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A series of dynamic single crystals with a chemical formula of [MII(en)3]SO4 (en = ethylene and MII = NiII, MnII, and CdII) was synthesized. As the temperature decreases, these materials exhibit dielectric switching in the vicinity of the phase transition point accompanied by anisotropic thermal expansion in the cell parameters as a consequence of the order–disorder structural change of SO 2−4 in a cavity surrounded by five [MII(en)3]2+ complex cations. Because the variation of metal centers with different ionic radii changes the shape of the complex cation, which affects the distribution of hydrogen-bond interactions around the SO 2−4 , the dynamic motion of SO 2−4 is substantially tuned. Correspondingly, the dielectric properties and anisotropic thermal expansion of materials were largely shifted, especially in the single crystals of [MnII(en)3]SO4, whose structural change is distinctly different from the crystals of Ni(II) and Cd(II). The detailed structural mechanism accounting for the different physical properties of these materials was discussed. [ABSTRACT FROM AUTHOR]

Reversible single crystal-to-single crystal transformations from [FeL2(NCS)2]·3MeOH (1·3MeOH, L = 2-(anthracen-10-yl)-1H-imidazo[4,5-f][1,10]phenanthroline) to 1 and 1·2H2O were reported, which were accompanied by on–off switching of the spin-crossover properties. [ABSTRACT FROM AUTHOR]

A cyano-bridged {Fe2Co2} complex shows reversible single crystal-to-single crystal transformation between diamagnetic and paramagnetic states switched specifically by losing and absorbing methanol at room temperature in the solid state. And the solvent loss form presents temperature- and pressure-induced intramolecular electron transfer behaviour. [ABSTRACT FROM AUTHOR]