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1. Gold(i)-catalyzed dehydrogenative cycloisomerization of 1,5-enynes.

Author

Chen, Gen-Qiang, Fang, Wei, Wei, Yin, Tang, Xiang-Ying, and Shi, Min

Subjects
ENYNES, CYCLOISOMERIZATION, CYCLOPROPANE, BENZOCYCLOBUTENE, BENZOQUINONES, GOLD metallurgy
Abstract

The gold(i)-catalyzed dehydrogenative cycloisomerization of cyclopropane-tethered 1,5-enynes proceeded smoothly to give multisubstituted benzene derivatives in good to excellent yields. Synthetically important benzocyclobutenes can be produced in high yields in the presence of a gold(i) catalyst and DDQ. Furthermore, this reaction also works very well for non-cyclopropane tethered 1,5-enynes. [ABSTRACT FROM AUTHOR]

Published
2016
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