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1. Carborane-based metal–organic frameworks as highly selective sorbents for CO2 over methane.

Author

Bae, Youn-Sang, Farha, Omar K., Spokoyny, Alexander M., Mirkin, Chad A., Hupp, Joseph T., and Snurr, Randall Q.

Subjects
CARBORANES, ORGANOMETALLIC chemistry, CARBON dioxide adsorption, METHANE, SEPARATION of gases, MIXTURES
Abstract

Separation of CO2/CH4 mixtures was studied in carborane-based metal–organic framework materials with and without coordinatively unsaturated metal sites; high selectivities for CO2 over CH4 (∼17) are obtained, especially in the material with open metal sites. [ABSTRACT FROM AUTHOR]

Published
2008
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