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Air-conditioning systems make the most significant part of energy consumption in the residential sector. There is no denying that it is essential to produce a comfortable indoor thermal environment for residents in a building. The actual goal is to achieve thermal comfort level without putting too much cost on the ecological system by trying to conserve the amount of energy consumed. An effective way to help achieve such a goal is by incorporating thermal insulation in buildings. Thermal insulations help reduce thermal energy gained during the implementation of a desired thermal comfort level. This study aims to use an environmentally friendly nanoparticle of date pits to create thermal insulations that can be used in buildings. Different ratios of the nanoparticle of the date pits and sand composite were investigated. Fourier transform infrared spectroscopy and scanning electron microscopy were used to characterize the new materials. The material with nanoparticles of date pits and 50% by-volume epoxy provided good thermal insulation with thermal conductivity of 0.26 W/mK that could be used in the existing buildings. This has the potential to reduce the overall energy consumption by 4,494 kWh and thereby reduce CO2 emissions of a 570 m2 house by 1.8 tons annually. In conclusion, the future of using nanoparticles of date pits in construction is bright and promising due to their promising results. The publication of this article was funded by the Qatar National Library. The funders had no role in study design, data collection and analysis, decision to publish, or preparation of the manuscript. Scopus

Incineration has emerged as one of the acceptable ways to treat municipal solid waste (MSW) due to its potential in reducing the mass and volume of the waste. However, it produces two major by-product residues, namely MSW-bottom ash (MSW-BA) and MSW-fly ash (MSW-FA). These residues have gained great attention to their hazardous nature and potential to be reused and recycled. In this paper, the physicochemical characterizations of the MSW-BA and the MSW-FA were performed, followed by a systematic investigation of metals extraction from MSW-BA and MSW-FA. Various extracting agents were used to investigate the possibility to extract 21 metals including cadmium (Cd), vanadium (V), chromium (Cr), and lead (Pb). It was revealed that some metals were present in a high amount in the MSW-BA while other metals were higher in the MSW-FA. Moreover, the energy-dispersive X-ray spectroscopy results revealed that the MSW-BA was dominated by oxygen (O) 55.4 ±0.6 wt%, silicon (Si) 22.5 ±0.3 wt%, and calcium (Ca) 18.5 ±0.2 wt%. On the other hand, the MSW-FA was enriched with Ca 45.2 ±0.5 wt%, and O 40.3 ±0.4 wt%. From the scanning electron microscopy, the MSW-BA was observed as flaky with an irregular surface that consisted of large pores, while, the MSW-FA was present as agglomerated particles and had a bimodal distribution. Moreover, Fourier transform infrared spectroscopy revealed that Al-Fe-OH, Al-Al-OH, Si-O, C-O, and C-H were some of the major functional groups present in the ashes. The F-tests concluded that the metal extraction from the MSW-BA and MSW-FA were significantly affected by the acid type. it is concluded that nitric acid and phosphoric acid were the best-suited acid for the MSW-BA while sulfuric acid and phosphoric acid for the MSW-FA. More than 11 wt% of Cd and 9 wt% of Cu were extracted from MSW-BA while 6 wt% of Pb and 4.5 wt% of V were extracted from the MSW-FA. The present methodology is an interesting development in metal extraction from the MSW-BA and the MSW-FA, which can develop in a cost-effective and sustainable option to utilize MSW.