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Your search keyword '"Yan, Chaoguo"' showing total 1 results
Start Over Author "Yan, Chaoguo" Topic visible spectra Publisher royal society of chemistry

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1 results on '"Yan, Chaoguo"'

1. Visible-light-induced ligand to metal charge transfer excitation enabled phosphorylation of aryl halides.

Author

Hou, Hong, Zhou, Bing, Wang, Jiawei, Sun, Duhao, Yu, Huaguang, Chen, Xiaoyun, Han, Ying, Shi, Yaocheng, Yan, Chaoguo, and Zhu, Shaoqun

Subjects
*CHARGE transfer, *PHOSPHORYLATION, *PHOSPHINE oxides, *METALS, *VISIBLE spectra, *NICKEL phosphide, *ARYL halides
Abstract

We herein described a visible light induced nickel(II)-catalyzed cross-coupling of secondary phosphine oxides with aryl halides. The Ni(I) species and chlorine atom radical ClË™ were generated via the ligand to metal charge transfer (LMCT) process of the NiCl2(PPh3)2, which allows nickel(IV)-phosphorus species in situ formation, giving various tertiary phosphine oxides under photocatalyst-free conditions. [ABSTRACT FROM AUTHOR]

Published
2021
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