Search

The first examples of half-sandwich Rh(i) complexes stabilized by borane coordination have been prepared and structurally characterized. As substantiated by NMR spectroscopy and single-crystal X-ray diffraction, the phosphine-borane ligand iPr 2 P-(o-C 6 H 4 )-BFxyl 2 1 [Fxyl = 3,5-(F 3 C) 2 C 6 H 3 ] engages in tight η 3 -BCC or η 1 -B coordination, depending on the metal environment.

A new class of tritopic ferrocene-based ambiphilic compounds has been prepared by assembling diphosphino- and boryl-substituted cyclopentadienides at iron. The presence of five sterically demanding substituents on the ferrocene platform induces conformational constraints, as is apparent from XRD and NMR data, but does not prevent the chelating coordination to platinum. The Lewis acid moiety is pendant in both the free ligand and the platinum complex.