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Your search keyword '"Mason, Sax A."' showing total 8 results
Start Over Author "Mason, Sax A." Publisher royal society of chemistry
8 results on '"Mason, Sax A."'

4. On intramolecular dyotropy: structural effects on reaction rates, crystal structure–molecular mechanics correlations and primary deuterium kinetic isotope effects. (Parameters for intramolecular recognition).

Author

Mackenzie, Kenneth, Howard, Judith A. K., Mason, Sax, Gravett, Edward C., Astin, K. Brian, Shi-Xiong, Liu, Batsanov, Andrei S., Vlaovic, Djordje, Maher, John P., Murray, Martin, Kendrew, Deborah, Wilson, Claire, Johnson, Robert E., Preiß, Thomas, and Gregory, Robert J.

Published
1993
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8. (+)-syn-Benzotriborneol an enantiopure C3-symmetric receptor for water.

Author

Fabris F, De Lucchi O, Nardini I, Crisma M, Mazzanti A, Mason SA, Lemée-Cailleau MH, Scaramuzzo FA, and Zonta C

Subjects
Hydrogen Bonding, Models, Molecular, Molecular Structure, Oxygen chemistry, Solutions, Stereoisomerism, Thermodynamics, Camphanes chemical synthesis, Water chemistry
Abstract

(+)-syn-Benzotriborneol forms stable complexes with one molecule of water. This is due to the ability of the host to form three hydrogen bonds with water, to act simultaneously as a hydrogen-bond acceptor and donor, and to a perfect geometrical match between the pair. We report experimental (X-ray and neutron diffraction, VT NMR, DSC, TGA) and stereochemical studies carried out to elucidate and quantify the molecular and thermodynamic aspects of this supramolecular complex.

Published
2012
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