sounding instrument that uses a length-modulated radiometer to measure the total atmospheric carbon monoxide (CO) column has been built. Measurements made in Toronto during August and September of 1994 showed average CO concentrations of 125 to 150 parts per billion in volume (ppbv, parts in [10.sup.9]). Similar measurements made in October at a rural site 80 km north of Toronto showed concentrations of approximately 100 ppbv. The latter measurements are shown to agree with other simultaneous ground- and satellite-based measurements. This instrument is an advanced prototype of the MOPITT (Measurements of Pollution in the Troposphere) satellite instrument.