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Promoting the separation of photogenerated electron–hole pairs and enhancing the charge carrier transfer are critical in photocatalysis. In our work, a ball-flower-like NiS/Zn3In2S6/g-C3N4 photocatalyst fabricated by a hydrothermal method exhibited superior performance for photocatalytic water splitting. The optimized 2.0% NiS/Zn3In2S6/g-C3N4 rivaled noble metal based Pt/g-C3N4 and showed an apparent quantum efficiency (AQE) of 24.3% at 420 nm, with a H2 yield of 4.135 mmol g−1 h−1, which was 30.4 and 9.51 times that of pure g-C3N4 and binary Zn3In2S6/g-C3N4 composites, respectively. The experimental and characterization results suggested that the heterojunction formed between Zn3In2S6/g-C3N4 and the decorating NiS co-catalyst cooperatively suppressed the electron–hole recombination and facilitated the charge carrier transfer, thus resulting in significant improvement of the H2 evolution performance. Moreover, the increased specific surface area and the enhanced visible-light absorption also contributed to superior water splitting performance. The prepared ternary catalytic system with the heterojunction and non-noble metal co-catalyst has great potential as an alternative to noble metals for achieving cost-efficient water splitting systems. [ABSTRACT FROM AUTHOR]

Promoting the separation of photogenerated electron-hole pairs and enhancing the charge carrier transfer are critical in photocatalysis. In our work, a ball-flower-like NiS/Zn 3 In 2 S 6 /g-C 3 N 4 photocatalyst fabricated by a hydrothermal method exhibited superior performance for photocatalytic water splitting. The optimized 2.0% NiS/Zn 3 In 2 S 6 /g-C 3 N 4 rivaled noble metal based Pt/g-C 3 N 4 and showed an apparent quantum efficiency (AQE) of 24.3% at 420 nm, with a H 2 yield of 4.135 mmol g -1 h -1 , which was 30.4 and 9.51 times that of pure g-C 3 N 4 and binary Zn 3 In 2 S 6 /g-C 3 N 4 composites, respectively. The experimental and characterization results suggested that the heterojunction formed between Zn 3 In 2 S 6 /g-C 3 N 4 and the decorating NiS co-catalyst cooperatively suppressed the electron-hole recombination and facilitated the charge carrier transfer, thus resulting in significant improvement of the H 2 evolution performance. Moreover, the increased specific surface area and the enhanced visible-light absorption also contributed to superior water splitting performance. The prepared ternary catalytic system with the heterojunction and non-noble metal co-catalyst has great potential as an alternative to noble metals for achieving cost-efficient water splitting systems.