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Start Over Author "Svetlana I. Zhivetyeva" Publisher pleiades publishing ltd
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1. 2-DIETHYLAMINOVINYL DERIVATIVES OF HALOGENATED 1,4-QUINONES: SYNTHETIC AND STRUCTURAL ASPECTS

Author

E. V. Tretyakov, I. A. Zayakin, I. Yu. Bagryanskaya, and Svetlana I. Zhivetyeva

Subjects
Inorganic Chemistry, Computational chemistry, Chemistry, Phase (matter), Materials Chemistry, Crystal structure, Physical and Theoretical Chemistry, 010402 general chemistry, 010403 inorganic & nuclear chemistry, 01 natural sciences, 0104 chemical sciences, Quinone
Abstract

Diethylaminovinyl derivatives of halogenated 1,4-quinones (enaminoquinones) are produced by the interaction of halogenated 1,4-quinones with N,N-diethyl-N-vinylamine obtained in situ from Et2NH and MeCHO. Molecular and crystal structures of enaminoquinones halogenated in the quinone fragment are determined. It is shown that in the solid phase, atoms of the entire push-pull system of enaminoquinones lie practically in one plane.

Published
2020

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